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121.
In this article we compare different force fields that are widely used (Gromacs, Charmm-22/x-Plor, Charmm-27, Amber-1999, OPLS-AA) in biophysical simulations containing aqueous NaCl. We show that the uncertainties of the microscopic parameters of, in particular, sodium, and, to a lesser extent, chloride, translate into large differences in the computed radial-distribution functions. This uncertainty reflect the incomplete experimental knowledge of the structural properties of ionic aqueous solutions at finite molarity. We discuss possible implications on the computation of potential of mean force and effective potentials. 相似文献
122.
Linnolahti M Luhtanen TN Pakkanen TA 《Chemistry (Weinheim an der Bergstrasse, Germany)》2004,10(23):5977-5987
Alumina nanostructures and three families of aluminoxanes, linear, cyclic, and cagelike structures, have structures that resemble their isovalent electronic hydrocarbon analogues. Specific examples of each family are the counterparts of fullerene, allene, benzene, and cubane, respectively. The aluminoxanes and alumina nanostructures are related to each other; the latter can be regarded as a hydrogen- or alkyl-free form of aluminoxane. By exploiting this relationship, the relative stabilities of the three families of aluminoxanes, alumina nanostructures, and alumina crystal lattices have been estimated. According to ab initio calculations, aluminoxane cages, which take the form of a truncated octahedron and related polyhedra, are favored. The stability of the preferred cage, T-symmetric Al28O28H28, is practically equal to that of the alpha-alumina crystal lattice. 相似文献
123.
Mikko K?rkk?inen Mikko Varonen Pekka Kangaslahti Kari Halonen 《Analog Integrated Circuits and Signal Processing》2004,42(1):37-46
Wide frequency bandwidth has been internationally allocated for unlicensed operation around the oxygen absorption frequency at 60 GHz. A power amplifier and a low noise amplifier are presented as building blocks for a T/R-unit at this frequency. The fabrication technology was a commercially available 0.15 m gallium arsenide (GaAs) process featuring pseudomorphic high electron mobility transistors (PHEMT). Using on-wafer tests, we measured a gain of 13.4 dB and a +17 dBm output compression point for the power amplifier at 60 GHz centre frequency when the MMIC was biased to 3 volts Vdd. At the same frequency, the low noise amplifier exhibited 24 dB of gain with a 3.5 dB noise figure. The AM/AM and AM/PM characteristics of the power amplifier chip were obtained from the large-signal S-parameter measurement data. Furthermore, the power amplifier was assembled in a split block package, which had a WR-15 waveguide interface in input and output. The measured results show a 12.5 dB small-signal gain and better than 8 dB return losses in input and output for the packaged power amplifier. 相似文献
124.
Mathematische Zeitschrift - This paper concerns harmonic analysis of the Ornstein–Uhlenbeck operator L on the Euclidean space. We examine the method of decomposing a spectral multiplier... 相似文献
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Eeva Heliövaara Henri Liljeqvist Dr. Mikko Muuronen Aleksi Eronen Karina Moslova Prof. Timo Repo 《Chemistry (Weinheim an der Bergstrasse, Germany)》2021,27(34):8668-8672
Development of new, environmentally benign dissolution methods for metallic gold is driven by needs in the circular economy. Gold is widely used in consumer electronics, but sustainable and selective dissolution methods for Au are scarce. Herein, we describe a quantitative dissolution of gold in organic solution under mild conditions by using hydrogen peroxide as an oxidant. In the dissolution reaction, two thiol ligands, pyridine-4-thiol and 2-mercaptobenzimidazole, work in a cooperative manner. The mechanistic investigations suggest that two pyridine-4-thiol molecules form a complex with Au0 that can be oxidized, whereas the role of inexpensive 2-mercaptobenzimidazole is to stabilize the formed AuI species through a ligand exchange process. Under optimized conditions, the reaction proceeds vigorously and gold dissolves quantitatively in two hours. The demonstrated ligand-exchange mechanism with two thiols allows to drastically reduce the thiol consumption and may lead to even more effective gold dissolution methods in the future. 相似文献
128.
Mona Aghababaeetafreshi Lasse K. Lehtonen Toni Levanen Mikko Valkama Jarmo Takala 《Journal of Signal Processing Systems》2016,85(1):167-182
Wireless standards are evolving rapidly due to the exponential growth in the number of portable devices along with the applications with high data rate requirements. Adaptable software based signal processing implementations for these devices can make the deployment of the constantly evolving standards faster and less expensive. The flagship technology from the IEEE WLAN family, the IEEE 802.11ac, aims at achieving very high throughputs in local area connectivity scenarios. This article presents a software based implementation for the Multiple Input and Multiple Output (MIMO) transmitter and receiver baseband processing conforming to the IEEE 802.11ac standard which can achieve transmission bit rates beyond 1Gbps. This work focuses on the Physical layer frequency domain processing. Various configurations, including 2×2 and 4×4 MIMO are considered for the implementation. To utilize the available data and instruction level parallelism, a DSP core with vector extensions is selected as the implementation platform. Then, the feasibility of the presented software-based solution is assessed by studying the number of clock cycles and power consumption of the different scenarios implemented on this core. Such Software Defined Radio based approaches can potentially offer more flexibility, high energy efficiency, reduced design efforts and thus shorter time-to-market cycles in comparison with the conventional fixed-function hardware methods. 相似文献
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Ruusunen Jarno Ihalainen Mika Koponen Tarmo Torvela Tiina Tenho Mikko Salonen Jarno Sippula Olli Joutsensaari Jorma Jokiniemi Jorma Lähde Anna 《Journal of nanoparticle research》2014,16(2):1-11
Enteric-coated formulations can delay the release of drugs until they have passed through the stomach. However, high concentration of drugs caused by rapidly released in the small intestine leads to the intestinal damage, and frequent administration would increase the probability of missing medication and reduce the patient compliance. To solve the above-mentioned problems, aspirin-loaded enteric-coated sustained-release nanoparticles with core–shell structure were prepared via one-step method using coaxial electrospray in this study. Eudragit L100-55 as pH-sensitive polymer and Eudragit RS as sustained-release polymer were used for the outer coating and inner core of the nanoparticles, respectively. The maximum loading capacity of nanoparticles was 23.66 % by changing the flow rate ratio of outer/inner solutions, and the entrapment efficiency was nearly 100 %. Nanoparticles with core–shell structure were observed via fluorescence microscope and transmission electron microscope. And pH-sensitive and sustained drug release profiles were observed in the media with different pH values (1.2 and 6.8). In addition, mild cytotoxicity in vitro was detected, and the nanoparticles could be taken up by Caco-2 cells within 1.0 h in cellular uptake study. These results indicate that prepared enteric-coated sustained-release nanoparticles would be a more safety and effective carrier for oral drug delivery. 相似文献