全文获取类型
收费全文 | 1393篇 |
免费 | 1篇 |
国内免费 | 13篇 |
专业分类
化学 | 943篇 |
力学 | 3篇 |
综合类 | 1篇 |
数学 | 8篇 |
物理学 | 329篇 |
无线电 | 123篇 |
出版年
2019年 | 1篇 |
2015年 | 2篇 |
2014年 | 4篇 |
2013年 | 13篇 |
2012年 | 115篇 |
2011年 | 162篇 |
2010年 | 52篇 |
2009年 | 15篇 |
2008年 | 122篇 |
2007年 | 124篇 |
2006年 | 118篇 |
2005年 | 122篇 |
2004年 | 105篇 |
2003年 | 80篇 |
2002年 | 92篇 |
2001年 | 49篇 |
2000年 | 47篇 |
1999年 | 12篇 |
1998年 | 10篇 |
1997年 | 6篇 |
1996年 | 19篇 |
1995年 | 15篇 |
1994年 | 23篇 |
1993年 | 33篇 |
1992年 | 18篇 |
1991年 | 13篇 |
1990年 | 10篇 |
1989年 | 6篇 |
1988年 | 6篇 |
1987年 | 2篇 |
1986年 | 2篇 |
1985年 | 2篇 |
1982年 | 2篇 |
1981年 | 1篇 |
1980年 | 1篇 |
1976年 | 1篇 |
1970年 | 1篇 |
1948年 | 1篇 |
排序方式: 共有1407条查询结果,搜索用时 348 毫秒
81.
82.
83.
84.
85.
Structural transformation of molecular nitrogen to a single-bonded atomic state at high pressures 总被引:1,自引:0,他引:1
Eremets MI Gavriliuk AG Serebryanaya NR Trojan IA Dzivenko DA Boehler R Mao HK Hemley RJ 《The Journal of chemical physics》2004,121(22):11296-11300
The transformation of molecular nitrogen to a single-bonded atomic nitrogen is of significant interest from a fundamental stand point and because it is the most energetic non-nuclear material predicted. We performed an x-ray diffraction of nitrogen at pressures up to 170 GPa. At 60 GPa, we found a transition from the rhombohedral (R3c) epsilon-N(2) phase to the zeta-N(2) phase, which we identified as orthorhombic with space group P222(1) and with four molecules per unit cell. This transition is accompanied by increasing intramolecular and decreasing intermolecular distances. The major transformation of this diatomic phase into the single-bonded (polymeric) phase, recently determined to have the cubic gauche structure (cg-N), proceeds as a first-order transition with a volume change of 22%. 相似文献
86.
Mehmood A Malik A Anis I Khan PM Riaz M Makhmoor T Choudhary MI 《Natural product letters》2002,16(6):371-376
Two new oleanane triterpenes; 2alpha,3alpha,24-trihydroxyolean-12-ene-28,30-dioic acid ([structure: see text]) and 2alpha,3alpha,24,28-tetrahydroxyolean-12-ene ([structure: see text]) have been isolated from the roots of Atropa acuminata. Anti-oxidant p-hydroxyphenethyl trans-ferulate ([structure: see text]), beta-sitosterol-3-O-beta-D-glucopyranoside ([structure: see text]) and oleanolic acid ([structure: see text]) have also been reported for the first time from this species. The structures were determined by spectroscopic studies including 2D-NMR. 相似文献
87.
Atta-ur-Rahman Nasim S Baig I Sener B Orhan I Ayanoglu F Choudhary MI 《Natural product research》2004,18(5):465-471
Two new isoflavones 1 and 2 along with eleven known compounds 3-13, have been isolated for the first time from the rhizomes of Iris soforana. The structures of these compounds were determined on the basis of spectroscopic methods and found to be 5,3'-dihydroxy-4'-methoxy-6,7-methylenedioxyisoflavone (1) (Soforanarin A), and 5,7,5'-trimethoxy-6,3',4'-trihydroxyisoflavone (2) (Soforanarin B). 相似文献
88.
Lambropoulou DA Giokas DL Sakkas VA Albanis TA Karayannis MI 《Journal of chromatography. A》2002,967(2):243-253
A method has been developed for the trace determination of two sunscreen constituents (2-hydroxy-4-methoxybenzophenone and octyldimethyl-p-aminobenzoic acid) in water samples, which are commonly used in commercial formulations. The method employs solid-phase microextraction (SPME) and gas chromatography with flame ionization and mass spectrometric detection. The technique was developed with headspace and direct sampling in order to demonstrate the applicability of these SPME extraction modes for the identification of these two UV absorbing compounds in waters. The main parameters affecting the SPME process, such as desorption time, extraction time profile, salt additives, pH, and temperature, were investigated. The poly(dimethylsiloxane) 100-microm and polyacrylate 85-microm fiber coatings were found to be the most efficient for the extraction of these compounds from aqueous matrices. Linear calibration curves in the wide range of 10-500 microg/l were obtained for both compounds yielding typical RSD values of 5-9% for both extraction modes. The recoveries were relatively high, 82-98%, with quantitation limits below 1 microg/l. A comparison between the proposed methods and the conventional multiresidue solid-phase extraction revealed that the proposed technique(s) can be reliably used for sunscreen residue measurement in water samples with satisfactory results. 相似文献
89.
EI Rodriguez Martinez CI Barriga-Paulino MI Zapata CC Chinchilla AM López-Jiménez CM Gómez 《BMC neuroscience》2012,13(1):104-23
ABSTRACT: BACKGROUND: The peri-adolescent period is a crucial developmental moment of transition from childhood to emergent adulthood. The present report analyses the differences in Power Spectrum (PS) of the Electroencephalogram (EEG) between late childhood (24 children between 8 and 13 years old) and young adulthood (24 young adults between 18 and 23 years old). RESULTS: The narrow band analysis of the Electroencephalogram was computed in the frequency range of 0--20 Hz. The analysis of mean and variance suggested that six frequency ranges presented a different rate of maturation at these ages, namely: low delta, delta-theta, low alpha, high alpha, low beta and high beta. For most of these bands the maturation seems to occur later in anterior sites than posterior sites. Correlational analysis showed a lower pattern of correlation between different frequencies in children than in young adults, suggesting a certain asynchrony in the maturation of different rhythms. The topographical analysis revealed similar topographies of the different rhythms in children and young adults. Principal Component Analysis (PCA) demonstrated the same internal structure for the Electroencephalogram of both age groups. Principal Component Analysis allowed to separate four subcomponents in the alpha range. All these subcomponents peaked at a lower frequency in children than in young adults. CONCLUSIONS: The present approaches complement and solve some of the incertitudes when the classical brain broad rhythm analysis is applied. Children have a higher absolute power than young adults for frequency ranges between 0-20 Hz, the correlation of Power Spectrum (PS) with age and the variance age comparison showed that there are six ranges of frequencies that can distinguish the level of EEG maturation in children and adults. The establishment of maturational order of different frequencies and its possible maturational interdependence would require a complete series including all the different ages. 相似文献
90.
山水评测室 《卫星电视与宽带多媒体》2012,(9):48-54
我们采用已内置配合内置地面、有线电视参数的satellites.xml的DM800se G3-iCVS2#84A整合版的IMG进行测试。接收设置首先进行卫星配置,以我们地区的数字有线电视为例,在【卫星】项目里选择"数字有线电 相似文献