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31.
Leong‐Huat Gan Palaniswamy Ravi Bao Wei Mao Kam‐Chiu Tam 《Journal of polymer science. Part A, Polymer chemistry》2003,41(17):2688-2695
Polymerization of 2‐(diethylamino)ethyl methacrylate (DEAEMA) via homogeneous atom transfer radical polymerization under various reaction conditions is described. The effects of the initiators and solvents were examined. With 1,1,4,7,10,10‐hexamethyl triethylenetetramine/copper(I) chloride/p‐toluenesulfonyl chloride as the ligand/catalyst/initiator system in methanol, poly(DEAEMA) with a polydispersity index as low as 1.07 was synthesized. Kinetic studies demonstrated the polymerization was very well controlled and exhibited the living characteristic of the process. Well‐defined block copolymers of DEAEMA and tert‐butyl methacrylate (tBMA) were successfully synthesized. The copolymers could be synthesized with equally good results by starting with either p(DEAEMA) or p(tBMA) as the macroinitiators. However, only the macroinitiators terminated with chlorine should be used. The corresponding macroinitiators with bromine as a transferable group did not yield well‐defined copolymers. © 2003 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 41: 2688–2695, 2003 相似文献
32.
In this paper, by the use of a fixed point theorem, many new necessary and sufficient conditions for the existence of positive solutions in C[0,1]∩C1[0,1]∩C2(0,1) or C[0,1]∩C2(0,1) are presented for singular superlinear and sublinear second-order boundary value problems. Singularities at t=0, t=1 will be discussed. 相似文献
33.
Positron-lifetime experiments have been carried out on two undoped n-type liquid encapsulated Czochralski (LEC)-grown InP samples with different stoichiometric compositions in the temperature range 10-300 K. For temperatures below 120 K for P-rich InP and 100 K for In-rich InP, the positron average lifetime began to increase rapidly and then leveled off, which was associated with the charge state change of hydrogen indium vacancy complexes from (VInH4)+ to (VInH4)0. This phenomenon was more obvious in P-rich samples that have a higher concentration of VInH4. The transformation temperature of approximately 120 K suggests that the complex VInH4 is a donor defect and that the ionization energy is about 0.01 eV. The ionization of neutral VInH4 accounted for the decrease of the positron average lifetime when the sample was illuminated with a photon energy of 1.32 eV at 70 K. These results provide evidence for hydrogen complex defects in undoped LEC InP. 相似文献
34.
35.
KunHuaLIN MaoPingSONG ChenXiaDU QiaoHongZHANG YangJieWU 《中国化学快报》2003,14(7):673-676
The cyclomercurated ferrocenylimines containing heterocyclic ring were prepared by the condensation of cyclomercuration of acylferrocene with the appropriate heterocyclic amine.This procedure provides an efficient method for the synthesis of cyclomerucurated ferrocenylimines containing heterocyclic ring which are difficultly synthesized by the conventional method.The reaction mechanism is proposed. 相似文献
36.
37.
本文根据ITU-T最新的Q.2971协议,以及笔者所从事的实际课题,提出一整套B-ISDN第三层UNI信令的软件实现策略,其特点是能同时满足用户对点到点以及点到多点广播这两种通信方式的要求,而且可以动态配置。 相似文献
38.
The quaternary alloy InAs1−x−ySbxPy, lattice-matched to InAs, is a promising material for the production of infrared light sources for the detection of gases
in the 2–4 μm region of the spectrum. In this work, thermodynamic phase equilibrium calculations have been carried out to
determine the compositions required for liquid phase epitaxial growth and the extent of the miscibility gap in the solid material.
For high band gap materials, the desired growth temperature is found to be intermediate between a low temperature required
to grow P-rich solids and higher temperatures required to avoidspinodal decomposition. Conventional LPE growth at an intermediate temperature of 583°C is found to produce good material with high
luminescence efficiency and excellent optical characteristics. Problems with phosphorus loss from the melt are also discussed
and lower growth temperatures are found to considerably reduce this problem. Growth in the metastable region between the binodal
and spinodal lines has been achieved with the production of phosphorus-rich solids with concentrations up to y = 0.445. 相似文献
39.
提出了用激光衍射功率谱方法测量柱形颗粒群直径分布的技术方法,解决了长颗粒随机排列时的功率谱探测,及数据快速优化方法等技术难题。此技术已地应用于由羊毛和化纤截成的柱形颗粒群直径分布的测量,实现结果证明了此技术的可行性和实用性。 相似文献
40.