Solid state kinetics of Cu(II) complex of [2-(1,2,3,4-thiatriazole-5-yliminomethyl)-phenol] from thermo gravimetric analysis

The ligand [2-(1,2,3,4-thiatriazole-5-yliminomethyl)-phenol] (L) is a schiff base derived from condensation reaction of 1,2,3,4-thiatriazole-5-ylamine and Salicylaldehyde. Synthesis of the ligand (L) and the complex [Cu(II)(L)₂]·2H₂O have been studied in our previous work (Bharti et al., Asian J Chem 23(2):773–776, 2011). Thermal decomposition behavior of synthesized Cu(II) complex has been investigated by thermo gravimetric (TG) analysis at heating rate of 10 °C min⁻¹ under nitrogen atmosphere. The mechanism of decomposition of Cu(II) complex has been established from TG data. Kinetic parameters such as order of reaction (n), activation energy (E _a), frequency factor (Z) and entropy of activation (∆S ^≠) were calculated by using Freeman and Carroll (J Phys Chem 62:394–397, 1958) as well as Doyle’s methods as modified by Zsako (J Phys Chem 72(7):2406–2411, 1968).     

Electric and electrochemical properties of solid LiH2PO4

Electrical and electrochemical properties of solid LiH₂PO₄ conductor were investigated in the temperature range from room temperature to 373 K. It was found that high conductivity throughout the temperature range, with activation energy 17.23 kJ/mol, originates from the movement of hydrogen ions (protons). The movement of protons in the correlation with phosphate groups rotation was considered. The slopes of Tafel lines and exchange current densities both for cathodic hydrogen and anodic oxygen evolution were determined (by means of usual electrochemical kinetic methods) at various temperatures. The energy of activation at the equilibrium potentials both for the cathodic and the anodic processes have been assessed to be 17.23 kJ/mol (0.18 eV) and 2.9 kJ/mol (0.03 eV), respectively.     

Titration of L-cysteine hydrochloride with standard nickel sulphate solution employing 1-(pyridyl-2′-azo)-naphthol-(2) as indicator

The estimation of cysteine hydrochloride can be carried out quantitatively against standard nickel sulphate solution using 1-(pyridyl-2′-azo)-naphthol-(2) in carbonate-bicarbonate buffer medium of pH 10.0. Other natural amino acids have no interference with the titration.     

D.C. electrical,optical and photoelectrical properties of GexTe1−x amorphous thin films

We give the main results of measurements on Ge_xTe_1?x(x = 0.5, 0.4, 0.3, 0.2, 0.1) amorphous alloys: variation of activation energy, conductivity, optical absorption, and μτ with composition. The striking features are that quantum efficiency is independent of photon energy and that shallow traps exist whose density increases with germanium content.     

Temporal order discrimination of tonal sequences by younger and older adults: the role of duration and rate

The effect of tone duration and presentation rate on the discrimination of the temporal order of the middle two tones of a four-tone sequence was investigated in young normal-hearing (YNH) and older hearing-impaired (OHI) listeners. The frequencies and presentation level of the tone sequences were selected to minimize the effect of hearing loss on the performance of the OHI listeners. Tone durations varied from 20 to 400 ms and presentation rates from 2.5 to 25 toness. Two experiments were conducted with anisochronous (nonuniform duration and rate across entire sequence) and isochronous (uniform rate and duration) sequences, respectively. For the YNH listeners, performance for both isochronous and anisochronous sequences was determined primarily by presentation rate such that performance decreased at rates faster than 5 toness. For anisochronous tone sequences alone, the effects of rate were more pronounced at short tone durations. For the OHI listeners, both presentation rate and tone duration had an impact on performance for both isochronous and anisochronous sequences such that performance decreased as rate increased above 5 toness or duration decreased below 40 ms. Temporal masking was offered as an explanation for the interaction of short durations and fast rates on temporal order discrimination for the anisochronous sequences.     

Synthesis of novel ferrocene-containing 1,3-thiazinan-2-imines: One-pot reaction promoted by ultrasound irradiation

A simple one-pot synthesis of new ferrocene-containing 1,3-thiazinan-2-imines from 3-arylamino-1-ferrocenylpropan-1-ols and phenyl isothiocyanate has been developed. The key intermediate β-hydroxy thioureas were generated in situ using ultrasound irradiation and subsequent cyclization was achieved by the addition of acetic acid. The scope of the reaction towards various 3-arylamino-1-ferrocenylpropan-1-ols has been explored and the corresponding 3-aryl-6-ferrocenyl-N-phenyl-1,3-thiazinan-2-imines were obtained in moderate to high yields (52–90%).     

Syntheses,characterizations, crystal structures,antibacterial and SOD-like activities of nickel(II) and copper(II) complexes with 2-((Z)-(4-methoxyphenylimino)methyl)-4,6-dichlorophenol

Three mononuclear nickel(II) and copper(II) complexes, [Ni(L)₂(py)₂] (1), [Ni(L)₂(DMF)(H₂O)] (2), and [Cu(L)₂] (3), where HL = 2-((Z)-(4-methoxyphenylimino)methyl)-4,6-dichlorophenol, py = pyridine and DMF = N,N-dimethylformamide, have been synthesized and their structures determined by single crystal X-ray analysis. Complexes 1–3 crystallized in the monoclinic system of the space groups C2/c, P2_1/n, and P2_1/c, respectively. The crystal structures of 1 and 2 present an octahedral geometry at the metal center and 3 shows a square-planar geometry. The FT-IR spectra, UV–vis spectra, and magnetic susceptibility measurements agree with the observed crystal structures. EPR spectra indicate a d_x2–y2 ground state (g_|| > g_⊥ > 2.0023 and A_|| > A_⊥) for 3 at RT and LNT. The results of simultaneous TG-DTA analyses of 1 and 3 showed the final degradation products are NiO for 1 and CuO for 3. The Schiff base (HL) behaves as monobasic bidentate ligand possessing N and O donor atoms. Electrochemical properties for the complexes are similar and involve two irreversible redox processes. Complex 3 exhibits the ability to inhibit jack bean urease, although its Schiff base has no ability to inhibit urease. Complex 1 exhibits more active scavenging effects against O₂^? than HL, 2 and 3 under the same conditions. Antibacterial screening activities of these complexes were also investigated.     

An efficient algorithm for backbone construction in cognitive radio networks

Numerous research articles exist for backbone formation in wireless networks; however, they cannot be applied straightforward in cognitive radio network (CRN) due to its peculiar characteristics. Since virtual backbone has many advantages such as reduced routing overhead, dynamic maintenance, and fast convergence speed, we intend to propose a backbone formation protocol in CRN. In this paper, we propose a tree‐based backbone formation protocol along with its maintenance. Our protocol is based on non‐iterative approach, thus leading towards limited message overhead and faster convergence speed. The proposed algorithm first forms the tree by maintaining the parent‐child relationship, and second, the parent nodes are connected together to form the virtual backbone. In the end, we evaluate the performance our protocol through extensive simulations.     

Efficiency enhancement for indirect vector-controlled induction motor drive

In this paper, efficiency enhancement algorithms are developed and implemented on an indirect vector-controlled three-phase induction motor (IM) drive, and its performance under different operating conditions is analysed. The controllable electrical losses in the IM are minimised through the optimal control of direct axis (d-axis) stator current, and improvement in motor efficiency is achieved by weakening the rotor flux. The optimal d-axis stator current is also estimated using particle swarm optimisation (PSO) to validate the results obtained through analytical control method. The developed algorithms are tested under various operating conditions and the dynamic performance of the IM drive is analysed. The effectiveness of analytical and PSO-based efficiency optimisation control over conventional constant flux control, especially during light load at rated speed operation, is summarised. The effectiveness of the developed algorithm is validated experimentally through development of laboratory prototype set-up. The effect of parametric variation on efficiency, stator current, torque and speed of IM drive is studied through sensitivity analysis. The effect of variation in stator and rotor resistance due to change in operating temperature of the IM is also analysed and the robustness of the developed algorithm against parametric variations is demonstrated through simulation and experimental studies.     

Clustering‐based resource discovery on Internet‐of‐Things

Resource discovery on Internet‐of‐Things paradigm is an eminent challenge due to data‐specific activities with respect to foraging and sense‐making loops. The prerequisite to deal with the challenge is to process and analyze the data that require resources to be indexed, ranked, and stored in an efficient manner. A novel clustering technique is proposed to resolve the specified challenge. The technique, namely, iterative k‐means clustering algorithm, targets concrete cluster formation using similarity coefficients of vector space model and performs efficient search against matching criteria with respect to complexity. It is simulated on MATLAB, and the obtained results are compared with fuzzy k‐means and fuzzy c‐means clustering algorithm with similarity coefficients of vector space model against exponential increase in the number of resources.