一种紫外-可见光谱法检测水质COD的浊度影响实验研究

消除浊度影响是直接光谱法检测水质COD的关键技术问题。此源于紫外-可见光谱法检测水质参数的关键依赖于化学计量法所建立的准确的水质参数分析模型,而浊度是影响其建模的一个重要参数。为此,选取福尔马肼浊度液和邻苯二甲酸氢钾标准溶液,开展了紫外-可见吸收光谱法检测水质COD的浊度影响实验研究,获得了选定溶液在245,300,360和560 nm几个特征波长点的吸光度随浊度变化的最小二乘法拟合曲线,分析了吸光度随浊度的变化规律。研究结果表明,在240～380 nm的紫外光谱段,由于引起浊度的颗粒物对有机物产生了吸附,致使浊度对水样的紫外光谱影响较为复杂;在380～780 nm的可见光谱区域,浊度对光谱的影响则是随着波长的增大而减弱。基于此,开展了多元散射校正法对受浊度影响的水样光谱进行校正试验。对某溪水水样的紫外-可见吸收光谱进行多元散射校正,通过处理前后光谱对比表明,浊度引起各个波长点的基线偏移都得到了有效的校正,而在紫外区域特征并未减弱。接着对选取的三种液体的紫外-可见吸收光谱进行多元散射校正,实验结果表明：该方法可在不影响水样紫外-可见吸收光谱特征的前提下对其吸收曲线进行有效的校正,这不仅提高了光谱法检测水质COD的信噪比,而且还为化学计量法建立准确、有效的水质检测COD分析模型进行数据预处理提供了一种新途径。     

模式V加密敌我识别系统

本文介绍了模式V加密敌我识别系统的特点,以及工作原理和系统构成。     

网络数据资源自动获取技术研究与应用

人类社会现已进入了一个信息大爆发的新时代,如何利用计算机新技术从互联网上自动获取特定主题信息并实时提供服务,成为信息技术研究领域的热点之一.在网络爬虫、数据抽取、文本智能分类等关键技术研究及实现的基础上,研制集成了全球油气行业动态信息系统PetroDIS.该系统在信息获取、信息分类、网页构建等多方面做到了自动化,极大地提高了信息收集效率.     

Dynamic release process of pollutants during suspended sediment transport in aquatic system

Pollutants release is highly consistent with suspended sediment concentration （SSC） in water column, especially during re-suspension and transport events. The present research focuses on pollutant dynamic release from re-suspended sediment, especially the vertical distribution relationship between them. The sediment erosion experiments on a series of uniform flow are conducted in a circulate flume. Reactive tracer （phosphorus） is used as the contaminant in fine-grained sediments to identify the release characteristic length and time. Experimental results show that the flow condition near-bed depends on the sediment surface roughness. The region with high turbulent intensities corresponds to a high concentration sediment layer. In addition, the SSC decreases with the distance, water depth, and particle grain size. The sediment in a smaller grain size takes much more time to reach equilibrium concentration. Total phosphorus （TP） concentration changes along the water depth as SSC in the initial re-suspension stage, appearing in two obvious concentration regimes： the upper low-concentration layer and the high-concentration near-bottom layer. This layered phenomenon remains for about 3 hours until SSC distri- bution tends to be uniform. Longitudinal desorption plays an important role in long-way transport to reduce the amount of suspended sediment in water column.     

度鲁特韦关键中间体的合成及分子蒸馏提纯工艺

4-甲氧基乙酰乙酸甲酯是合成抗HIV新药度鲁特韦的关键中间体。本文以4-氯乙酰乙酸甲酯与甲醇为起始原料，氢化钠和甲醇钾作为混合碱，合成4 甲氧基乙酰乙酸甲酯，通过分子蒸馏法对其进行提纯获得纯品，总收率88%，纯度99.7%，其结构经¹H NMR和¹³C NMR确证。并对分子蒸馏工艺条件进行了优化。     

Narrow band quantitative and multivariate electroencephalogram analysis of peri-adolescent period

ABSTRACT: BACKGROUND: The peri-adolescent period is a crucial developmental moment of transition from childhood to emergent adulthood. The present report analyses the differences in Power Spectrum (PS) of the Electroencephalogram (EEG) between late childhood (24 children between 8 and 13 years old) and young adulthood (24 young adults between 18 and 23 years old). RESULTS: The narrow band analysis of the Electroencephalogram was computed in the frequency range of 0--20 Hz. The analysis of mean and variance suggested that six frequency ranges presented a different rate of maturation at these ages, namely: low delta, delta-theta, low alpha, high alpha, low beta and high beta. For most of these bands the maturation seems to occur later in anterior sites than posterior sites. Correlational analysis showed a lower pattern of correlation between different frequencies in children than in young adults, suggesting a certain asynchrony in the maturation of different rhythms. The topographical analysis revealed similar topographies of the different rhythms in children and young adults. Principal Component Analysis (PCA) demonstrated the same internal structure for the Electroencephalogram of both age groups. Principal Component Analysis allowed to separate four subcomponents in the alpha range. All these subcomponents peaked at a lower frequency in children than in young adults. CONCLUSIONS: The present approaches complement and solve some of the incertitudes when the classical brain broad rhythm analysis is applied. Children have a higher absolute power than young adults for frequency ranges between 0-20 Hz, the correlation of Power Spectrum (PS) with age and the variance age comparison showed that there are six ranges of frequencies that can distinguish the level of EEG maturation in children and adults. The establishment of maturational order of different frequencies and its possible maturational interdependence would require a complete series including all the different ages.     

Grand Canonical Ensemble Interpretation for Charged Particle Quantum Tunneling Radiation

In this paper, we present a grand canonical ensemble interpretation for the massive charged particles tunneling from a charged black hole. The probability distribution function corresponding the emission shell system is derived in details, and the expression is same as the tunneling rate in Parikh-Wilzeck framework. With this result, the statistical significance of the quantum tunneling radiation is discussed.     

基于ATE的卫星导航射频芯片测试技术

卫星导航射频芯片是导航系统中的关键部分,其指标的优劣决定着导航系统的导航精度。通过分析卫星导航射频芯片的结构特点,针对主要参数进行了测试分析。在基于集成电路自动测试系统(ATE)的基础上,结合射频测试设备实现卫星导航射频芯片的性能测试。该技术对基于ATE的射频芯片测试均具有借鉴意义。     

宽带脉冲行波管放大器功率管理技术研究

介绍了一种宽带脉冲行波管放大器,阐述了行波管放大器的基本工作原理,分析了影响行波管输出功率的主要因素,并提出了一种切实可行的宽带行波管放大器的功率管理技术。     

推进器辅助系泊系统的动态张力控制

在良好的环境条件下,无推进器锚泊系统足以完成定位。然而,随着石油生产发展到深水区海域,这种超尺寸的锚泊系统就不适用了。因此,必须发展"混合动力"方法,即利用推进器补偿来设计更轻量级的锚泊系统。提出了在动力辅助锚泊系统中,通过动态控制锚泊线张力的方法来减少能量消耗,根据无源性推导出一个参考自适应控制策略。仿真包含并采用了船舶刚体子模型和锚泊有限元子模型。仿真结果验证了使用动态锚线张力的可行性。