Various carbon dust particles

Nano-sized carbon dusts are suspected of having negative effects on human health. An exact characterization of such particles is necessary to understand possible toxic effects, i.e. in the lung. Observed by transmission electron microscopy (TEM), the carbon dusts are a composite of very small primary particles and larger agglomerates of these. A differentiation of the primary particles and agglomerates according to source is not possible by TEM, however, thermogravimetry investigations in synthetic air atmosphere are helpful. Standardized carbon black and graphite show a single-step oxidation behaviour, whereas ethene soot and diesel soot, for example, show more complex-reaction mechanisms. The results of ethene soot exemplarily demonstrate the oxidation mechanism. In addition to the oxidation reaction to carbon dioxide, a sintering process takes place. To confirm the oxidation mechanism, thermal behaviour of ethene soot has been simulated by kinetic modulation using a three-step reaction mechanism of n-th order. The reaction order indicates a complex mechanism for the first-reaction step. For the second and third-reaction step, a phase boundary mechanism could be suggested.     

Synthesis of novel azanorbornylpurine derivatives

Azanorbornylpurine derivatives were prepared by Mitsunobu reaction of appropriate hydroxyazanorbornane derivative with 6-chloropurine or construction of purine base at azanorbornylamines. The prepared target compounds were evaluated for antiviral activity and effect on neuronal and muscle nicotinic acetylcholine receptors.     

Dynamic connectivity and path formation time in Poisson networks

The connectivity of wireless networks is commonly analyzed using static geometric graphs. However, with half-duplex radios and due to interference, static or instantaneous connectivity cannot be achieved. It is not necessary, either, since packets take multiple time slots to propagate through the network. For example, if a packet traverses a link in one time slot, it is irrelevant if the next link is available in that time slot also, but it is relevant if the next hop exists in the next time slot. To account for half-duplex constraints and the dynamic changes in the transmitting set of nodes due to MAC scheduling and traffic loads, we introduce a random multi-digraph that captures the evolution of the network connectivity in a dynamic fashion. To obtain concrete results, we focus on Poisson networks, where transmitters form a Poisson point process on the plane at all time instants. We first provide analytical results for the degree distribution of the graph and derive the distributional properties of the end-to-end connection delay using techniques from first-passage percolation and epidemic processes. Next, we prove that under some assumptions, the delay scales linearly with the source–destination distance even in the presence of interference. We also provide simulation results in support of the theoretical results.     

Light emission from nanocrystalline silicon clusters embedded in silicon dioxide: Role of the suboxide states

Silicon clusters embedded in a silicon dioxide matrix were prepared by ultrasound-assisted implantation resulting in a modified concentration of suboxide states as revealed by high-resolution photoelectron spectroscopy. It is suggested that ultrasound treatment results in formation of different interface structure between silicon cluster and silicon dioxide matrix which is characterized by a distinctly reduced concentration of the suboxide states. It is observed that photoluminescence properties are strongly correlated with the concentration of the suboxide states thereby providing an evidence that besides a quantum confinement effect a closer look at the chemical composition of the nc-Si/SiO₂ system is important.     

3G LTE将继续推动移动替代固网飞思卡尔MSC8156 DSP支持3G LTE基站的高性能要求

3G LTE(长期演进)是第三代伙伴计划(3GPP)的一个高级标准,为广域网提供下一代宽带无线技术. 和以前各阶段的3GPP相比,3G LTE的目标是更高的吞吐量、更低的时延以及高效的IP回程,提供一种新的可以大规模部署的移动网络技术,预示着一个富媒体和实时服务新时代的到来.