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11.
Dr. Tana Koudelakova Dr. Radka Chaloupkova Dr. Jan Brezovsky Dr. Zbynek Prokop Dr. Eva Sebestova Dr. Martin Hesseler Dr. Morteza Khabiri Maryia Plevaka Daryna Kulik Dr. Ivana Kuta Smatanova Dr. Pavlina Rezacova Dr. Rudiger Ettrich Prof. Uwe T. Bornscheuer Prof. Jiri Damborsky 《Angewandte Chemie (International ed. in English)》2013,52(7):1959-1963
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Hossein Asadi Alireza Haghdoost Morteza Ramezani Nima Elyasi Amirali Baniasadi 《Microelectronics Reliability》2014
Reliability of the current microprocessor technology is seriously challenged by radiation-induced soft errors. Accurate Vulnerability Factor (VF) modeling of system components is crucial in designing cost-effective protection schemes in high-performance processors. Although Statistical Fault Injection (SFI) techniques can be used to provide relatively accurate VF estimations, they are often very time-consuming. Unlike SFI techniques, recently proposed analytical models can be used to compute VF in a timely fashion. However, VFs computed by such models are inaccurate as the system-level impact of soft errors is overlooked. 相似文献
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A template-free seeded short-time in situ hydrothermal treatment was carried out in a brass autoclave to synthesize crystalline mordenite (MOR) membranes on alumina-silicate disk supports with micro-scale pores. According to XRD analysis, MOR was the only zeolitic material present in the membrane layers on the supports. SEM examination of the membranes showed three different layers of the membrane thickness: (i) support sub-layer, (ii) mix penetrated mid-layer, the MOR crystals filling the pores among the support (about 4–5 μm), and (iii) MOR top-layer (about 4–5 μm). The crystalline bonds between MOR crystals of the membrane top-layer and the crystals of the support were clearly observed within the mid-layer. The continuous top-layer of zeolitic membrane was formed by many large and well-shaped crystals. The seeding treatment significantly enhanced the formation of MOR crystals onto the surface of the supports. EDAX analysis showed a Si/Al ratio of 6.8 for the MOR layer of the membrane. Due to their hydrophilic natures, the polycrystalline MOR membranes were found to be selective for continuous dehydration of different EtOH–water mixtures through an adsorption–diffusion–desorption mechanism. Both total permeation flux and separation factor of the membrane were found to increase by increasing temperature and water concentration of feed. The continuity and high crystallinity of the membrane top-layer led to the fairly high dehydration of EtOH. It was found that there was no pinhole within the layer and the morphology of the membrane was almost defect-free. 相似文献
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Let G be a 2k-edge-connected graph with and let for every . A spanning subgraph F of G is called an L-factor, if for every . In this article, we show that if for every , then G has a k-edge-connected L-factor. We also show that if and for every , then G has a k-edge-connected L-factor. 相似文献
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A series of dinuclear cycloplatinated(II) complexes with general closed formula of [Pt2Me2(C^N)2(μ‐P^P)] (C^N = 2‐vinylpyridine (Vpy), 2,2′‐bipyridine N‐oxide (O‐bpy), 2‐(2,4‐difluorophenyl)pyridine (dfppy); P^P = 1,1‐bis(diphenylphosphino)methane (dppm), N,N‐bis(diphenylphosphino)amine (dppa)) are reported. The complexes were characterized by means of NMR spectroscopy. Due to the presence of dppm and dppa with short backbones as bridging ligands, two platinum centres are located in front of each other in these complexes so a Pt…Pt interaction is established. Because of this Pt…Pt interaction, the complexes have bright orange colour under ambient light and are able to strongly emit red light under UV light exposure. These strong red emissions originate from a 3MMLCT (metal–metal‐to‐ligand charge transfer) electronic transition. In most of these complexes, the emissions have unstructured bell‐shaped bands, confirming the presence of large amount of 3MMLCT character in the emissive state. Only the complexes bearing dfppy and dppa ligands reveal dual luminescence: a high‐energy structured emission originating from 3ILCT/3MLCT (intra‐ligand charge transfer/metal‐to‐ligand charge transfer) and an unstructured low‐energy band associated with 3MMLCT. In order to describe the nature of the electronic transitions, density functional theory calculations were performed for all the complexes. 相似文献
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Reaction pathways of ethylene and carbon monoxide on the singlet and triplet potential energy surfaces (PESs) have been calculated at B3LYP/6-311++G (3df, 3dp), G3B3 and CCSD(T)//B3LYP levels. Reaction mechanisms have been investigated by analysis of various structures. Suggested reaction mechanisms reveal that 3P3(CH2CHCHO) and 3P4(CH3CCHO) are thermodynamically stable adducts with the negative value in Gibbs free energies on the triplet PES. In addition, results show that one intersystem crossing exists between triplet and singlet PESs, which are obtained by scanning of the C–C bond length in 1IN3 and 3IN7 species. 相似文献
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