Solid state reactions of nitrogenous heterocyclic compounds(Ⅰ)——Solid state reactions of 3-methyl-l-phenyl-5-pyrazolone with carbonyl compounds

The solid state reaction of 3-methyl-1-phenyl-5-pyrazolone (MPP) with aromatic aldehydes and ke-tones benzil derivatives and imides,and the solid state Michael addition reaction of MPP with 4-arylidene-3-methyl-1-phenyl-5-pyrnzolone 2 were investigated.Some new solid state reactions between the reactants were found,from which a series of new compounds were obtained The structures of the products were identified by IR,1H NMR,MS,elemental analyses and also by X-ray crystal analysis,and the reaction mechanism of MPP with aromatic aldehydes and ketones was proposed     

335 GHz非平衡式肖特基二极管三倍频器

基于混合集成的方式,采用对称锥形渐变线匹配结构设计了335 GHz非平衡式三倍频器。在保证单模传输的条件下,该匹配结构不仅能够固定二极管位置,而且可以增大匹配效果,解决了高频段倍频器3 dB带宽较窄的问题。实测结果表明,该倍频器在330~356 GHz频率范围内输出功率均大于5 mW。驱动功率为220 mW时,有最高输出功率11.2 mW,由它作为核心器件组成的固态太赫兹本振源,能够驱动超外差接收机中670 GHz二次谐波混频器。     

InAs基范德华异质结界面电荷转移特性第一性原理计算的研究进展

由低维InAs材料和其他二维层状材料堆叠而成的垂直范德华异质结构在纳米电子、光电子和量子信息等新兴领域中应用广泛。探索跨结界面的电荷转移机制对于全面理解该类器件的非凡特性至关重要。第一性原理计算在揭示界面电荷转移特性与各种能量稳定型InAs基范德华异质结的电、光、磁等原理物理特性和器件性能变化之间的内在关系方面发挥着不可比拟的作用。文中梳理、总结和探讨了近年来InAs基范德华异质结间界面电荷转移特性的理论研究工作与潜在的功能应用,提出在理论方法和计算精度方面大力发展第一性原理计算的几个途径,为更好地开展InAs基范德华异质结的基础科学研究和应用器件设计提供可借鉴的量化研究基础。     

A rare-earth spectral traceability anti-counterfeiting detection technology

In this paper, a rare-earth spectral traceability anti-counterfeiting detection technology is proposed. Configure rare-earth samples No.1, No.2 and No.3 with different doping ratios. The spectral signals of these three samples are collected and integrated into a sample library. The traceability anti-counterfeiting detection is to compare the spectral information of the samples to be tested with the established sample library by selecting specific wavelength points for light intensity values. If the sample to be measured meets the light intensity range of the established sample library at a specific wavelength point, the sample model will be output. If it does not meet the light intensity range, the sample to be tested is fake. After testing, the anti-counterfeit rate of samples No.1, No.2 and No.3 can reach 100%. This testing process does not destroy the sample, and the anti-counterfeit effect is unique and reliable.     

5G时代,有线接入网基础资源布局思路探讨

双千兆时代,网络规模空前巨大,有线接入网更是因覆盖范围广,建设规模大,投入人力多,投资占比高等因素,成为研究重点。文章根据有线接入网架构演进,从“点(各类业务及分纤点)、线(各级管线)、面(业务汇聚区)”三个层面对基站、家客、集客等业务接入、分纤点规划及业务汇聚机房等基础资源规划进行研究。     

基于EDMA的TMS320C6713片外Flash自举引导

在基于DSP的系统设计中,为了保证掉电时程序不丢失,总是将程序保存在非易失性存储器中,以便系统在上电复位时可将其引导到DSP内部的RAM中执行.以TI公司的TMS320C6713浮点DSP和AMD公司的AM29LV040 Flash存储器为例,通过JTAG加载来设计一个完整的自举引导方案.着重描述了引导引脚以及相关寄存器的设置,分析了采用EDMA传输方式将代码从Flash复制到DSP的过程,并对引导程序给出基于汇编语言的代码实现.工程实践证明,该设计方案是可行、有效的.     

基于WebGL的3D立库可视化系统设计与实现

针对当前扩大化和普及化的仓储物流,提出了一种3D自动化立体仓库可视化系统的实现方案,用以解决仓储系统中遇到的数据不直观的问题.该系统采用JavaScript编程语言,以Three.js引擎为基础,构建了基于WebGL的三维自动化立体仓库的可视化系统,该系统能有效直观的进行仓储管理,适合现代化仓储企业的管理需求.     

基于海天线提取和混合灰度差的船舶检测方法

为了快速、准确检测海天背景下远距离水平观测的船舶目标,提出了一种基于海天线提取和混合灰度差的船舶检测方法.首先,利用边缘检测算法将图像分为天空、海天线和海面三个区域,并根据海天区域连接点,采用直线拟合方法确定海天线的直线参数;然后提取海天线区域作为目标感兴趣区域,并在去除海面杂波和噪声等干扰后利用混合灰度差水平投影和垂...     

Cs(6P)激发态的辐射及与Ne碰撞的能量转移

应用激光吸收和荧光方法,测量了Cs(6P)态与Ne碰撞的精细结构转移和碰撞猝灭截面.Cs原子被激光激发到6P3/2态,将与泵浦激光束反向平行的检测激光束调到6PJ→8S1/2的跃迁,测量6PJ激发态的密度及空间分布,由此计算了6PJ→6S的有效辐射率.在T=337 K和Ne密度0.5×1018＜N＜4×1018cm-3范围内测量了6P1/2→6S1/2(895 nm)发射的敏化荧光强度I895,量N/I895与N有抛物线型的关系,表明6PJ的猝灭是由于与Ne原子的碰撞产生的,而不是由与Cs基态原子碰撞产生的.由最小二乘法确定的二次多项式的系数得到6P态与Ne碰撞精细结构转移截面σ21=(1.90±0.82)×10-19 cm2,猝灭截面σD=(8.97±3.85)×10-19 cm2.     

Friedmann Cosmology with a Generalized Equation of State and Bulk Viscosity

The universe content is considered as a non-perfect fluid with bulk viscosity and is described by a more general equation of state (endowed some deviation from the conventionally assuned cosmic perfect fluid model).We assume the bulk viscosity is a linear combination of two termsone is constant,and the other is proportional to the scalar expansion θ = 3a/a.The equation of state is described as p = (γ - 1)p p0,where p0 is a parameter.In this framework we demonstrate that this model can be used to explain the dark energy dominated universe,and different proper choices of the parameters may lead to three kinds of fates of the cosmological evolutionno future singularity,big rip,or Type-Ⅲ singularity as presented in [S.Nojiri,S.D.Odintsov,and S.Tsujikawa,Phys.Rev.D 71 (2005) 063004].