Effect of carbon nanotubes on the thermal conductivity enhancement of synthesized hydroxyapatite filled with water for dental applications: experimental characterization and numerical study

Journal of Thermal Analysis and Calorimetry - The hydroxyapatite is one of the biocompatible and insulating bioceramics, while the carbon nanotube has a high thermal conductivity potential. This...     

Reversibly Switchable Fluorescent Molecular Systems Based on Metallacarborane–Perylenediimide Conjugates

Icosahedral metallacarboranes are θ-shaped anionic molecules in which two icosahedra share one vertex that is a metal center. The most remarkable of these compounds is the anionic cobalt-based metallacarborane [Co(C₂B₉H₁₁)₂]⁻, whose oxidation-reduction processes occur via an outer sphere electron process. This, along with its low density negative charge, makes [Co(C₂B₉H₁₁)₂]⁻ very appealing to participate in electron-transfer processes. In this work, [Co(C₂B₉H₁₁)₂]⁻ is tethered to a perylenediimide dye to produce the first examples of switchable luminescent molecules and materials based on metallacarboranes. In particular, the electronic communication of [Co(C₂B₉H₁₁)₂]⁻ with the appended chromophore unit in these compounds can be regulated upon application of redox stimuli, which allows the reversible modulation of the emitted fluorescence. As such, they behave as electrochemically-controlled fluorescent molecular switches in solution, which surpass the performance of previous systems based on conjugates of perylendiimides with ferrocene. Remarkably, they can form gels by treatment with appropriate mixtures of organic solvents, which result from the self-assembly of the cobaltabisdicarbollide-perylendiimide conjugates into 1D nanostructures. The interplay between dye π-stacking and metallacarborane electronic and steric interactions ultimately governs the supramolecular arrangement in these materials, which for one of the compounds prepared allows preserving the luminescent behavior in the gel state.     

Active transient elasto-acoustic response damping of a thick-walled liquid-coupled piezolaminated cylindrical vessel

The linear 3D piezoelasticity theory in conjunction with the versatile transfer matrix approach and the wave equation for the internal acoustic domain are employed for active non-stationary vibroacoustic response control of an arbitrarily thick, tri-laminate, fluid-filled, simply supported, piezocomposite cylindrical tank, excited by arbitrary (non-axisymmetric) time-dependent on-surface mechanical loads. The smart structure is composed of a supporting core layer of functionally graded orthotropic material perfectly bonded to inner and outer spatially distributed radially polarized functionally graded piezoceramic sensor and uniform force actuator (FGPM) layers. Active vibration damping is implemented by transferring the accumulated voltage on the sensor layer to the piezoelectric actuator layer in context of proportional and derivative control laws. Durbin's numerical inverse Laplace transform scheme is utilized to calculate the time response histories of the relevant interface displacement/stress components, center-point acoustic pressure, and actuator voltage, for selected loading configurations (i.e., concentrated step, impulse, and moving external loads). Numerical simulations demonstrate the effectiveness of the adopted distributed sensing/actuation configuration together with the active damping control strategy in suppressing the vibroacoustic response of a three-layered (Ba₂NaNb₅O₁₅/Al/PZT4) water-filled piezoelastic cylindrical tank. Limiting cases are considered and the validity of results is established by comparison with the available data as well as with the aid of a commercial finite element package.     

Available and Waiting Times for Cognitive Radios

Cognitive radios (CRs) have been recently proposed for the problem of spectrum scarcity. The principle of CRs?? operation is based on the opportunistic access to the frequency spectrum mainly dedicated to primary users (PUs). The statistical time pattern of PUs?? channel usage and arrival can affect the usability of specific frequency bands for CRs. In this note, the effect of the arrival rate and channel holding time of PUs on the available times for CRs is analyzed. To this end, first, based on Poissonian arrivals, the available time for CRs is calculated. Then, assuming a gamma distribution for the inter-arrival times and a uniform distribution of channel holding time of PU in these intervals, the probability density function and moments of the available time for CRs are derived. Next, the effect of PUs statistical parameters on the average number of packets and the average symbol rate that a CR can transmit is analyzed. Also, taking that CR needs at least T seconds, the average waiting time is calculated.     

A Reconfigurable TDMP Decoder for Raptor Codes

A Raptor code is a concatenation of a fixed rate precode and a Luby-Transform (LT) code that can be used as a rateless error-correcting code over communication channels. By definition, Raptor codes are characterized by irregularity features such as dynamic rate, check-degree variability, and joint coding, which make the design of hardware-efficient decoders a challenging task. In this paper, serial turbo decoding of architecture-aware Raptor codes is mapped into sequential row processing of a regular matrix by using a combination of code enhancements and architectural optimizations. The proposed mapping approach is based on three basic steps: (1) applying systematic permutations on the source matrix of the Raptor code, (2) confining LT random encoding to pseudo-random permutation of messages and periodic selection of row-splitting scenarios, and (3) developing a reconfigurable parallel check-node processor that attains a constant throughput while processing LT- and LDPC-nodes of varying degrees and count. The decoder scheduling is, thus, made simple and uniform across both LDPC and LT decoding. A serial decoder implementing the proposed approach was synthesized in 65 nm, 1.2 V CMOS technology. Hardware simulations show that the decoder, decoding a rate-0.4 code instance, achieves a throughput of 36 Mb/s at SNR of 1.5 dB, dissipates an average power of 27 mW and occupies an area of 0.55 mm².     

Facile,one-pot synthesis of new phenanthridine derivatives through 1,4-dipolar cycloaddition of phenantridine,activated acetylenes,and aromatic aldehydes

A facile, one-pot synthesis of new phenanthridine derivatives by a three-component reaction between phenantridine, dialkyl acetylenedicarboxylates（DAADs）, and aromatic aldehydes is described. The reaction is characterized by mild conditions, high selectivity, and tolerance to various functional groups.     

Chromium(VI) Based Oxidants III.1,2 Ferric Dichromate,Polyvinylpyridine Supported Zinc,and Ferric Dichromates as New Oxidizing Agents

Ferric dichromate, polyvinylpyridine supported zinc and ferric dichromates complexes are prepared and used as stable, mild, and efficient oxidizing reagents for the oxidation of different organic compounds. Ferric dichromate complex is more efficient.