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31.
Mikko Waltari Lauri Sumanen Tuomas Korhonen Kari A. I. Halonen 《Analog Integrated Circuits and Signal Processing》2003,37(3):201-213
A 13-bit, 50-MS/s pipeline ADC with IF-sampling capability is presented. A high sampling linearity is obtained through the use of bootstrapped switches. A digital self-calibration algorithm with modified capacitor measurement scheme is employed to improve the accuracy of the first two pipeline stages. The prototype, implemented with a 0.35-m BiCMOS (SiGe) technology, shows a 76.5-dB SFDR at a 194.2-MHz signal frequency and dissipates 715 mW power from a 2.9-V supply. 相似文献
32.
In this paper, we propose an architecture for secure push services for mobile users that supports common-of-the-shelf (COTS) WLAN base stations. The architecture focuses on the creation of flexible access networks based on easily deployable base stations. The push functionality is realized using client-initiated connections with SIP, and TLS or dTLS for security. The central building block of the distributed system is the edge proxy, which manages and implicitly authenticates all inbound connections, and performs privacy enhancement. The main driving force of our architecture has been airline services, but the system is applicable also for other service domains. 相似文献
33.
This paper studies particle propagation in a one-dimensional inhomogeneous medium where the laws of motion are generated by chaotic and deterministic local maps. Assuming that the particle’s initial location is random and uniformly distributed, this dynamical system can be reduced to a random walk in a one-dimensional inhomogeneous environment with a forbidden direction. Our main result is a local limit theorem which explains in detail why, in the long run, the random walk’s probability mass function does not converge to a Gaussian density, although the corresponding limiting distribution over a coarser diffusive space scale is Gaussian. 相似文献
34.
Aino J. Karhu Juho Jämsä J. Mikko Rautiainen Raija Oilunkaniemi Tristram Chivers Risto S. Laitinen 《无机化学与普通化学杂志》2017,643(7):495-500
The reaction of tBuNH2 with a mixture of SeCl2 and SeOCl2 in a 6:2:1 molar ratio produces the novel selenium‐nitrogen chain ClSeN(tBu)Se(O)Cl ( 4 ), in which the selenium atoms are in two different oxidation states, SeII and SeIV. The crystal structure of 4 is compared with that of the related SeII/SeII system ClSeN(tBu)SeCl ( 1 ) and differences are attributed to hyperconjugative effects. The energetics of the formation of 4 via two different routes are elucidated by PBE0/def2‐TZVPP calculations. 相似文献
35.
We apply time-dependent density functional theory to study the valence electron excitations of molecules and generalize the typically used time-propagation scheme and Casida's method to calculate the full wavevector dependent response function. This allows the computational study of dipole-forbidden valence electron transitions and the dispersion of spectral weight as a function of the wavevector. The method provides a novel analysis tool for spectroscopic methods such as inelastic x-ray scattering and electron energy loss spectroscopy. We present results for benzene and CF(3)Cl and make a comparison with experimental results. 相似文献
36.
Vladimir A. Sivakov Dr. Katja Höflich Michael Becker Dr. Andreas Berger Dr. Thomas Stelzner Dr. Kai‐Erik Elers Dr. Viljami Pore Dr. Mikko Ritala Prof. Dr. Silke H. Christiansen Dr. 《Chemphyschem》2010,11(9):1995-2000
A new method to prepare plasmonically active noble metal nanostructures on large surface area silicon nanowires (SiNWs) mediated by atomic layer deposition (ALD) technology has successfully been demonstrated for applications of surface‐enhanced Raman spectroscopy (SERS)‐based sensing. As host material for the plasmonically active nanostructures we use dense single‐crystalline SiNWs with diameters of less than 100 nm as obtained by a wet chemical etching method based on silver nitrate and hydrofluoric acid solutions. The SERS active metal nanoparticles/islands are made from silver (Ag) shells as deposited by autometallography on the core nanoislands made from platinum (Pt) that can easily be deposited by ALD in the form of nanoislands covering the SiNW surfaces in a controlled way. The density of the plasmonically inactive Pt islands as well as the thickness of noble metal Ag shell are two key factors determining the magnitude of the SERS signal enhancement and sensitivity of detection. The optimized Ag coated Pt islands on SiNWs exhibit great potential for ultrasensitive molecular sensing in terms of high SERS signal enhancement ability, good stability and reproducibility. The plasmonic activity of the core‐shell Pt//Ag system that will be experimentally realized in this paper as an example was demonstrated in numerical finite element simulations as well as experimentally in Raman measurements of SERS activity of a highly diluted model dye molecule. The morphology and structure of the core‐shell Pt//Ag nanoparticles on SiNW surfaces were investigated by scanning‐ and transmission electron microscopy. Optimized core–shell nanoparticle geometries for maximum Raman signal enhancement is discussed essentially based on the finite element modeling. 相似文献
37.
Armentano A Riese M Taherkhani M Ben Yezzar M Müller-Dethlefs K Fujii M Dopfer O 《The journal of physical chemistry. A》2010,114(42):11139-11143
The various dissociation thresholds of phenol(+)···Ar(3) complexes for the consecutive loss of all three Ar ligands were measured in a molecular beam using resonant photoionization efficiency and mass analyzed threshold ionization spectroscopy via excitation of the first excited singlet state (S(1)). The adiabatic ionization energy is derived as 68077 ± 15 cm(-1). The analysis of the dissociation thresholds demonstrate that all three Ar ligands in the neutral phenol···Ar(3) tetramer are attached to the aromatic ring via π-bonding, denoted phenol···Ar(3)(3π). The value of the dissociation threshold for the loss of one Ar ligand from phenol(+)···Ar(3)(3π), ~190 cm(-1), is significantly lower than the binding energy measured for the π-bonded Ar ligand in the phenol(+)···Ar(π) dimer, D(0) = 535 ± 3 cm(-1). This difference is rationalized by an ionization-induced π → H isomerization process occurring prior to dissociation, that is, one Ar atom in phenol(+)···Ar(3)(3π) moves to the OH binding site, leading to a structure with one H-bonded and 2 π-bonded ligands, denoted phenol(+)···Ar(3)(H/2π). The dissociation thresholds for the loss of two and three Ar atoms are also reported as 860 and 1730 cm(-1). From these values, the binding energy of the H-bound Ar atom can be estimated as 870 cm(-1). 相似文献
38.
In the first editorial of this two-part special issue, we pointed out that one of the biggest trends in wireless broadband, radar, sonar, and broadcasting technology is software RF processing and digital front-end [1]. This 相似文献
39.
Tanja Seraidaris Arto Puranen Mikko Karesoja Barbro Lfgren Timo Repo Markku Leskel Jukka Seppl 《Journal of polymer science. Part A, Polymer chemistry》2006,44(16):4743-4751
Elastic polypropene has gained growing industrial and academic interest as a thermoplastic elastomer. In this study, “rac”‐ and “meso”‐dimethylsilyl(3‐benzylindenyl)(2‐methylindenyl)hafnium dichloride complexes (Hfr and Hfm, respectively), activated with [NHMe2Ph][B(C6F5)4]/triisobutyl aluminum, were used in propene polymerization. Using these catalyst systems, we obtained polymers with high molar masses, up to 550 kg/mol, and moderate isotacticities between 34 and 52%. By varying the polymerization conditions, we could modify the polymer microstructure and molar mass. 13C NMR was used to calculate the polymer pentad sequence distributions. The crystalline parts of the polymers were analyzed with the differential scanning calorimetry successive self‐nucleation and annealing (SSA) technique. The SSA thermograms revealed that Hfr produced polypropene with a more uniform lamellar structure than Hfm. The mechanical properties were tested with dynamic mechanical analysis creep‐recovery tests. In the series, the polymers with the lowest isotacticities and therefore lowest crystallinities showed the best elastic properties. © 2006 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 44: 4743–4751, 2006 相似文献
40.
We show that a trader, who starts with no initial wealth and is not allowed to borrow money or short sell assets, is theoretically able to attain positive wealth by continuous trading, provided that she has perfect foresight of future asset prices, given by a continuous semimartingale. Such an arbitrage strategy can be constructed as a process of finite variation that satisfies a seemingly innocuous self-financing condition, formulated using a pathwise Riemann–Stieltjes integral. Our result exemplifies the potential intricacies of formulating economically meaningful self-financing conditions in continuous time, when one leaves the conventional arbitrage-free framework. 相似文献