Evaluation of characteristic parameters for high performance hall cells

The current work focuses on presenting specific Hall cells with high performance, and their corresponding parameters. The design, integration, measurements and model development for their performance assessment are necessary stages considered in the generation of the Hall cells. Experimental results regarding the Hall cells absolute sensitivity, offset and offset temperature drift are provided for two particular structures exhibiting the best behavior in terms of maximum sensitivity and lowest offset. Three-dimensional physical simulations were performed for the structures and the Hall mobility was extracted. Representation of the inverse of the geometrical correction factor for the Greek-cross Hall cell is also provided.     

Plumbagin,a Naturally Occurring Naphthoquinone: Its Isolation,Spectrophotometric Determination in Roots,Stems, and Leaves in Plumbago Europaea L.

A new method for isolation and spectrophotometric determination of plumbagin is presented. Plumbagin was isolated by thin layer chromatography (TLC) and column chromatography (CC) techniques, as an orange tinged yellow long crystalline substances. Plumbagin exhibits two absrop-tion maxima at 410 and 510 nm. Stability of the color, pK_a value, and the effect of pH were studied. Beer's law is obeyed over the range 0.9-45 ppm. The method is applied to the determination of plumbagin in roots, stems, and leaves of Plumbago europaea L. plant.     

RNA-RNA noncovalent interactions investigated by microspray ionization mass spectrometry.

Electrospray ionization mass spectrometry is playing an increasing role in the study of noncovalent interactions involving biomolecules. RNA-RNA complexes are important in many areas of biology, including RNA catalysis, RNA splicing, ribosome function, and gene regulation. Here, microelectrospray mass spectrometry (microESI-MS) is used to study noncovalent base-pairing interactions between RNA oligonucleotides, an area not previously explored by this technique. Using a set of complementary RNA oligonucleotides, we demonstrate the formation of the expected double-helical RNA complexes composed of three distinct oligonucleotides. The ability to study specific RNA noncovalent interactions by microESI-MS has the potential to provide a unique method by which to analyze and assign precise molecular masses to RNA-RNA complexes.     

Free radicals in γ-irradiated poly-α-methylstyrene

Electron spin resonance (ESR) spectra were observed at ?160°C and at room temperature for γ-irradiated poly-α-methylstyrene. The spectrum observed at room temperature has been attributed to the radical species while that at ?160°C results from the same radical and superposition of the spectrum due to the radical ?H₂-C(CH₃)(C₆H₅)-. The radicals which are stable at room temperature could be used to graft vinyl acetate.     

Dinuclear molybdenum complexes derived from diphenols: electrochemical interactions and reduced species

The new diphenolato complexes [{Mo(NO){HB(dmpz)₃}Cl}₂Q] where dmpz = 3,5-dimethylpyrazolyl and Q = OC₆H₄(C₆H₄O (n = 1 or 2), OC₆H₄CR=CRC₆H₄O (R = H or Et), and OC₆H₄CH=CHC₆H₄CH=CHC₆H₄O have been prepared and their electrochemical properties (cyclic and differential pulse voltammetry) compared with previously reported analogues where Q = OC₆H₄O, OC₆H₄EC₆H₄O (E = SO₂, CO and S), OC₆H₄ (CO)C₆H₄ C₆H₄(CO)C₆H₄O and 1,5- and 2,7-O₂C₁₀H₆. The electrochemical interaction between the redox centres in the new complexes is very weak, in contrast to that in the 1,4-benzenediolato and naphthalendiolato species. The EPR spectra of the reduced mixed-valence species [{Mo(NO){HB(dmpz)₃}Cl}₂Q]⁻ where Q = 1,3- and 1,4-OC₆H₄O and OC₆H₄SC₆H₄O shows that they are valence-trapped at room temperature, whereas those of the dianions [{Mo(NO){HB(dmpz)₃}Cl}₂Q]²⁻ where Q = 1,4-OC₆H₄O, OC₆H₄EC₆H₄O (E = CO or S) and OC₆H₄CH=CHC₆H₄CH=CHC₆H₄O shows that the unpaired spins on each molybdenum centre are strongly correlated (J, the spin exchange integral A_Mo, the metal-hyperfine coupling constant). The electrochemical properties and the comproportionation constants for the reaction [{Mo(NO){HB(dmpz)₃} Cl}₂Q] + [{Mo(NO){HB(dmpz)₃}Cl}O]₂]²⁻2[{Mo(NO) {HB(dmpz)₃}Cl}₂Q]⁻ where Q = diphenolato bridge, are compared with related compounds containing benzenediamido and dianilido bridges.     

Cavity Length Independent Continuous Repetition Rate Tuning of a Self-Seeded Gain-Switched Fabry–PÉrot Laser

We propose a novel method that allows continuous repetition rate tuning of a self-seeded gain-switched Fabry-Perot laser without the need for change in cavity length. This is achieved by employing a linearly chirped fiber Bragg grating with a large dispersion parameter. The dispersed pulses overlap to produce a continuous-wave-like feedback into the gain-switched laser cavity. By using the proposed experimental setup, we demonstrate pulses portraying sidemode suppression ratios of at least 30 dB and widths of about 30 ps over the entire repetition rate tuning range of 2.5-10 GHz.     

Hypoelliptic Jacobi–Dunkl Convolution of Distributions

In this paper we give a necessary and sufficient condition in terms of the Jacobi–Dunkl transform in order that a Jacobi–Dunkl convolution of distributions is hypoelliptic.     

Kinetic resolution of sec-alcohols using a new class of readily assembled (S)-proline-derived 4-(pyrrolidino)-pyridine analogues

We report the development of a new class of readily prepared chiral 4-(pyrrolidino)-pyridine catalysts capable of exploiting both van der Waals (pi) and H-bonding interactions, thus allowing remote chiral information to stereochemically control the kinetic resolution of sec-alcohols.     

Selective Limit Theorems for Random Walks on Parabolic Biangle and Triangle Hypergroups

Let K be respectively the parabolic biangle and the triangle in and be a sequence in [0, +[ such that lim_p (p)=+. According to Koornwinder and Schwartz,⁽⁷⁾ for each there exist a convolution structure (*_(p)) such that (K, *_(p)) is a commutative hypergroup. Consider now a random walk on (K, *_(p)), assume that this random walk is stopped after j(p) steps. Then under certain conditions given below we prove that the random variables on K admit a selective limit theorems. The proofs depend on limit relations between the characters of these hypergroups and Laguerre polynomials that we give in this work.