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211.
Synthesis, Structure and Conductivity of the New Charge-transfer Salt (ET)_2(CH_2=CH-CH_2-SO_3)·H_2O
Zhi LIU Qi FANG* Wen Tao YU Min Hua JIANG De Qing ZHANG Dao Ben ZHU State Key Laboratory of Crystal Materials Shandong University Jinan Institute of Chemistry The Chinese Academy of Sciences Beijing 《中国化学快报》2003,14(4)
ET is one of the most famous electron-donor molecules, which forms charge-transfer complexes (abbr. CT-complexes) with various types of counterions. These complexes have received intense attention because a wide range of physical properties such as conductivity and superconductivity1, ferromagnetism2-4 and nonlinear optical properties5 was found in these materials. Although the majority of the ET-based CT-complexes were prepared by combining with inorganic counterions, CT-complexes with o… 相似文献
212.
H. Willems A.G.C. Kobussen I.C. Vinke J.H.W. De Wit G.H.J. Broers 《Journal of Electroanalytical Chemistry》1985,194(2):287-303
Open-circuit overpotential decays on an aged cobalt electrode in the oxygen evolution range in 6 M KOH show different slopes for two overpotential regions. These slopes are lower than the Tafel slope in the same region: Tafel slopes of ~100 and ~40 mV/dec, at high and low overpotentials, respectively. compared to decay slopes of ~?60 and ~?20 to ?30 mV/dec. For a fresh cobalt electrode a decay slope of ~?40 mV/dec is found at high overpotentials. From impedance measurements during a decay it is concluded that the electrode capacitance cannot account for the decay curves obsered. By means of steady-state potentiostatic impedance measurements (with stabilization times > 24 h) it is found that the differential Tafel slope remains constant at ~40–50 mV/dec and differs considerably from the Tafel slope at high overpotentials, ~100 mV/dec. Galvanostatic pulse experiments give evidence of the presence of CoO2 in the oxide layer.Two models which may explain the observed experimental results are analysed. Both include a potential-dependent (extra) process which is fixed by the amount of CoO2 at the surface. In one model, CoO2 is responsible for partial surface blockage (parallel process); in the other model, CoO2 controls the conductivity of the top layer of the oxide layer on the electrode. 相似文献
213.
F. Meyer J. Dupré C. Meyer C. Lambeau M. De Vleeschouwer J. -G. Lahaye A. Fayt 《International Journal of Infrared and Millimeter Waves》1982,3(1):83-95
The 5 band of methylacetylene has been studied simultaneously by means of CO2 Laser Stark spectroscopy and high resolution infrared absorption spectroscopy (0.012 cm–1). The primary aim of this work was to assign all the Stark coïncidences. Effective vibration-rotation parameters and the dipole moment of the v5=1 state have been determined. 相似文献
214.
Ligia Bicudo de Almeida Marilene De Vuono Camargo Penteado George Britton Peter Uebelhart Murat Acemoglu Conrad Hans Eugster 《Helvetica chimica acta》1988,71(1):31-32
The 5,6:5′,6′-diepoxy-5,6:5′,6;-tetrahydro-β,β-carotene, isolated from tubers of a white-fleshed variety of sweet potato (Ipomoea batatas LAM .) has been assigned the (5R,6S,5′R,6′S)-chirality on the basis of its HPLC, UV/VIS, and CD data. 相似文献
215.
Miriam Bareket 《Zeitschrift für Angewandte Mathematik und Physik (ZAMP)》1981,32(4):464-469
Let
1 (k)
2 (k) be the eigenvalues of an operator of a certain type depending on a real parameterk. The paper shows that under certain requirements on the operator and on the nature of its dependence onk, the sum
1 (k)++
N
(k) is a concave function ofk, for any positive integerN.
Zusammenfassung Seien 1 (k) 2 (k) die Eigenwerte eines von einem reellen Parameterk abhängigen Operators. Man zeigt, daß unter gewissen Voraussetzungen über den Operator und seine Abhängigkeit vonk die Summe 1 (k)++ N (k) für jedesN eine konkave Funktion vonk ist.相似文献
216.
A conductometric method is proposed for the determination of quaternary ammonium salts (chloride or bromide), based on the poor solubility of the relative perchlorates. A comparison between expected and found values shows that the method is suitable, rapid, and easy for quantities in the range from 0.2 to 5 g. The error depends on the solubility of the relative perchlorate. The apparent and tentative solubility product of the studied compounds were calculated. The obtained values allowed to propose benzyltributyl ammonium chloride (BTBA Cl) as precipitant for the conductometric titration of perchlorate. This easy, rapid and accurate determination can be used to analyze the perchlorate ion even in concentrated solutions and to determine stability constants for complex formation in aqueous solutions. 相似文献
217.
In this work we have studied the stabilizing effect of the lignin, obtained as a by-product of the acid hydrolysis of sugar cane bagasse, herein called sugar cane bagasse lignin, on the thermal and environmental degradation of butadiene rubber. This stabilizer was investigated in various concentrations in the pure form and as a substitute for a hindered phenol, in a commercially used formulation also containing a p-phenylene-diamine. For thermal degradation the stabilization level of the commercial sample is reached with 1·3% of pure lignin and the substitution of the hindered phenol in the commercial formulation increased the stabilization by a factor of 1·2. In the environmental ageing experiments the performance of the rubber stabilized with lignin was poorer than that of the commercial sample. This behaviour is assigned to the strong degradative effect of light on the rubber. 相似文献
218.
De Angelo C. Bossio G. Solsona J. Garcia G.O. Valla M.I. 《Industrial Electronics, IEEE Transactions on》2006,53(2):406-414
A new sensorless scheme for high-performance speed control of permanent-magnet ac motors (PMACMs) driving an unknown load is proposed. This scheme uses an extended nonlinear reduced-order observer to estimate the induced electromotive force (EMF) and load torque. From the estimated variables, the rotor position, the rotor speed, and the position derivative of flux are calculated and are used to close the control loop. In order to improve the drive performance, the estimated load torque is incorporated as a feedforward signal in the closed control loop. In addition, the proposed sensorless PMACM drive allows the torque-ripple and copper-loss minimization for motors with an arbitrary EMF waveform. Simulation and experimental results to validate the proposal are presented in this paper. 相似文献
219.
Simoen E. Eneman G. Verheyen P. Loo R. Kristin De Meyer Claeys C. 《Electron Devices, IEEE Transactions on》2006,53(5):1039-1047
The impact of different processing factors on the low-frequency (LF) noise of nMOSFETs fabricated in strained-silicon (SSi) substrates will be described. It is shown that the use of an SSi substrate can yield improved LF noise performance compared with standard Czochralski silicon material. This is demonstrated for both full-wafer and selective epitaxial SSi material. The lower 1/f noise points to an improved gate oxide quality, i.e., with a lower interface and bulk defect density, and is correlated with the low-field mobility or transconductance of the transistors. At the same time, it will be demonstrated that there exist defect-related LF noise mechanisms, which generally give rise to excess generation-recombination (GR) noise. Associated with this GR noise, a degradation of either the OFF-state leakage current or the mobility (transconductance) of the devices is observed. It is clear that noise is a sensitive parameter to local defectiveness and may be a useful tool for both materials' characterization and the analysis of processing-related device degradation mechanisms. 相似文献
220.
This letter presents an analytical framework of the cell stay time (CST) in wireless LAN environment. CST is an important parameter that can be used to estimate how long a mobile user will stay in a particular cell and how many cells he will probably visit during his call holding time. CST can be also used to make predictive advanced reservations. A probability density function (p.d.f.) of the CST is obtained and an analytical expression of its main parameters such as the average and standard deviation values is outlined as a function of the average mobile user speed and cell radius 相似文献