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41.
Andrzej Rajca Prof. Velavan Kathirvelu Dr. Sandip K. Roy Dr. Maren Pink Dr. Suchada Rajca Dr. Santanu Sarkar Sandra S. Eaton Prof. Gareth R. Eaton Prof. 《Chemistry (Weinheim an der Bergstrasse, Germany)》2010,16(19):5778-5782
Site‐directed spin labeling and EPR spectroscopy offer accurate, sensitive tools for the characterization of structure and function of macromolecules and their assemblies. A new rigid spin label, spirocyclohexyl nitroxide α‐amino acid and its N‐(9‐fluorenylmethoxycarbonyl) derivative, have been synthesized, which exhibit slow enough spin‐echo dephasing to permit accurate distance measurements by pulsed EPR spectroscopy at temperatures up to 125 K in 1:1 water/glycerol and at higher temperatures in matrices with higher glass transition temperatures. Distance measurements in the liquid nitrogen temperature range are less expensive than those that require liquid helium, which will greatly facilitate applications of pulsed EPR spectroscopy to the study of structure and conformation of peptides and proteins. 相似文献
42.
We comment on a recent Letter [Opt. Lett. 35, 4121 (2010)], in which the authors discuss an optimal pulse-width modulation (OPWM) method for sinusoidal fringe generation. We consider that the comparison of the squared binary method (SBM) and the sinusoidal pulse-width modulation (SPWM) method has considerable deficiencies. 相似文献
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Mayté Paredes Zaldivar Norma Galego Fernández Cristina Gastón Peña Manuel Rapado Paneque Sonia Altanés Valentín 《Journal of Thermal Analysis and Calorimetry》2011,106(3):725-730
A new polyacrylic acid/polyhydroxybutyrate semi-interpenetrating polymer network hydrogel, the s-IPN/PAA-PHB, was prepared
by a gamma radiation-induced polymerization. Thermal behavior was studied by thermogravimetric analysis (TG) and Differential
scanning calorimetry (DSC), while the s-IPNs composition, FTIR spectra, and swelling kinetics were also determined. It was
found that the DSC curve showed a melting point which is attributed to polyhydroxybutyrate. The TG curves showed various stages
of degradation which are in correspondence of the presence of crosslinked polyacrylic acid and confirmed the higher thermal
stability of the polymer network. The s-IPN/PAA-PHB composition was 10% of PHB and 90% of PAA. Moreover, the network reached
approximately 600% of swelling in water, so it behaves like a superabsorbent hydrogel. 相似文献
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The titanium content of pyrope garnet can be quantified using the intensity of a Raman band at about 830 cm−1 that is normalized to the 363 cm−1 band using a spectrometer‐specific calibration using 10 to 15 chromian pyropes from Bohemia, Czech Republic. An accuracy of 0.025 wt% could be achieved for TiO2 contents between 0.17 and 0.67 wt% TiO2 with a Raman spectrometer with a spectral resolution of better than 3.9 cm−1. The technique can be used in petrological and gemmological studies. Copyright © 2015 John Wiley & Sons, Ltd. 相似文献
49.
A method for the detection of small masses with the aid of a longitudinally vibrating band is described and further applications, e.g. for viscosity and humidity measurement are discussed. The complex Young's modulus of the band can also be determined. 相似文献
50.
Boerner LJ Mazumder S Pink M Baik MH Zaleski JM 《Chemistry (Weinheim an der Bergstrasse, Germany)》2011,17(51):14539-14551
The synthesis of a new series of free‐base, NiII and ZnII 2,3,12,13‐tetra(ethynyl)‐5,10,15,20‐tetraphenyl porphyrins is described. Upon heating, two of the four ethynyl moieties undergo Bergman cyclization to afford the monocyclized 2,3‐diethynyl‐5,20‐diphenylpiceno[10,11,12,13,14,15‐jklmn]porphyrin in 30 %, 10 %, and trace yields, respectively. The structures of all products were investigated by using quantum chemical calculations and the free‐base analogue was isolated and crystallized; all compounds show significant deviation from the idealized planar structure. No fully‐cyclized bispiceno[20,1,2,3,4,5,10,11,12,13,14,15‐fghij]porphyrin was isolated from the reaction mixture. To understand why only two of the four enthynyl groups undergo Bergman cyclization, the reaction coordinates were examined by using DFT at the PWPW91/cc‐pVTZ(‐f) level coupled to a continuum solvation model. The barrier to cyclization of the second pair of ethynyl groups was found to be 5.5 kcal mol?1 higher than the first, suggesting a negative cooperative effect and significantly slower rate for the second cyclization. Cyclization reactions for model porphyrin–enediynes with ethene‐ and H‐functionality substitutions at the meso‐phenyl rings were also examined, and found to have a similar barrier to diradical formation for the second cyclization event as for the first in these highly planar molecules. By enforcing an artificial 30° cant in two of the pyrrole rings of the porphyrin, the second barrier was increased by 2 kcal mol?1 in the ethene model system; this suggests that the disruption of the π conjugation of the extended porphyrin structure is the cause of the increased barrier to the second cyclization event. 相似文献