全文获取类型
收费全文 | 314篇 |
免费 | 47篇 |
国内免费 | 26篇 |
专业分类
化学 | 198篇 |
晶体学 | 3篇 |
力学 | 18篇 |
综合类 | 6篇 |
数学 | 20篇 |
物理学 | 41篇 |
无线电 | 101篇 |
出版年
2024年 | 5篇 |
2023年 | 21篇 |
2022年 | 23篇 |
2021年 | 46篇 |
2020年 | 32篇 |
2019年 | 43篇 |
2018年 | 17篇 |
2017年 | 21篇 |
2016年 | 37篇 |
2015年 | 26篇 |
2014年 | 27篇 |
2013年 | 20篇 |
2012年 | 23篇 |
2011年 | 9篇 |
2010年 | 9篇 |
2009年 | 7篇 |
2008年 | 2篇 |
2007年 | 4篇 |
2006年 | 4篇 |
2005年 | 1篇 |
2004年 | 2篇 |
2001年 | 2篇 |
1999年 | 1篇 |
1994年 | 1篇 |
1990年 | 2篇 |
1979年 | 1篇 |
1959年 | 1篇 |
排序方式: 共有387条查询结果,搜索用时 234 毫秒
61.
Spatially Separated CdS Shells Exposed with Reduction Surfaces for Enhancing Photocatalytic Hydrogen Evolution 下载免费PDF全文
Mingyang Xing Bocheng Qiu Mengmeng Du Qiaohong Zhu Lingzhi Wang Jinlong Zhang 《Advanced functional materials》2017,27(35)
To the photocatalytic H2 evolution, the exposure of a reduction surface over a catalyst plays an important role for the reduction of hydrogen protons. Here, this study demonstrates the design of a noble‐metal‐free spatially separated photocatalytic system exposed with reduction surfaces (MnOx @CdS/CoP) for highly solar‐light‐driven H2 evolution activity. CoP and MnOx nanoparticles are employed as the electron and hole collectors, which are selectively anchored on the outer and inner surface of CdS shells, respectively. Under solar light irradiation, the photogenerated holes and electrons can directionally move to the MnOx and CoP, respectively, leading to the exposure of a reduction surface. As a result, the H2 evolution increases from 32.0 to 238.4 µmol h?1, which is even higher than the activity of platinum‐loaded photocatalyst (MnOx @CdS/Pt). Compared to the pure CdS with serious photocorrosion, the MnOx @CdS/CoP maintains a changeless activity for the H2 evolution and rhodamine B degradation, even after four cycles. The research provides a new strategy for the preparation of spatially separated photocatalysts with a selective reduction surface. 相似文献
62.
Dr. Huanhuan Shi Prof. Mengmeng Li Shuai Fu Dr. Christof Neumann Dr. Xiaodong Li Dr. Wenhui Niu Yunji Lee Prof. Mischa Bonn Dr. Hai I. Wang Prof. Andrey Turchanin Dr. Ali Shaygan Nia Dr. Sheng Yang Prof. Xinliang Feng 《Angewandte Chemie (International ed. in English)》2023,62(28):e202303929
Two-dimensional van der Waals heterostructures (2D vdWHs) have recently gained widespread attention because of their abundant and exotic properties, which open up many new possibilities for next-generation nanoelectronics. However, practical applications remain challenging due to the lack of high-throughput techniques for fabricating high-quality vdWHs. Here, we demonstrate a general electrochemical strategy to prepare solution-processable high-quality vdWHs, in which electrostatic forces drive the stacking of electrochemically exfoliated individual assemblies with intact structures and clean interfaces into vdWHs with strong interlayer interactions. Thanks to the excellent combination of strong light absorption, interfacial charge transfer, and decent charge transport properties in individual layers, thin-film photodetectors based on graphene/In2Se3 vdWHs exhibit great promise for near-infrared (NIR) photodetection, owing to a high responsivity (267 mA W−1), fast rise (72 ms) and decay (426 ms) times under NIR illumination. This approach enables various hybrid systems, including graphene/In2Se3, graphene/MoS2 and graphene/MoSe2 vdWHs, providing a broad avenue for exploring emerging electronic, photonic, and exotic quantum phenomena. 相似文献
63.
An easy method to prepare solid phase microextraction fibers by introducing an inorganic binder was demonstrated in this study, where MoS2 was selected as the extraction phase material because of its graphite-like layered structure with large specific adsorption area and good stability, and was then adhered to a stainless steel wire by acid aluminum phosphate binder with the spraying method. The as-prepared solid phase microextraction fiber coupled with gas chromatography was then used to extract some polycyclic aromatic hydrocarbons target analytes including the low-volatile benzo(a)pyrene etc. from a standard sample. Comparing with the MoS2-epoxy resin and commercial polyacrylate fibers, the MoS2-acid aluminum phosphate fiber has a higher thermal stability because of highly thermal stable acid aluminum phosphate, which is durable for a long service life at a high temperature (320 °C), and has the advantage in the extraction of low-volatility analytes. After the optimization of adsorption and desorption factors (ionic strength, adsorption time and temperature, and desorption temperature), method detection limits of <0.1 μg L−1 were achieved, and the calibration curves were all linear (R2 ≥ 0.9981) within the range of 0.1–100 μg L−1. The satisfying repeatability was also achieved, the RSD values of single-fiber were 3.49–5.81%, and the ones of fiber-to-fiber were 5.32–7.22%. As a result, the present fiber with good thermal stability can work at high temperature for a long service life, which is useful for the detection of low-volatility target analytes in practical applications. 相似文献
64.
研究一类具有分数阶线性微分算子的非线性微分方程积分边值问题解的存在性与唯一性.利用Schauder不动点定理及压缩映射原理,建立并证明了边值问题解的存在性定理和唯一性定理,并给出两个例子以说明所得结论. 相似文献
65.
Jingjing Yu Daxiang Liu Zhenyu Ding Yanan Yuan Jiayuan Zhou Fangfang Pei Haolin Pan Tianping Ma Feng Jin Lingfei Wang Wenguang Zhu Shouguo Wang Yizheng Wu Xue Liu Dazhi Hou Yang Gao Ziqiang Qiu Mengmeng Yang Qian Li 《Advanced functional materials》2024,34(2):2307259
The advent of van der Waals (vdW) ferromagnetic (FM) and antiferromagnetic (AFM) materials offers unprecedented opportunities for spintronics and magneto-optic devices. Combining magnetic Kerr microscopy and density functional theory calculations, the AFM-FM transition is investigated and a surprising abnormal magneto-optic anisotropy in vdW CrSBr associated with different magnetic phases (FM, AFM, or paramagnetic state) is discovered. This unique magneto-optic property leads to different anisotropic optical reflectivity from different magnetic states, permitting direct imaging of the AFM Néel vector orientation and the dynamic process of the AFM-FM transition within a magnetic field. Using Kerr microscopy, not only the domain nucleation and propagation process is imaged but also the intermediate spin-flop state in the AFM-FM transition is identified. The unique magneto-optic property and clear identification of the dynamics process of the AFM-FM phase transition in CrSBr demonstrate the promise of vdW magnetic materials for future spintronic technology. 相似文献
66.
大花无柱兰是一种珍稀兰科植物,具有一定的观赏和药用价值,但数量十分稀少,该物种亟待保护。本研究采用SRAP分子标记技术,对10个居群的115份DNA样品进行PCR扩增,并开展遗传多样性分析。从81对引物中筛选出9个条带清晰、多态性好、重复性高的引物组合,共扩增得到305条谱带。在物种水平上,多态性比率(PPB)为100%,Nei’s基因多样性指数(H )为0.209 8,Shannon’s指数(I )为0.340 2;在居群水平上,PPB为24.59%~52.13%,H 为0.079 6~0.165 5,I 为0.120 9~0.252 3。居群水平上,基因分化度(Gst)为0.520 9,基因流(Nm)为0.459 9,遗传距离为0.091 9~0.198 4。UPGMA聚类结果表明,10个居群可分为3大类,地理距离相近的居群优先聚集。大花无柱兰的遗传多样性较为丰富,居群间存在一定的遗传分化和基因交流,可采用就地保护和人工栽培等方式加以保护。 相似文献
67.
通过在线跟踪水滴在凹槽状聚二甲基硅氧烷(PDMS)基底上的挥发行为, 研究了蒸馏水的挥发规律Cassie-Wenzel转变行为. 结果表明, 初始阶段, 水滴处于Cassie状态, 且在垂直于凹槽方向(V)和平行于凹槽方向(P)上存在显著的各向异性. 水滴的挥发过程依次表现出接触直径不变模式、 接触角不变模式及共同减小模式, 与平滑基底上水滴的挥发规律类似. 在挥发过程中, 发生了Cassie-Wenzel转变, 转变发生的时间与PDMS基底上突起部分的面积分数(即固相率)呈现良好的线性关系. 随着挥发的进行, 水滴的各向异性在接触角不变模式阶段消失, 即挥发导致水滴从开始的椭球缺状变为球缺状. 相似文献
68.
69.
Xiaobo Zhu Tongen Lin Eric Manning Yuancheng Zhang Mengmeng Yu Bin Zuo Lianzhou Wang 《Journal of nanoparticle research》2018,20(6):160
The ever-growing market of electrochemical energy storage impels the advances on cost-effective and environmentally friendly battery chemistries. Lithium-ion batteries (LIBs) are currently the most critical energy storage devices for a variety of applications, while sodium-ion batteries (SIBs) are expected to complement LIBs in large-scale applications. In respect to their constituent components, the cathode part is the most significant sector regarding weight fraction and cost. Therefore, the development of cathode materials based on Earth’s abundant elements (Fe and Mn) largely determines the prospects of the batteries. Herein, we offer a comprehensive review of the up-to-date advances on Fe- and Mn-based cathode materials for LIBs and SIBs, highlighting some promising candidates, such as Li- and Mn-rich layered oxides, LiNi0.5Mn1.5O4, LiFe1-xMnxPO4, NaxFeyMn1-yO2, Na4MnFe2(PO4)(P2O7), and Prussian blue analogs. Also, challenges and prospects are discussed to direct the possible development of cost-effective and high-performance cathode materials for future rechargeable batteries. 相似文献
70.
通过葡萄糖、丙烯酸羟乙酯和丁二胺反应,制备了含不饱和双键的糖基功能单体。 采用傅里叶红外光谱和核磁共振氢谱对合成的产物进行结构表征确定。 采用紫外光引发接枝聚合技术,将制备的不饱和糖单体接枝聚合到聚氨酯膜的表面,以衰减全反射模式下傅里叶红外光谱对表面接枝反应进行了确认。 通过静态水接触角实验和血小板黏附实验,分别对改性聚氨酯膜表面的亲水性和血液相容性进行了研究,结果表明,改性聚氨酯膜表面的接触角从86°降低到45°,血小板的粘附量由14.36×103 cells/mm2减少到2.57×103 cells/mm2,亲水性明显增强,血液相容性显著改善。 相似文献