全文获取类型
收费全文 | 2195篇 |
免费 | 129篇 |
国内免费 | 32篇 |
专业分类
化学 | 1362篇 |
晶体学 | 13篇 |
力学 | 133篇 |
数学 | 336篇 |
物理学 | 271篇 |
无线电 | 241篇 |
出版年
2024年 | 3篇 |
2023年 | 15篇 |
2022年 | 46篇 |
2021年 | 81篇 |
2020年 | 98篇 |
2019年 | 108篇 |
2018年 | 134篇 |
2017年 | 105篇 |
2016年 | 176篇 |
2015年 | 115篇 |
2014年 | 164篇 |
2013年 | 264篇 |
2012年 | 183篇 |
2011年 | 161篇 |
2010年 | 136篇 |
2009年 | 121篇 |
2008年 | 106篇 |
2007年 | 76篇 |
2006年 | 50篇 |
2005年 | 39篇 |
2004年 | 30篇 |
2003年 | 16篇 |
2002年 | 21篇 |
2001年 | 12篇 |
2000年 | 5篇 |
1999年 | 5篇 |
1998年 | 7篇 |
1997年 | 5篇 |
1996年 | 4篇 |
1995年 | 5篇 |
1994年 | 3篇 |
1993年 | 7篇 |
1992年 | 9篇 |
1991年 | 3篇 |
1990年 | 3篇 |
1989年 | 3篇 |
1987年 | 2篇 |
1986年 | 3篇 |
1985年 | 5篇 |
1984年 | 6篇 |
1983年 | 3篇 |
1982年 | 2篇 |
1981年 | 3篇 |
1980年 | 2篇 |
1974年 | 1篇 |
1971年 | 1篇 |
1970年 | 2篇 |
1969年 | 1篇 |
1968年 | 1篇 |
1967年 | 1篇 |
排序方式: 共有2356条查询结果,搜索用时 15 毫秒
21.
22.
23.
Bimetallic Gold(I) Complexes with Ethynyl‐Helicene and Bis‐Phosphole Ligands: Understanding the Role of Aurophilic Interactions in their Chiroptical Properties
下载免费PDF全文
![点击此处可从《Chemistry (Weinheim an der Bergstrasse, Germany)》网站下载免费的PDF全文](/ch/ext_images/free.gif)
Dr. Mehdi El Sayed Moussa Dr. Hui Chen Zuoyong Wang Dr. Monika Srebro‐Hooper Dr. Nicolas Vanthuyne Dr. Soizic Chevance Prof. Christian Roussel Prof. J. A. Gareth Williams Prof. Jochen Autschbach Prof. Régis Réau Prof. Zheng Duan Dr. Christophe Lescop Dr. Jeanne Crassous 《Chemistry (Weinheim an der Bergstrasse, Germany)》2016,22(17):6075-6086
Monometallic gold(I)‐alkynyl‐helicene complexes ( 1 a , b ) and bimetallic gold(I)‐alkynyl‐helicene architectures featuring the presence ( 2 a , b ) or absence ( 3 a , b ) of aurophilic intramolecular interactions were prepared by using different types of phosphole ligands (mono‐phosphole L1 or bis‐phospholes L2 , 3 ). The influence of the AuI d10 metal center(s) on the electronic, photophysical, and chiroptical properties of these unprecedented phosphole‐gold(I)‐alkynyl‐helicene complexes was examined. Experimental and theoretical results highlight the importance of ligand‐to‐ligand‐type charge transfers and the strong effect of the presence or absence of AuI–AuI interactions in 2 a , b . 相似文献
24.
25.
Ali Reza Kiasat Foad Kazemi Mehdi Fallah Mehr Jardi 《Phosphorus, sulfur, and silicon and the related elements》2013,188(9):1841-1844
A simple and efficient method for the conversion of various oxiranes to the corresponding thiiranes using thiourea under solvent free conditions is described. 相似文献
26.
Peyman Salehi Mohammad Mehdi Khodaei Amin Rostami 《Phosphorus, sulfur, and silicon and the related elements》2013,188(11):2235-2243
Alanine/chlorochromic acid/silica gel is a new and selective reagent for the efficient oxidation of sulfides, thiols, oximes, and alcohols. Oxidation of sulfides is solvent dependent. In chloroform at room temperature sulfoxides are formed as the major products, while in carbon tetrachloride or under solvent-free conditions solfones are produced in good-to-excellent yields. 相似文献
27.
Mehdi Taassori Meysam Taassori Sener Uysal 《Design Automation for Embedded Systems》2016,20(3):191-210
Network on chip (NoC) has been proposed as an appropriate solution for today’s on-chip communication challenges. Power dissipation has become a key factor in the NoCs because of their shrinking sizes. In this paper, we propose a new encoding approach aimed at power reduction by decreasing the number of switching activities on the buses. This approach assigns the symbols to data word in such a way that the more frequent words are sent by less power consumption. This algorithm dedicates the symbols with less ones to high probability data and uses transition signaling to transmit data. The proposed method, unlike the existing low power encoding, does not rely on spatial redundancy and keeps the width of the bus constant. Experimental evaluations show that our approach reduces the power dissipation up to 46 % with 2.70, 0.51, and 15.43 % power, critical path and area overhead in the NoCs, respectively. 相似文献
28.
29.
30.
Nader Mansoori Oghaz Behzad Haghighi Mohammad Mehdi Alavianmehr Ebrahim Ghiamati 《Journal of solution chemistry》2013,42(3):544-554
A robust and efficient procedure is presented for calculating the solubility parameter. An analytical equation for internal pressure is proposed. Through a simple relation reported by Verdier and Andersen (fluid phase equilibrium 231: 125–137, 2005), one can easily find the solubility parameter via our analytical equation for the internal pressure. Also, the radial distribution function (RDF) of a Lennard–Jones LJ (12, 6) fluid, proposed by Xu and Hu (fluid phase equilibrium 30: 221–228, 1986), has been employed to calculate the internal pressure of normal alkanes from methane to decane. Their solubility parameters were evaluated according to the calculated values of the internal pressure. A comparison between the experimental and the estimated values demonstrated a very good agreement between them. 相似文献