全文获取类型
收费全文 | 2697篇 |
免费 | 67篇 |
国内免费 | 19篇 |
专业分类
化学 | 1453篇 |
晶体学 | 24篇 |
力学 | 86篇 |
数学 | 442篇 |
物理学 | 419篇 |
无线电 | 359篇 |
出版年
2021年 | 27篇 |
2020年 | 31篇 |
2019年 | 36篇 |
2018年 | 26篇 |
2017年 | 22篇 |
2016年 | 45篇 |
2015年 | 49篇 |
2014年 | 40篇 |
2013年 | 106篇 |
2012年 | 83篇 |
2011年 | 111篇 |
2010年 | 61篇 |
2009年 | 55篇 |
2008年 | 80篇 |
2007年 | 102篇 |
2006年 | 113篇 |
2005年 | 130篇 |
2004年 | 103篇 |
2003年 | 110篇 |
2002年 | 94篇 |
2001年 | 64篇 |
2000年 | 53篇 |
1999年 | 35篇 |
1998年 | 37篇 |
1997年 | 46篇 |
1996年 | 38篇 |
1995年 | 44篇 |
1994年 | 43篇 |
1993年 | 41篇 |
1992年 | 53篇 |
1991年 | 44篇 |
1990年 | 39篇 |
1989年 | 38篇 |
1988年 | 42篇 |
1987年 | 23篇 |
1986年 | 23篇 |
1985年 | 45篇 |
1984年 | 42篇 |
1983年 | 42篇 |
1982年 | 38篇 |
1981年 | 34篇 |
1980年 | 40篇 |
1979年 | 30篇 |
1978年 | 39篇 |
1977年 | 29篇 |
1976年 | 39篇 |
1975年 | 32篇 |
1974年 | 42篇 |
1973年 | 41篇 |
1972年 | 21篇 |
排序方式: 共有2783条查询结果,搜索用时 15 毫秒
121.
The selection and quality of hops is a major determinant in beer flavour. Brewers acknowledge that distinctive characteristics of different hop varieties can be traced to the composition of their essential oils. The difficulty in characterising complex mixtures such as hop oil using 1-D chromatography is that many compounds co-elute. With the introduction of comprehensive multidimensional capillary gas chromatography (GC x GC), there is a tremendous improvement in the separation power or peak capacity. Recent work using GC x GC with flame ionisation detection has suggested that there may be over 1,000 compounds in hop oil. This work describes the use of GC x GC combined with TOFMS detection (Leco Pegasus 4D instrument) to analyse Target hop oil. The TOFMS spectral acquisition rate of 60 Hz provided sufficient spectra per peak (2-D peak base width of 0.1-0.2 s) for identification (119 components were identified with 45 previously unreported compounds). When analysing results, an advantage of GC x GC coupled to TOFMS is that 2-D chromatograms can be viewed for individual masses that are characteristic of particular functional groups. This allows the analyst to view the various homologous series of compounds although in certain cases coelution may still be present as shown by the esters with mass 75. 相似文献
122.
J A Lewis D C Lommen W D Raddatz J W Dolan L R Snyder I Molnar 《Journal of chromatography. A》1992,592(1-2):183-195
Computer simulation software (DryLab I/mp) is described for predicting high-performance liquid chromatographic separation as a function of changes in mobile phase pH. Three experimental runs with pH (only) varied are used to derive values of pKa plus capacity factors (k') for the ionized and non-ionized form of each ionizable solute. Various tests of the experimental data then allow classification of each solute as acidic, basic, neutral (including strong or weak acids or bases) and amphoteric. Experimental data are reported for the separation of several substituted anilines as a function of pH and solvent composition (%B). Experimental requirements for the accurate prediction of separation (ca. +/- 2-4% in alpha) as a function of pH are discussed. The reliability of the software is demonstrated for three different samples: mixtures of (a) substituted benzoic acids, (b) substituted anilines and (c) catecholamine-related compounds. 相似文献
123.
124.
Larry N. Lewis 《Journal of organometallic chemistry》1982,234(3):355-365
The photoacoustic spectrum (PAS) was measured in the near IR region (1000 to 2600 nm) for organic compounds (C6H6, C6D6, C7H8, and C6H12) and organometallic compounds (Cp2Fe, Cp2Fe2(CO)4, Cp4Fe4(CO)4, Cp4Fe4S4, C6H6Cr(CO)3, CpCo(C4Ph4) and CpCo(CO)2). Band assignments were made by comparison to the infrared spectra. The bands were assigned as the CH overtone stretch and combinations of CH and other IR fundamentals. These bands provide fingerprint spectra for these compounds. 相似文献
125.
Lewis FD 《Photochemistry and photobiology》2005,81(1):65-72
Synthetic DNA conjugates in which one or both ends of a short duplex is capped by a stilbene chromophore have been prepared and characterized crystallographically. Selective excitation of the chromophore can be used to initiate electron transfer processes in which a nucleobase serves as either an electron donor or an electron acceptor. These processes include hole- and electron injection and hole migration. The dynamics of these processes and its dependence on distance, driving force, and base sequence have been investigated by means of femtosecond time-resolved spectroscopy. Duplexes with identical chromophores at both ends have been used to study both the dynamics of electron transfer processes and exciton coupling between the two chromophores by means of circular dichroism spectroscopy. Duplexes with different chromophores can also be used to study distance dependence of both electron transfer and exciton coupling. 相似文献
126.
A high-performance liquid affinity chromatographic method for the purification of serum immunoglobulin A (IgA) using a jacalin column is described. The automated procedure takes about 2 with minimal manipulation. The yields of the isolated IgA and of its IgG and IgM contamination were studied by enzyme-linked immunosorbent assay (ELISA) of 30 sera. Purity was assured by immunoelectrophoresis. The ratio of IgA1 to total IgA was unchanged after purification, as verified by ELISA. The results showed that greater than 90% IgA could be recovered with less than 0.5% total IgG and greater than 2.0% total IgM remaining in the fractions containing purified IgA. 相似文献
127.
David F. V. Lewis 《Journal of computational chemistry》1989,10(2):145-151
Results of molecular orbital (MO) calculations by the complete neglect of differential overlap (CNDO /2) method on 50 small molecules are reported. The summation of calculated atomic polarizabilities are equated with molecular polarizabilities, and these are compared with experimentally determined values. It is found that there is very good agreement between calculated and experimental molecular polarizability. This provides a reliable method for the determination of molecular polarizabilities for compounds for which experimental values are not known. The relationship between log P and polarizability is discussed and analyzed in terms of contributions from electronic components to the partitioning energy. 相似文献
128.
Lewis JR 《Natural product reports》2002,19(2):223-258
This review covers alkaloids classified in the plant families Amaryallidaceae and Sceletium. In addition alkaloids possessing imidazole, oxazole and thiazole structures are listed followed by alkaloids possessing peptide linkages. Finally miscellaneous alkaloids include those compounds found naturally which cannot be classified into known groups; a relative Pandora's box. A total of 620 structures has been reviewed from 218 references found in the literature for the period July 1999 to June 2000. 相似文献
129.
Hamann TW Gstrein F Brunschwig BS Lewis NS 《Journal of the American Chemical Society》2005,127(40):13949-13954
The interfacial energetic and kinetics behavior of n-ZnO/H2O contacts have been determined for a series of compounds, cobalt trisbipyridine (Co(bpy)3(3+/2+)), ruthenium pentaamine pyridine (Ru(NH3)5 py(3+/2+)), cobalt bis-1,4,7-trithiacyclononane (Co(TTCN)2(3+/2+)), and osmium bis-dimethyl bipyridine bis-imidazole (Os(Me2bpy)2(Im)2(3+/2+)), which have similar formal reduction potentials yet which have reorganization energies that span approximately 1 eV. Differential capacitance vs potential and current density vs potential measurements were used to measure the interfacial electron-transfer rate constants for this series of one-electron outer-sphere redox couples. Each interface displayed a first-order dependence on the concentration of redox acceptor species and a first-order dependence on the concentration of electrons in the conduction band at the semiconductor surface, in accord with expectations for the ideal model of a semiconductor/liquid contact. Rate constants varied from 1 x 10(-19) to 6 x 10(-17) cm4 s(-1). The interfacial electron-transfer rate constant decreased as the reorganization energy, lambda, of the acceptor species increased, and a plot of the logarithm of the electron-transfer rate constant vs (lambda + deltaG(o)')(2)/4lambda k(B)T (where deltaG(o)' is the driving force for interfacial charge transfer) was linear with a slope of approximately -1. The rate constant at optimal exoergicity was found to be approximately 5 x 10(-17) cm4 s(-1) for this system. These results show that interfacial electron-transfer rate constants at semiconductor electrodes are in good agreement with the predictions of a Marcus-type model of interfacial electron-transfer reactions. 相似文献
130.
Lawrence JF Niedzwiadek B Menard C Lau BP Lewis D Kuper-Goodman T Carbone S Holmes C 《Journal of AOAC International》2001,84(4):1035-1044
More than 100 samples of blue-green algae products (consisting of Aphanizomenon, Spirulina, and unidentified blue-green algae) in the form of pills, capsules, and powders were collected from retail outlets from across Canada. The samples were extracted with 75% methanol in water and centrifuged to remove solids. Aliquots of the extracts along with spiked blank sample extracts were sent to each participating laboratory and independently analyzed for microcystins by enzyme-linked immunosorbent assay (ELISA), protein phosphatase inhibition assay, and by liquid chromatography-tandem mass spectrometry (LC-MS/MS) after sample cleanup using C18 solid-phase extraction. The results obtained by ELISA and LC-MS/MS agreed very well over a concentration range of about 0.5-35 microg/g. The colorimetric phosphatase results generally agreed with the other 2 methods. While the 2 biochemical assays measured total microcystin content compared with a standard of microcystin LR, the LC-MS/MS method measured specific microcystins (LA, LR, RR, YR) using external standards of these for identification and quantitation. Microcystin LR was found in all positive samples by LC-MS/MS. Microcystin LA was the only other microcystin found in the samples analyzed. These 2 microcystins represent essentially all the microcystins that were present in the extracts. Otherwise, the LC-MS/MS results would have been significantly lower than the results of the biochemical assays had other unknown microcystins been present. 相似文献