Rheological and thermal properties of agarose aqueous solutions and hydrogels

In this article, we report on the rheological properties of agarose aqueous solutions and gels. Viscosity curves were determined for homogeneous agarose aqueous solutions at different temperatures (from 68 to 38 °C) to study the viscosity behavior as the systems undergo gelation. The gelation phenomenon of agarose solutions was also investigated by shear oscillation experiments and differential scanning calorimetry. The gelation and melting temperature as a function of agarose concentration were determined together with the gelation and melting enthalpies. The results obtained were interpreted using the two‐step model describing the gelation of agarose in water. © 2007 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 46: 322–328, 2008     

A measurement of the proton structure functions from neutrino-hydrogen and antineutrino-hydrogen charged-current interactions

Within the framework of the quark-parton model, the quark and anti-quark structure functions of the proton have been measured by fitting them to the distributions of the events in the Bjorkeny variable. The data used form the largest sample of neutrino and antineutrino interactions on a pure hydrogen target available, and come from exposures of BEBC to the CERN wide band neutrino and antineutrino beams. It is found that the ratiod _v /u _v of valence quark distributions falls with increasing Bjorkenx. In the context of the quark-parton model the results constrain the isospin composition of the accompanying diquark system. Models involving scattering from diquarks are in disagreement with the data.     

Stable gravity wave of arbitrary amplitude in finite depth

A combination and modification of two existing methods, which involves balancing static and dynamic pressure differences between points along the surface and conserving mass through cross sections below the surface in the reference frame moving with the phase velocity, is applied to surface gravity waves of arbitrary amplitude in water of finite depth. For a given still water depth and wave height the method determines in closed form the phase velocity, wavelength, and wave profile of the stable wave. The main assumption is that the horizontal component of the fluid velocity be independent of depth. The motion is not assumed to be irrotational. The wavelength of the stable wave is found to be about 3.6 times the still water depth for infinitesimal amplitude, and at finite amplitude the wavelength decreases as the amplitude increases. Therefore, shallow water waves are concluded to be unstable even at infinitesimal amplitude, for which the assumption is accurate. Previously it has been argued that only at finite amplitude will shallow water waves change form as they propagate. The wave profile is found to be sinusoidal for infinitesimal amplitude and to be asymmetric at finite amplitude, the crests being higher and narrower and the troughs shallower and broader. These results are consistent with well-known theoretical work and laboratory measurements.     

Small cliques in random graphs

For d ≥ 1, a d-clique in a graph G is a complete d-vertex subgraph not contained in any larger complete subgraph of G. We investigate the limit distribution of the number of d-cliques in the binomial random graph G(n, p), p = p(n), n→∞.     

Zur Analyse der Legirungen

Ohne Zusammenfassung     

Pharmazeutische Pr?parate

Ohne Zusammenfassung     

Reaction of 3-chloroquinoline-2,4-diones with ethanolamine and rearrangement of the reaction products

The reaction of tertiary α-chloroketones with ethanolamine has not been hitherto described in the literature. Herein, we describe the reaction of tertiary 3-chloroquinoline-2,4-diones with ethanolamine to give novel 3-(2-hydroxyethylamino)quinoline-2,4-diones. These compounds provide 3-(2-oxooxazolidin-3-yl)quinoline-2,4(1H,3H)-diones and new compounds with dimeric character after reaction with triphosgene. Molecular rearrangement proceeds during the reaction of 3-(2-hydroxyethylamino)quinoline-2,4-diones with isocyanic acid. Three types of reaction products arise: 2-(2-hydroxyethyl)imidazo[1,5-c]quinazoline-3,5-diones, 3-(2-hydroxyethyl)-3,3a-dihydro-2H-imidazo[4,5-]quinoline-4(5H)diones and primarily 5-hydroxy-1-(hydroxyethyl)-1′H-spiro[imidazolidine-5,3′-indole]-2,2′-diones. The reaction mechanism and product stereochemistry are discussed. The ¹H, ¹³C and ¹⁵N NMR spectra of the prepared compounds were measured, and all resonances were assigned from appropriate two-dimensional experiments.