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991.
R. Mahesh Rupali Sharma Parteek Kour 《Phosphorus, sulfur, and silicon and the related elements》2013,188(12):1091-1097
AbstractA cerium(III) chloride-catalysed expeditious synthesis of α-hydroxyphosphonates via a modified Abramov synthetic protocol has been developed. The scope of the current protocol is broad, with a range of aromatic, α,β-unsaturated and heterocyclic aldehydes being efficiently converted to the anticipated products in very good to excellent yields (89–96%) in 15?min using low catalytic loading. The protocol was efficiently extended to hitherto unactivated cyclic ketones such as cyclopentanone and cyclohexanone to afford the required products in excellent yields. However, the reaction with cyclohexenone delivered a Michael product instead of the anticipated α-hydroxyphosphonates. The solvent-free conditions, low catalytic loadings, avoidance of toxic reagents and good to excellent yields are significant advantages of this protocol. 相似文献
992.
JPC – Journal of Planar Chromatography – Modern TLC - Holoptelea integrifolia (Sanskrit: chirivilva, Hindi: chilbil, family: Ulmaceae) is a large deciduous tree, growing up to 18 m... 相似文献
993.
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995.
Rodney A. Fernandes Mahesh B. Halle Asim K. Chowdhury Arun B. Ingle 《Tetrahedron: Asymmetry》2012,23(1):60-66
A diastereoselective synthesis of (+)-nephrosterinic acid and (+)-protolichesterinic acid, common members of the paraconic acids is described. The synthesis is based on a diastereoselective orthoester Johnson–Claisen rearrangement of a (Z)-allyl alcohol with a vicinal dioxolane moiety as key steps. The synthesis is completed in 10 steps and with overall yields of 15.9% for (+)-nephrosterinic acid and 16.4% for (+)-protolichesterinic acid. 相似文献
996.
Adivireddy Padmaja Thalari Payani Akkarapalli Muralikrishna Konda Mahesh 《Journal of heterocyclic chemistry》2011,48(1):199-204
A new class of pyrazolidinediones, isoxazolidinediones, pyrimidinetriones, and thioxopyrimidinediones were synthesized by the reaction of Michael adduct, dimethyl 2‐(1′,2′‐diarylsulfonyl)ethylmalonate with different nucleophiles, hydrazine hydrate, hydroxylamine hydrochloride, and urea derivatives. J. Heterocyclic Chem., 2011. 相似文献
997.
Rajeswari Gopal Geetha Sivakumar Krishnankutty Nair Chandrika Gayathri G. Saraswathy Asha Nair Sivakumari Manjula Sakuntala 《Molecules (Basel, Switzerland)》2021,26(8)
Osmotin, a plant defense protein, has functional similarity to adiponectin, an insulin sensitizingsensitising hormone secreted by adipocytes. We speculated that Piper colubrinum Osmotin (PcOSM) could have functional roles in obesity-related cancers, especially breast cancer. Immunofluorescence assays, flow cytometry, cell cycle analysis and a senescence assay were employed to delineate the activity in MDAMB231 breast cancer cell line. PcOSM pre-treated P. nigrum leaves showed significant reduction in disease symptoms correlated with high ROS production. In silico analysis predicted that PcOSM has higher binding efficiency with adiponectin receptor compared to adiponectin. PcOSM was effectively taken up by MDAMB231 cancer cells which resulted in marked increase in intracellular ROS levels leading to senescence and cell cycle arrest in G2/M stage. This study provides evidence on the ROS mediated direct inhibitory activity of the plant derived osmotin protein on the phytopathogen Phytophthora capsici, and the additional functional roles of this plant defense protein on cancer cells through inducing ROS associated senescence. The strong leads produced from this study could be pursued further to obtain more insights into the therapeutic potential of osmotin in human cancers. 相似文献
998.
Garud Kunal Sandip Seo Jae-Hyeong Patil Mahesh Suresh Bang You-Ma Pyo Young-Dug Cho Chong-Pyo Lee Moo-Yeon 《Journal of Thermal Analysis and Calorimetry》2021,143(1):387-419
Journal of Thermal Analysis and Calorimetry - In this study, an electro-thermo-structural coupled numerical analysis is conducted to evaluate the thermal, electrical, and structural performances of... 相似文献
999.
In this paper, we define Sumudu transform with convergence conditions in bicomplex space. Also, we derive some of its basic properties and its inverse. Applications of bicomplex Sumudu transform are illustrated to find the solution of differential equation of bicomplex-valued functions and find the solution for Cartesian transverse electric magnetic (TEM) waves in homogeneous space. 相似文献
1000.
The multiple depot ring-star problem (MDRSP) is an important combinatorial optimization problem that arises in optical fiber network design and in applications that collect data using stationary sensing devices and autonomous vehicles. Given the locations of a set of customers and a set of depots, the goal is to (i) find a set of simple cycles such that each cycle (ring) passes through a subset of customers and exactly one depot, (ii) assign each non-visited customer to a visited customer or a depot, and (iii) minimize the sum of the routing costs, i.e., the cost of the cycles and the assignment costs. We present a mixed integer linear programming formulation for the MDRSP and propose valid inequalities to strengthen the linear programming relaxation. Furthermore, we present a polyhedral analysis and derive facet-inducing results for the MDRSP. All these results are then used to develop a branch-and-cut algorithm to obtain optimal solutions to the MDRSP. The performance of the branch-and-cut algorithm is evaluated through extensive computational experiments on several classes of test instances. 相似文献