基于不同自组装单层的酞菁氧钒薄膜晶体管

研究了不同界面修饰层对酞菁氧钒(VOPc)薄膜晶体管性能的影响。通过AFM图谱分析不同界面修饰层上VOPc薄膜的生长行为,通过半导体参数测试仪测试分析不同界面上器件的电学特性。实验结果表明,十八烷基三氯硅烷(OTS-18)修饰后生长的VOPc薄膜,比正辛基三氯硅烷(OTS-8)和苯基三氯硅烷(PTS)修饰后的薄膜晶体尺寸更大、质量更优;基于OTS-18修饰的底栅顶接触型VOPc有机薄膜晶体管,在4种结构器件中具有最高的场效应迁移率(0.51cm2/V·s),相对于未修饰的器件迁移率提高了近40倍。较长的烷基链能够有效地隔绝VOPc分子和二氧化硅之间的相互作用,利于形成大晶粒尺寸、少缺陷的优质薄膜,获得高迁移率的TFT器件。绝缘层表面自组装单分子层的厚度对其上薄膜的生长行为和相应器件的性能影响极为明显,这一结论对有机半导体薄膜生长和器件制备具有指导意义。     

加速度地震检波器简谐振子有限元分析

介绍简谐振子的工作原理。利用ANSYS软件,采用有限元法创建了简谐振子质量块的实体模型,选择单晶硅作为简谐振子中质量块的材料;设置了模型的材料属性,采用智能分网的方式对模型划分网格,并对质量块模型施加沿x轴水平方向载荷,进行三维的静力分析和模态分析。静力分析得到实体模型的总位移是0.236×10-19μm;模态分析时只对前四阶模型进行了分析,根据其振型图及其总位移的应力云图,得到实体模型的二十阶振动模态的频率是78 001Hz,二十阶的总位移是0.122×10-6μm。     

Efficiently Releasing the Trapped Energy Flow in White Organic Light‐Emitting Diodes with Multifunctional Nanofunnel Arrays

White organic light‐emitting diodes (OLEDs) hold great promise for applications in displays and lighting due to high efficiency and superior white color balance. However, further improvement in efficiency remains a continuous and urgent demand due to limited energy flow extraction. A powerful method for drastically releasing the trapped energy flow in conventional white OLEDs is demonstrated by implementing unique quasi‐periodic subwavelength nanofunnel arrays (NFAs) via soft nanoimprinting lithography, which is ideal for enhancing light extraction without any spectral distortion or angular dependence. The resulting efficiency is over 2 times that of a conventional OLED used as a comparison. The external quantum efficiency and power efficiency are raised to 32.4% and 56.9 lm W^?1, respectively. Besides, the substantial increase in efficiency over a broad bandwidth with angular color stability, the experimental proofs show that the NFA‐based extraction structure affords the enticing capacity against scrubbing and the self‐cleaning feature, which are critical to the commercial viability in practical applications.     

铝合金激光-MIG复合焊接头性能研究

探讨了激光与电弧相互作用后,焊缝中心上部和下部晶粒大小不同的原因,在此基础上研究了焊接速度的改变对6009铝合金接头的微观组织、拉伸性能、显微硬度的影响。结果表明：6009铝合金激光-MIG焊焊接接头的抗拉强度和延伸率随着焊接速度的增加而增加,拉伸试样的断裂位置由焊缝区转移到热影响区,断口呈现均匀分布的韧窝形貌,断裂机制为微孔聚集形断裂;焊缝中心上部晶粒小于焊缝中心下部,而且尺寸分布均匀。焊缝中心上部的显微硬度则高于焊缝下部。接头热影响区存在软化区,宽度为4～6 mm。     

ANALYSIS OF THIOCYANATES BY NMR

Abstract

An unexpected nmr spectrum of β-phenyl ethyl thiocyanate in CDCl₃ solution has led to its analysis in a series of solvents of increasing polarity. Changes in polarity produce increments of ^δAB, transforming the signal from a singlet for 4 methylenic protons to a clear A₂B₂ pattern. Signals appear to split following increasing values of dielectric constants and dipole moments. Rotational isomerism is assumed to be the reason for it since the reaction field parameter depends directly on the dipole moments of rotamers, thus changes in their population affect the reaction field and ultimately the chemical shifts.     

Tautomerism of Diisopropoxyphosphoryl Benzylisothiourea

Abstract

As part of our studies in preparation and physical properties of Potential ligands containing l-phosphoryl(P?O)-3-3-carbonyI(C?X, X?NH, O or S) group, we have investigated the intrdinta molecular hydrogen bonding of diisoproxy- phosphorylquanidine[l] as well as the tautomerism of phosphoryl benzylisothiourea. These are of interest as in interpretation of their chelation behavior as well as in development of other potential ligands for specific metal cations.     

Hexamethylphosphoramide Compounds: II. The Structure of a Complex Containing Two Different Coordination Polyhedra for Two Independent Neodymium(III) Ions

Abstract

The crystal structure of the complex of formula {|Nd(NCS)₃ (HMPA)₃‖ |Nd(NCS)₃ (HMPA)₄|} was determined by three-dimensional X-ray diffraction methods and refined anisotropically to a R=0.040. The compound crystallizes in the trigonal system, space group R3 (No 146), with a=19.947(3), b=19.947(3), c=20.106(3) Å, α=β=90, γ=120°, V=6928(4) ų, M=1891.4, Z=3, D_c=1.360 g cm^?3, λ(MoKα)=0.71073 Å, μ=1.4 cm^?1, F (000)=2922.01. There are two independent Nd³⁺ ions located in the three fold axis. One of them, located at the origin (000) is coordinated to nitrogen atoms of three symmetry related NCS^? anions which are below the (x y) plane (negative z) and also to the oxygen atoms of three symmetry related HMPA groups above that plane. The coordination polyhedron is a slightly distorted octahedron. The other Nd³⁺ ion is located at (00,0.5025(1)). It is coordinated to the nitrogen atoms of three symmetry related NCS^? anions above the (xy 1/2) plane and to oxygen atoms of three symmetry related HMPA groups below that plane. Another HMPA group has the O and P atoms located on the three-fold axis, above the (xy 1/2) plane. The coordination number is in this case 7 and the polyhedron is a capped trigonal antiprism. The mean distances are: Nd-N=2.44 Å, Nd-0=2.35 Å and Nd-N=2.52 Å, Nd-0=2.36 Å for the octahedron and antiprism configurations, respectively. (CNPq, FAPESP, FINEP)     

Isolation,anticholinesterase properties and acute toxicity of the four stereoisomers of the nerve agent soman

Abstract

The four stereoisomers of pinacolyl methylphospho-nofluoridate (soman) were isolated with more than 99% optical purity. The bimolecular rate constants for inhibition of electric eel acetylcholinesterase and the LD₅₀-values (sc, mice) of the stereoisomers were determined.     

CHIRAL VARIANTS OF ARYLALKYL SULFUR REAGENTS. (R)-CAMPHOR KETIMINES OF OGIOVANNA AMINOTHIOETHERS AND OXIDES

Abstract

Ketimines la-d derived from ortho-aminosubstituted phenylthioethers were prepared in order to determine the degree of chirality transfer from the chiral auxiliary to the sulfur atom in the formation of the sulfoxide or to the α-carbon atom in the reaction of the anion with alkyl halides or benzaldehyde. Oxidation to the sulfoxide occurred with little or no asymmetric induction. The crystalline benzyl sulfone 4c was deprotonated by alkyllithium or Grignard reagents and reacted with alkyl halides and benzaldehyde, in all cases with little to fair transfer of chirality. The major diastereoisomer from methylation of the anion of 4c with methyl iodide, was isolated, and afforded the enantiomerically pure amine 5 after removal of the chiral auxiliary. An X-ray structure determination of 4d allowed the assignment of the absolute configuration of the asymmetric carbon and revealed that the conformation of the ketimine in the crystal state is not homogeneous.