T1rho Dispersion profile of rat tissues in vitro at very low locking fields

The purpose of this study was to show the T(1rho) dispersion profile in various rat tissues (liver, brain, spleen, kidney, heart and skeletal muscle) at low (0.1 T) B(0) field at very low locking field B1, starting from 10 microT. The T(1rho) dispersion profile showed a quite similar pattern in all tissues. The highest R(1rho) relaxation rates were seen in the liver and muscle followed by the heart, whereas the values for spleen, kidney and brain were rather similar. The greatest difference between R2 relaxation rate and R(1rho) relaxation rate at B1=10 microT was seen in the liver and muscle. The steepest slope for a dispersion curve was seen in the muscle. The value of T(1rho) approximately approached the value of T2 when the locking field B1 approached 0. Except for the liver, the calculated apparent relaxation rate R2' was slightly larger than the calculated one. The potential value of T(1rho) imaging is to combine high R1 contrast of low-field imaging with the high signal-to-noise ratio (SNR) of high static field imaging. T(1rho) relaxation and dispersion data presented in the current study help to optimize the rotating-frame MR imaging.     

Binary homogeneous nucleation in water-succinic acid and water-glutaric acid systems

Binary homogeneous nucleation of water-succinic acid and water-glutaric acid systems have been investigated. The numerical approach was based on the classical nucleation theory. Usually, nucleation is discussed in terms of kinetics, but the thermodynamics involved is undoubtedly equally important. In this paper we studied the above mentioned binary systems giving a quantitative insight into the nucleation process and a detailed consideration of the thermodynamics involved. Both diacids in study are in solid state at room temperature. They behave in environment according to their liquid state properties because of the absence of crystalline lattice energies, and therefore their subcooled liquid state thermodynamics have to be considered. The lack of consistent thermodynamic data for pure organic components and their aqueous solutions represent a high source of uncertainty. However, the present simulations indicate that in atmospheric conditions these binary systems will not form new particles.     

Identification of organic compounds in atmospheric aerosol particles by on-line supercritical fluid extraction-liquid chromatography-gas chromatography-mass spectrometry

Atmospheric particles were collected with a high-volume sampling system at an urban site in Helsinki (Finland). The samples were analysed by on-line coupled supercritical fluid extraction-liquid chromatography-gas chromatography-mass spectrometry (SFE-LC-GC-MS). The aerosol sample was first extracted by SFE. The extract was then transferred to a liquid chromatograph where it was fractionated into four fractions according to polarity. Each fraction from the liquid chromatograph was transferred to a gas chromatograph by large-volume injection, where final separation was carried out. The first LC fraction (280 microl) contained nonpolar compounds, such as n-alkanes, hopanes and steranes. The second fraction (840 microl) included polycyclic aromatic hydrocarbons (PAHs) and alkyl-PAHs, while the third and fourth fractions (840 microl each) contained more polar compounds, such as n-alkan-2-ones, n-alkanals, oxy-PAHs and quinones.     

Mass and thermal accommodation during gas-liquid condensation of water

In this Letter we report, for the first time, direct and simultaneous determinations of mass and thermal accommodation coefficients for water vapor condensation in air, based on the observation of droplet growth kinetics in an expansion cloud chamber. Our experiments exclude values below 0.85 for the thermal and below 0.4 for the mass accommodation coefficients at temperatures ranging from 250 to 290 K. Both coefficients are likely to be 1 for all studied conditions. Previously available experimental data on the mass accommodation coefficient for water span about 3 orders of magnitude. Our results provide new and firm insight to cloud microphysics and consequently to the global radiative balance.     

A low noise 0.9 GHz FBAR clock

A low noise 0.9 GHz FBAR clock consisting of an oscillator and divider circuit for single-sided-to-differential conversion for a high-speed interleaved pipeline A/D-converter was designed, realized with an in-house FBAR and a commercial 0.35 μm CMOS process, and tested. The circuit showed very good jitter and phase noise performance. A temperature coefficient of –47 ppm/K was measured.     

Compensation of non-reciprocal interference in adaptive MIMO-OFDM cellular systems

In a time-division-duplex communication system, the channel knowledge can be obtained at the transmitter side due to channel reciprocity and it can be used to increase the spectral efficiency of a multiple-input multiple-output (MIMO) communications. However, the interference structure between transmission directions does not necessarily correlate. The obtained quality of service at the receiver may differ significantly from the desired one if the transmission parameters are assigned based on the reverse link measurements only. In this paper, the performance of an orthogonal frequency division multiplexing (OFDM) cellular system with adaptive MIMO transmission is studied in the presence of non-reciprocal inter-cell interference when the downlink interference structure is known at the receiver and only limited feedback information about the interference is available at the transmitter. The results are compared to those with perfectly known interference structure per each sub-carrier. The system level impact of realistic interference non-reciprocity scenarios is studied via network simulations. Linear minimum mean squared error (MMSE) filter is applied at the receiver to suppress the impact of structured inter-cell interference together with a simple and bandwidth efficient closed-loop compensation algorithm. Both link and system level simulation results show that the proposed compensation algorithm with a simple scalar power offset feedback combined with interference suppression at the receiver results in nearly the same performance as the ideal case     

Thermoplastic Xylan Derivatives with Propylene Oxide

Polymeric xylan can be reacted with propylene oxide (PO) in aqueous alkali homogeneously. Since xylan is isolated from biomass in aqueous alkaline solution, an in-line modification with PO as part of the isolation protocol, is most practical. Hydroxypropyl xylan (HPX) is a low molecular weight, branched, water-soluble polysaccharide with low intrinsic viscosity and thermoplasticity. Following peracetylation of HPX in formamide solution, water-insoluble acetoxypropyl xylan (APX) is formed that is also thermoplastic but no longer water soluble. The glass transition temperature (T _g) of APX varies in relation to degree of substitution with hydroxypropyl groups (DS_PO), and this is found to decline from 160 to 70°C as DS_PO rises from 0.2 to 2.0. At a temperature above the T _g of HPX a molecular reorganization is noted, and a faint transition due to melting (T _m) is observed at 205°C. HPX thermally degrades with a weight loss maximum at 317°C, or approximately 60°C below that of a corresponding cellulose derivative. HPX forms clear films when solvent cast from aqueous solution. Films are higher in ultimate tensile strength and lower in toughness than corresponding cellulose derivative films. The properties of HPX and APX derivatives qualify this material as a potential biodegradable and thermoplastic additive to melt-processed plastics. Blend characteristics with polystyrene reveal a shear-thinning effect in melt and a plasticization effect in solid state.     

Fluorine-free organoxenon chemistry: HXeCCH,HXeCC, and HXeCCXeH

Three novel Xe-containing organic compounds, HXeCCH, HXeCC (open-shell species), and HXeCCXeH, are identified using infrared absorption spectroscopy. They are prepared in a low-temperature Xe matrix using UV photolysis of acetylene and subsequent annealing at 40-45 K. The experimental observations are supported by extensive ab initio calculations. This work demonstrates a new way to activate the H-Ctbd1;C- group without use of XeF(2), which can extend the range of organoxenon compounds.     

Negative gastrointestinal contrast enhancement and image distortion induced by superparamagnetic particles at 0.02 Tesla

Gastrointestinal contrast enhancement and image distortion induced by superparamagnetic particles were evaluated in vitro and in rabbits at 0.02 Tesla. Test tubes containing 0.01–1.0 mg particles/ml were imaged in an oil or water bath in order to demonstrate the concentration-dependent signal void and image distortion in vitro at several pulse sequences. The lowest concentration of particles tested clearly decreased the signal intensity. Image distortion was observed when the concentration exceeded 0.07 mg/ml and was more pronounced on the T₂-weighted images. The in vitro T₂ relaxation time decreased from 122 ms to 56 ms with an increase in the particle concentration from 0.01 to 0.06 mg/ml. A loss of the GI-tract signal was observed in rabbits after the administration of 1 mg particles/kg, given as a 0.03 mg/ml suspension. At a dose of 20 mg/kg (0.6 mg/ml suspension) significant image distortion was observed.