全文获取类型
收费全文 | 349篇 |
免费 | 13篇 |
国内免费 | 2篇 |
专业分类
化学 | 180篇 |
力学 | 8篇 |
数学 | 57篇 |
物理学 | 78篇 |
无线电 | 41篇 |
出版年
2023年 | 3篇 |
2020年 | 5篇 |
2019年 | 8篇 |
2016年 | 7篇 |
2015年 | 7篇 |
2014年 | 9篇 |
2013年 | 5篇 |
2012年 | 16篇 |
2011年 | 21篇 |
2010年 | 6篇 |
2009年 | 6篇 |
2008年 | 10篇 |
2007年 | 15篇 |
2006年 | 13篇 |
2005年 | 11篇 |
2004年 | 14篇 |
2003年 | 17篇 |
2002年 | 7篇 |
2001年 | 11篇 |
2000年 | 9篇 |
1998年 | 7篇 |
1997年 | 5篇 |
1996年 | 9篇 |
1995年 | 3篇 |
1994年 | 6篇 |
1993年 | 4篇 |
1992年 | 4篇 |
1991年 | 3篇 |
1990年 | 5篇 |
1988年 | 6篇 |
1987年 | 6篇 |
1986年 | 4篇 |
1985年 | 6篇 |
1984年 | 3篇 |
1983年 | 3篇 |
1982年 | 7篇 |
1981年 | 6篇 |
1980年 | 6篇 |
1979年 | 5篇 |
1978年 | 5篇 |
1977年 | 6篇 |
1976年 | 5篇 |
1973年 | 3篇 |
1967年 | 3篇 |
1958年 | 2篇 |
1955年 | 2篇 |
1939年 | 2篇 |
1937年 | 2篇 |
1916年 | 2篇 |
1914年 | 2篇 |
排序方式: 共有364条查询结果,搜索用时 15 毫秒
21.
Based on Tresca's yield criterion and the flow rule associated with it, the behaviour of a linearly strain-hardening elastic-plastic hollow shaft subject to a positive radial temperature gradient and monotonously increasing angular speed is studied. (© 2008 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim) 相似文献
22.
We consider dark matter annihilation into standard model particles and show that the least detectable final states, namely, neutrinos, define an upper bound on the total cross section. Calculating the cosmic diffuse neutrino signal, and comparing it to the measured terrestrial atmospheric neutrino background, we derive a strong and general bound. This can be evaded if the annihilation products are dominantly new and truly invisible particles. Our bound is much stronger than the unitarity bound at the most interesting masses, shows that dark matter halos cannot be significantly modified by annihilations, and can be improved by a factor of 10-100 with existing neutrino experiments. 相似文献
23.
24.
Mack R. Holdiness 《Thermochimica Acta》1983,71(3):257-263
An experimental determination of heats of atomization of some ortho-substituted benzoic acids has been performed by combustion and differential scanning calorimetry. Resonance energy was calculated by the difference between the heat of atomization in the gas phase and the sum of the bond energies of a fixed bond structure for a resonating molecule. As the van der Waals radii of the ortho-substituent increased a decrease in resonance energy was observed. 相似文献
25.
26.
27.
Mack J Bunya M Shimizu Y Uoyama H Komobuchi N Okujima T Uno H Ito S Stillman MJ Ono N Kobayashi N 《Chemistry (Weinheim an der Bergstrasse, Germany)》2008,14(16):5001-5020
The optical spectra of a series of core-modified tetrabenzoporphyrins were analyzed to determine the effects of core modification, ligand folding, and partial benzo substitution at the ligand periphery on the electronic structure by using magnetic circular dichroism (MCD) and NMR spectroscopy, X-ray crystallography, cyclic and differential pulse voltammetry, and TD-DFT calculations. Planar 21-carba-, 21-thia-, 21,23-dithia-, and 21-oxa-23-thiatetrabenzo[b,g,l,q]porphyrins reported previously were studied together with the previously unreported 21-oxa- and 21-carba-23-thiatetrabenzo[b,g,l,q]porphyrins. The optical properties of these compounds are compared to those of tetrabenzo[b,g,l,q]-, 5,10,15,20-tetraphenyl-, 5,10,15,20-tetraphenyltetrabenzo[b,g,l,q]-21-thia-, 5,10,15,20-tetraphenyltetrabenzodithia-, 5,10,15,20-tetraphenyldibenzo[g,q]-21,23-dithia-, 5,10,15,20-tetraphenyldibenzo[b,l]-21,23-dithia-, 5,10,15,20-tetraphenyltribenzo[g,q,l]-21-thia-, and 5,10,15,20-tetraphenylbenzo[b]-21-thiaporphyrins. Michl's perimeter model and Gouterman's four-orbital model are used to conceptualize the results and to account for red shifts commonly observed in the spectral bands of nonplanar porphyrinoids. 相似文献
28.
Stanley R. Hobart Charles H. Mack Darrell J. Donaldson Julius P. Neumeyer 《Thermochimica Acta》1976,16(2):149-171
Differential thermal analyses (DTA) were made on a series of polyester/cotton blend fabrics before and after treatment with Thpc—urea—poly(vinyl bromide). This flame retardant did not affect the polyester melting endotherm, which was proportional to the polyester content and appeared at approximately 250°C. In nitrogen atmosphere, DTA of the treated blends showed exothermic peaks at 285°C for the cotton decomposition. and at 415°C for the polyester decomposition. In air, DTA of the treated blends showed exothermic peaks at 333°C for cellulose decomposition, at 431°C for polyester decomposition and at 490°C for char decomposition. The Thpc-urea component of the flame retardant is effective on the cotton cellulose portion of the blend; the poly(vinyl bromide) appears to decompose and act in the vapor state on the polyester. 相似文献
29.
30.
Adam Jaffe Stephanie A. Mack Yu Lin Wendy L. Mao Jeffrey B. Neaton Hemamala I. Karunadasa 《Angewandte Chemie (International ed. in English)》2020,59(10):4017-4022
We show that the onset pressure for appreciable conductivity in layered copper‐halide perovskites can decrease by ca. 50 GPa upon replacement of Cl with Br. Layered Cu–Cl perovskites require pressures >50 GPa to show a conductivity of 10?4 S cm?1, whereas here a Cu–Br congener, (EA)2CuBr4 (EA=ethylammonium), exhibits conductivity as high as 2×10?3 S cm?1 at only 2.6 GPa, and 0.17 S cm?1 at 59 GPa. Substitution of higher‐energy Br 4p for Cl 3p orbitals lowers the charge‐transfer band gap of the perovskite by 0.9 eV. This 1.7 eV band gap decreases to 0.3 eV at 65 GPa. High‐pressure X‐ray diffraction, optical absorption, and transport measurements, and density functional theory calculations allow us to track compression‐induced structural and electronic changes. The notable enhancement of the Br perovskite's electronic response to pressure may be attributed to more diffuse Br valence orbitals relative to Cl orbitals. This work brings the compression‐induced conductivity of Cu‐halide perovskites to more technologically accessible pressures. 相似文献