宽带化GSM-HI技术应用浅析

选取某市发达农村附近连续覆盖的基站作为研究对象,采用GSM 900M上行5 MHz频谱带宽作为GSM-HI的频谱带宽,从GSM-HI对GSM网络性能影响、室外组网性能、室外单站覆盖性能、室外基站覆盖室内、多用户同点/散点分布单扇区吞吐率、控制面/用户面时延几个方面的测试应用分析,证明GSM-HI所提供无线宽带接入能力,能够有效解决农村地区数据宽带接入的问题。     

管道检测对IRST系统探测与虚警概率的影响

探测概率、虚警概率是衡量红外搜索跟踪系统性能的重要指标,其大小由系统硬件水平、检测算法设计等因素决定。通过分析影响红外搜索跟踪系统探测概率、虚警概率的因素,建立了管道检测与探测概率、虚警概率关系模型,研究了序列图像检测中管道检测对系统探测概率、虚警概率的影响。通过仿真分析了实验结果,系统总检测概率与总虚警概率分别随单帧检测概率与单帧虚警概率的增加而增加,在管道长度相同的情况下,总检测概率和总虚警率都将随需检测帧数的增大而减小。     

地基望远镜风载数值分析

风载是影响地基望远镜性能的主要因素之一,为了研究风载荷的作用以及对望远镜性能的影响程度,首先建立了望远镜、圆顶和流场的几何模型。然后利用CFD(Computational Fluid Dynamics)分析了在外界风速为10 m/s 的情况下,3 种不同高角(30、60、120)流场中截面空气速度、压力、湍流动能以及主镜面的静压力的瞬态分布,最后通过有限元方法获得了主镜去除刚体位移后的面形。仿真结果表明,望远镜以不同高角观测时主镜面静压力功率谱密度与Gemini 望远镜的实测结果接近,真实模拟了风载荷的作用。由风载引起的镜面变形RMS 值分别为3.74E-1 nm,2.5E-2 nm,1.71E-1 nm,满足面形精度要求。     

对地观测星载激光测高系统高程误差分析

星载激光测高系统通过接收卫星平台激光器发出的激光脉冲经地表反射的微弱回波,计算卫星与地表的距离;结合卫星轨道和姿态数据,生成激光脚点精确地理位置和高程结果.其高程误差主要受器件、环境和目标参数影响,目前还没有完整描述对地观测星载激光测高系统平面和高程误差的数学模型.简化并完善了针对固体地表的激光测距误差模型,建立了完整的激光脚点平面和高程误差模型.利用高程精度和空间分辨率更高的机载Lidar数据评估了星载激光测高系统GLAS实测数据的高程偏差,评估结果符合所建误差模型.在较平坦的冰盖表面,GLAS系统高程精度可以达到设计值约15 cm.研究内容对测高系统高程误差评估和系统参数设计具有参考意义.     

低温条件下光学厚度对Tm3+：YAG材料光谱烧孔孔深的影响

通过理论与实验研究了光学厚度对Tm3+：YAG材料光谱烧孔孔深的影响。提出了一种用于分析光学厚度对光谱烧孔孔深影响的新模型。该模型从理论上推导了烧孔孔深与光学厚度的关系。根据提出的理论模型,当温度大于4K时,通过选择合适的光学厚度可以使光谱烧孔孔深得到最大值。最后通过使用合适的激光与Tm3+：YAG材料所形成的光谱烧孔实验证明了实验结果与理论分析是相一致的。     

基于加权模糊C均值算法改进的高光谱图像分类方案设计

为了有效改善高光谱图像数据分类的精确度,减少对大数目数据集的依赖,在原型空间特征提取方法的基础上提出一种基于加权模糊C均值算法改进型原型空间特征提取方案。该方案通过加权模糊 C 均值算法对每个特征施加不同的权重,从而保证提取后的特征含有较高的信息量。实验结果表明,与业内公认的原型空间提取算法相比 该方案在相对较小的数据集下,其性能仍具有较为理想的稳定性,且具有相对较高的分类精度,这样子就大大降低了对数据集样本数量的依赖性,同时改善了原型空间特征方法的效率。     

切向空气流速度对玻璃纤维增强树脂基复合材料激光烧蚀热的影响

烧蚀热可用于材料抗激光加固性能表征和材料的激光加工效率描述。实验研究了亚音速表面切向空气气流速度和激光功率密度对玻璃纤维/树脂复合材料烧蚀热的影响规律,结果表明,相同气流速度下,烧蚀热在100~500 W/cm2激光功率密度范围内先迅速降低然后趋于稳定,转折点约位于200 W/cm2;相同激光作用下,功率密度较低时,烧蚀热随着气流速度提升而变大,功率密度高于一定值(约200 W/cm2)后,烧蚀热随气流速度提升而降低。分析认为材料内部扩散、热解气体燃烧、残碳氧化放热、辐射能量损失、气流剥蚀等多个因素的竞争是激光能量利用效率变化的原因。     

Quinazoline Antifolate Thymidylate Synthase Inhibitors: Replacement of Glutamic Acid by Aminophosphonic Acids

The synthesis of six analogues of the potent thymidylate synthase (TS) inhibitor N -[4-[ N -[(3,4-dihydro-2-methyl-4-oxo-6-quinazolinoyl)-methyl]- N -prop-2-ynylamino]benzoyl]- L -glutamic acid 2 is described in which the glutamic acid residue has been replaced by DL -aminophosphonic acids. New antifolates were tested as inhibitors of TS isolated from mouse L1210 leukemic cells as well as inhibitors of growth mouse leukemic L5178Y cells. In general these modifications result in compounds that are considerably less potent than 2 as TS inhibitors with K i 's 0.17-1.10 w M. Very poor solubility in water limited their proper assay of growth cells inhibition.     

Hydrolysis kinetics of silane coupling agents studied by near-infrared spectroscopy plus partial least squares model

Abstract

A method of Fourier transform near-infrared (FT-NIR) spectroscopy combined with partial least squares (PLS) model was successfully applied to investigate the hydrolysis kinetics of four kinds of silane coupling agents (phenyltriethoxysilane, vinyltriethoxysilane, 3-mercaptopropyltriethoxysilane, 3-chloropropyltriethoxysilane) in an acid-catalyzed EtOH system. The fast scanning speed and high sensitivity of the FT-NIR spectroscopy, and the powerful data processing ability of the PLS, enabled the method to quantitatively and accurately catch the fast changing H₂O concentration during the hydrolysis processes without delay, realizing the study of the fast-paced hydrolysis reactions of the silane coupling agents. The results showed that electrophilic substitution occurred in the hydrolysis reactions, which followed second-order reactions and greatly depend on the catalyst concentration and reaction temperature. The hydrolysis rate constants, activation energy, and Arrhenius Frequency factors were gained. In conclusion, the FT-NIR PLS model is a powerful tool for hydrolysis kinetics researching of the silane coupling agents.     

NEW DERIVATIVES OF 4,5-BENZO-1,3,2-OXAZA (OR D1AZA)-PHOSPHOLANE FROM CONVENIENT CONDENSATION OF SUBSTITUTED UREA WITH TRIS(DIALKYLAMINO)PHOSPHINE

Abstract

The condensation of N-phenyl-N′-(2-hydroxylphenyl)urea or N-phenyl-N′-(2-aminophenyl)urea with tris(dia1kylamino)phosphine afforded derivatives of 4,5-benzo-1,3,2-oxaza (or diaza)-phospholane which formed intramolecular hydrogen bond. The cleavage of the amide bond to give N,N-dialky1-N′-phenylurea together with polymers of 1,3,2-benzodiazaphosphole was observed in the latter reaction.