Quantitative Analysis of Holmium Ion by a Ho3+ Ion‐Selective Sensor Based on a Symmetric Thio‐Schiff's Base

A poly(vinyl chloride) (PVC) membrane sensor for holmium ions was fabricated based on N‐[(Z)‐1‐(2‐thienyl)‐ methylidene]‐N‐[4‐(4‐{[(Z)‐1‐(2‐thienyl)methylidene]amino} phenoxy)phenyl] amine (TPA) as a new ion carrier, acetophenon (AP) as plasticizing solvent mediator and sodium tetraphenyl borate (NaTPB) as an anion excluder. The electrode shows a good selectivity towards Ho³⁺ ions respect to other inorganic cations, including alkali, alkaline earth, transition and heavy metal ions. The constructed sensor displays a Nernstian behavior (19.5±0.3 mV/decade) over the concentration range of 1.0×10⁻⁶ to 1.0×10⁻² mol·L⁻¹ with the detection limit of the electrode being 4.6×10⁻⁷ mol·L⁻¹ and very short response time (ca. 5 s). It has a useful working pH range of 3.2–9.8 for at least 8 weeks. The electrode was successfully applied as an indicator electrode for the potentiometric titration of a Ho³⁺ solution with EDTA and holmium determination in some alloys. The proposed sensor accuracy was studied by the determination of Ho³⁺ in mixtures of three different ions.     

Synthesis of mesoporous functional hematite nanofibrous photoanodes by electrospinning

Iron(III) oxide (hematite, Fe₂O₃) nanofibers, as visible light‐induced photoanode for water oxidation reaction of a water splitting process, were fabricated through electrospinning method followed by calcination treatment. The prepared samples were characterized with scanning electron microscopy, and three‐electrode galvanostat/potentiostat for evaluating their photoelectrochemical (PEC) properties. The diameter of the as‐spun fibers is about 300 nm, and calcinated fibers have diameter less than 110 nm with mesoporous structure. Optimized multilayered electrospun α‐Fe₂O₃ nanostructure mats showed photocurrent density of 0.53 mA/cm² under dark and visible illumination conditions at voltage 1.23 V and constant intensity (900 mW/cm²). This photovoltaic performance of nanostructure mats makes it suitable choice for using in the PEC water splitting application as an efficient photoanode. This method, if combined with appropriate flexible conductive substrate, has the potential for producing flexible hematite solar fuel generators. Copyright © 2015 John Wiley & Sons, Ltd.     

电池充电管理：新兴趋势

简介手机、便携式媒体播放器、便携式导航工具及蓝芽（Bluetooth）耳机等新一代手持装置不断缩小体积外型,同时加强效能与功能。就充电管理而言,这些强化的功能使得设计工程人员必须同时顾及用户的便利性与体验感受,以及整体充电时间与成本的均衡。     

Crystal Structure and Mass-, Electronic-, Infrared Spectral Studies on Hexaaqua Ni(II) Bis(O-Tolylazo-Citrazinate) Hexahydrate Complex

A new crystalline octahedral hexaaqua Ni(II) bis(o-tolylazo-citrazinate)hexahydrate complex was synthesized. The analytical data proved the formation of 1:2 stoichiometry. An X-ray structure investigation has been carried out. The triclinic space group is p and the unit cell parameters are a = 585.5 pm, b = 993 pm, c = 1139.4 pm, α = 101.6°, β = 97.4°, γ = 102.4°. Evaluation of intensity data revealed the structure with an R-value of 0.03 (2316 observed independent reflections). The compound consists of hexaaqua nickel(2+) ions, univalent anions of the carboxylic acid and six additional water molecules per     

Pricing mechanism for interconnection between phone operators and virtual mobile VoIP operators

Lately software based virtual mobile voice over Internet Protocol (VMVoIP) services have become available to end-users which may endanger profit of regular telephone operators from phone calls. In this situation, telephone operators should decide on a proper mechanism for interconnection with such VMVoIP operators which secures mutual benefit of both operators. In this paper, we study both monopolistic and oligopolistic markets of VMVoIP in which a single VMVoIP and several VMVoIP operators available in the market respectively. We model the interaction among a phone operator, VMVoIP operators and end-users as a leader-follower dynamic game and find a sub-game perfect Nash equilibrium (SPNE) for the game. The SPNE shows the phone operator’s best pricing strategy (i.e., wholesale price for VMVoIP operators and retail price for end-users) and its best decision on the interconnection with VMVoIP operators. We further study economic interpretation of the SPNE. We show that in specific end-users’ demands, the phone operator may increase its total profit by allowing the interconnection and taking right price discrimination strategy.     

Implementation Issues in Turbo Decoding for 3GPP FDD Receiver

In the Frequency Division Duplex (FDD) mode of the Third Generation Partnership Project (3GPP) standard, implementation of the turbo decoder, especially for the mobile equipments, faces design decisions related to computational complexity, power efficiency, and memory requirements. In this paper we compare different approaches of low complexity implementation of the turbo decoder, with emphasis on the issues of signal scaling and quantization, the sliding window operation for memory size reduction and the iteration stopping algorithms. The demodulated signal at the output of the RAKE receiver may have a wide dynamic range and it may require many bits of precision. In order to overcome the numerical precision problem and to prevent Log Likelihood ratio (LLR) metric overflow, a scaling algorithm must be used. Our simulation results indicate that the Average Absolute (AA) algorithm using dynamic scaling outperforms other scaling schemes and it is less sensitive to the channel conditions. One of the major challenges in the implementation of a practical turbo decoder is optimization of memory requirements. In this paper we evaluate the performance of the sliding window algorithm using different main and guard window sizes. We show that the bit and block error rate performance of the sliding window scheme mainly depend on the guard window size rather than the main window size. The simulation results indicate that small guard window sizes can significantly decrease the iteration gain for large frames in fast fading channels. Iteration stopping algorithms reduce the power consumption and the latency of the decoder and help to dedicate more resources to other functions of the receiver. The block error distribution in the fading channels makes it even more essential to use an iteration stopping rule. Our simulations conclude that a rule called the minimum absolute value appears to be a very effective, low complexity and robust algorithm. Mohamadreza Marandian Hagh was born in Tabriz, Iran on January 1974. He received the B.S. and the M.S. degrees in electrical engineering from Tehran University with honors in 1996 and 1999, respectively. He is pursuing the Ph.D. degree in electrical engineering at Northeastern University, Boston. His research interests includes information theory, channel coding and iterative techniques for wireless communication systems. His current research is focused on low complexity designs for iterative receivers using Space-Time coding in time-dispersive channels. He is also interested in Exit-Chart analysis of iterative receivers. From 1996 to 1999, he was with Sana Pro Inc. as a system engineer, developing simulation tools for OFDM, WCDMA, CDMA2000. He is currently with Airvana Inc. in Chelmsford, MA and working on 1xEVDO wireless systems. Masoud Salehi received BS degree (Summa Cum Laude) from Tehran University and MS and Ph.D. degrees from Stanford University all in Electrical Engineering. Before joining Northeastern, he was with the Departments of Electrical and Computer Engineering, Isfahan University of Technology and Tehran University. From February 1988 to May 1989 Dr. Salehi was a visiting professor at the Information Theory Research Group, Department of Electrical Engineering, Eindhoven University of Technology, The Netherlands, where he did research in network information theory and coding for storage media.In 1989 Dr. Salehi joined Department of Electrical and Computer Engineering, Northeastern University. Professor Salehi is a member of the CDSP (Communication and Digital Signal Processing) Center. His main areas of research interest are network information theory, source-channel matching problems in single and multiple user systems, data compression, turbo coding, coding for fading channels, and digital watermarking. Professor Salehi’s research has been supported by research grants from the National Science Foundation (NSF), GTE, NUWC, CenSSIS, and Analog Devices. Professor Salehi has also done consulting to the industry including Teleco Oilfield Services and AT&T. Professor Salehi is currently a member of the Editorial Board of The International Journal of Electronics and Communications.Professor Salehi is the coauthor of the textbooks “Communication Systems Engineering”, Prentice-Hall 1994, 2002, “Contemporary Communication Systems Using MATLAB and Simulink” Thomson 1998, 2000, 2004, and “Fundamentals of Communication Systems”, Prentice-Hall 2005. Abhay Sharma received B.E. (Hons) Electrical and Electronics Engineering degree from Birla Institute of Technology and Science, Pilani, India in 1996 and M.S. Electrical Engineering degree from Ohio State University, Columbus in 2000. From 2000 to 2005 he was working with Analog Devices, RF and Wireless Systems Group, Wilmington, USA, where he was working on design and implementation of algorithms for the emerging cellular communication standards. Currently he is working with Allgo Embedded Systems, Bangalore, India, in the area of wireless networks and systems based on the emerging W-PAN wireless technologies. Zoran Zvonar received the Dipl. Ing. degree in 1986 and the M.S. degree in 1989, both from the Department of Electrical Engineering, University of Belgrade, Yugoslavia, and the Ph.D. degree in Electrical Engineering from the Northeastern University, Boston, in 1993.From 1986 to 1989 he was with the Department of Electrical Engineering, University of Belgrade, Belgrade, Yugoslavia, where he conducted research in the area of telecommunications. 1993 to 1994 he was a Post-Doctoral investigator at the Woods Hole Oceanographic Institution, Woods Hole, MA, anconducted research on multiple-access communications for underwater acoustic networks. Since 1994 he has been with the Analog Devices, Communications Division, Wilmington, USA. He is the Manager of the Systems Engineering Group focusing on the design of algorithms and architectures for wireless communications, with emphasis on integrated solutions and real-time software.He was a Guest Editor of the IEEE Transactions on Vehicular Technology, the International Journal of Wireless Information Networks and the ACM/Baltzer Wireless Networks, Associate Editor of the IEEE Communications Letters and a co-editor of the books GSM: Evolution Towards Third Generation Systems, Kluwer Academic Publishers, 1998, Wireless Multimedia Networks Technologies, Kluwer Academic Publishers, 1999 and Software Radio Technologies: Selected Reading, IEEE Press, 2001. Dr. Zvonar is currently Co-Editor of the Radio Communication Series in the IEEE Communications Magazine.     

Synthesis and characterization of some nickel(II) Schiff bases complexes

Summary The reaction of nickel(II) salts with 2-picolyl- and 2,6-lutidyl-phenylketone benzoylhydrazone and theirp-nitro- andp-methoxy-derivatives were carried out and the compounds characterized on the basis of analytical and spectral data.     

Thermal and electrical conductivity properties of some CrIII, MnII and UO 2 II amino alcohol complexes

Cr^III, Mn^II and UO₂ ^II amino alcohol complexes were prepared and analyzed. The IR spectra proved that the ligation occurs via oxygen and nitrogen atoms. The nujol mull electronic absorption spectra joined with the room temperature magnetic moment values proved that the complexes are of O_h geometry. The thermal behaviour of the complexes was studied by DTA and TG techniques. The mechanism of the decomposition was suggested. The thermodynamic parameters of the decomposition were evaluated and discussed. The entropy of activation changes, S*, showed that the transition states are more ordered than the reacting complexes. The D.C. electrical conductivity measurements of Cr- and Mn-amino alcohol complexes are of semiconductor behaviour. Empirical equations were deduced for the conduction of the investigated complexes.This revised version was published online in November 2005 with corrections to the Cover Date.     

Organoplatinum(IV) tris-chelate complexes, each having a cyclic metallacarbonate ring: synthesis, characterization and kinetic studies of the formation

The complexes [Pt[(CH2)4](NN)], 1a (NN = 2,2'-bipyridine) and 1b (NN = 1,10-phenanthroline) react with 2,3-epoxypropylphenyl ether in the presence of CO2 to give tris-chelate platina(IV)cyclopentane complexes characterized by 1H and 13C NMR spectroscopy as [Pt[(CH2)4](CH2CHCH2OPhOCO2)(NN)], 2. The reactions proceed by the SN2 mechanism and the rates were independent of concentration of CO2. It is demonstrated that for 1a, the reaction proceeds 2.32 times faster than the similar reaction in which the dimethyl analog, [PtMe2(2,2'-bipyridine)], is used. The analog tris-chelate complex [Pt[(CH2)4](CH2CHPhOCO2)(phen)], 3a, was similarly synthesized.     

An optode membrane for determination of gold using a simple light-emitting diode-based device

Abstract  

A selective optode based on immobilization of 5-(p-dimethylaminobenzylidene)rhodanine on a triacetylcellulose membrane was developed for quantitative determination of Au(III). The determination procedure was performed using a simple light-emitting diode (LED)-based device as a new effort to overcome low reproducibility and repeatability problems which usually accompany optode-based determinations. The results obtained were compared with those of conventional spectrophotometric methods. The response characteristics of the sensor including dynamic range, reproducibility, response time, and lifetime are discussed in detail. This sensor was used for the determination of Au(III) in ore and electroplating liquid effluent samples with satisfactory results in comparison with flame atomic absorption spectroscopy as standard method. Under the optimum conditions, the calibration plot was linear in the concentration range of 0.3–6.0 μg cm⁻³. The relative standard deviations for five replicate determinations of 1.0 μg cm⁻³ Au(III) and the corresponding limits of detection were 1.76% and 0.12 μg cm⁻³, respectively.