首页 | 本学科首页   官方微博 | 高级检索  
文章检索
  按 检索   检索词:      
出版年份:   被引次数:   他引次数: 提示:输入*表示无穷大
  收费全文   5142篇
  免费   219篇
  国内免费   45篇
化学   3002篇
晶体学   38篇
力学   178篇
数学   442篇
物理学   1027篇
无线电   719篇
  2024年   20篇
  2023年   42篇
  2022年   219篇
  2021年   260篇
  2020年   197篇
  2019年   191篇
  2018年   218篇
  2017年   159篇
  2016年   225篇
  2015年   181篇
  2014年   208篇
  2013年   400篇
  2012年   310篇
  2011年   318篇
  2010年   198篇
  2009年   167篇
  2008年   193篇
  2007年   202篇
  2006年   159篇
  2005年   160篇
  2004年   107篇
  2003年   100篇
  2002年   111篇
  2001年   87篇
  2000年   67篇
  1999年   72篇
  1998年   36篇
  1997年   38篇
  1996年   61篇
  1995年   52篇
  1994年   39篇
  1993年   36篇
  1992年   41篇
  1991年   45篇
  1990年   22篇
  1989年   27篇
  1988年   30篇
  1987年   28篇
  1986年   34篇
  1985年   38篇
  1984年   25篇
  1983年   26篇
  1982年   28篇
  1981年   14篇
  1980年   32篇
  1979年   22篇
  1978年   33篇
  1977年   29篇
  1976年   18篇
  1973年   11篇
排序方式: 共有5406条查询结果,搜索用时 78 毫秒
71.
72.
Base station's location privacy in a wireless sensor network (WSN) is critical for information security and operational availability of the network. A key part of securing the base station from potential compromise is to secure the information about its physical location. This paper proposes a technique called base station location privacy via software-defined networking (SDN) in wireless sensor networks (BSLPSDN). The inspiration comes from the architecture of SDN, where the control plane is separated from the data plane, and where control plane decides the policy for the data plane. BSLPSDN uses three categories of nodes, namely, a main controller to instruct the overall operations, a dedicated node to buffer and forward data, and lastly, a common node to sense and forward the packet. We employ three kinds of nodes to collaborate and achieve stealth for the base station and thus protecting it against the traffic-analysis attacks. Different traits of the WSN including energy status and traffic density can actively be monitored by BSLPSDN, which positively affects the energy goals, expected life of the network, load on common nodes, and the possibility of creating diversion in the wake of an attack on the base station. We incorporated multiple experiments to analyze and evaluate the performance of our proposed algorithm. We use single controller with multiple sensor nodes and multiple controllers with multiple sensor nodes to show the level of anonymity of BS. Experiments show that providing BS anonymity via multiple controllers is the best method both in terms of energy and privacy.  相似文献   
73.

In communication industry one of the most rapidly growing area is wireless technology and its applications. The efficient access to radio spectrum is a requirement to make this communication feasible for the users that are running multimedia applications and establishing real-time connections on an already overcrowded spectrum. In recent times cognitive radios (CR) are becoming the prime candidates for improved utilization of available spectrum. The unlicensed secondary users share the spectrum with primary licensed user in such manners that the interference at the primary user does not increase from a predefined threshold. In this paper, we propose an algorithm to address the power control problem for CR networks. The proposed solution models the wireless system with a non-cooperative game, in which each player maximize its utility in a competitive environment. The simulation results shows that the proposed algorithm improves the performance of the network in terms of high SINR and low power consumption.

  相似文献   
74.
75.
76.
Optogalvanic spectra of some 30 transitions of calcium originating from the ground state as well as from several excited states (4s4p 1,3P, 4s3d 1,3D, 4s5p 3P, 3d4p 3D, 3F) have been investigated using laser-irradiation of a low-current glow discharge in a thermionic diode. The influence of various experimental parameters such as bias field, oven temperature and buffer gas pressure on the spectra are reported. Seven previously unreported transitions are recorded including four forbidden transitions which violate the J selection rules. An interesting anomaly observed in the non-statistical population of the 4s3d 3D3,2,1 multiplet is discussed where the populations of 3D3:3D2:3D1 are in the ratio of 94:5:1. A possible explanation is based on avoided crossing between potential energy curves of the Ca-Ar molecule.  相似文献   
77.
Amides or vinylogous amides react with tosyl chloride-pyridine to form activated intermediates which condense with Fischer's base or their vinylogs to give carbocyanine structures. Under the same conditions formylated Fischer's base reacts with vinylogous Fischer's bases to give trinuclear carbocyanines in good yields. Their structure and the limitations of this route are discussed.  相似文献   
78.
Usnic acid, a lichen substance, has a wide range of pharmaceutical applications, including antibiotic, antimycotic, antifeedant, antitubercular, antitumor, and analgesic activities. Some products containing usnic acid are marketed as weight control supplements; however, hepatotoxicity and acute liver failures were reported as severe side effects. The usnic acid content present in the plant materials and market products was analyzed by reversed-phase high-pressure liquid chromatography with a photodiode array detector at 233 nm. A Waters XTerra RP18 (150 x 4.6 mm; 5 microm particle size) column was the stationary phase; mobile phase was aqueous 0.1% acetic acid and acetonitrile gradient at flow rate of 1.0 mL/min. The temperature was held constant at 30 degrees C. The retention time of usnic acid was approximately 13.3 min. Acetone extraction of the samples took place with sonication. The precision of the method was confirmed by a standard deviation below 3.0% (n=3) and usnic acid recovery was 99.0%. Limit of detection was 0.4 microg/mL and the response was linear from 1.4 to 570.0 microg/mL with a correlation coefficient (R2) of 0.9991. The content of usnic acid in 4 raw materials and 22 finished products was analyzed.  相似文献   
79.
5-Azido-4-cyano-1-phenylpyrazole reacts with benzylcyanide in the presence of sodium methoxide to give the title ring system.  相似文献   
80.
A series of new dissymmetric chiral Schiff base complexes has been obtained by a systematic condensation of (1S,2S)(+)-diaminocyclohexane and 3-acetyl-4-hydroxy-6-methyl-2-pyrone with salicylaldehyde, 5-chloro-, 5-methoxy-and 5-nitrosalicylaldehyde and by subsequent metallation with manganese and ruthenium. The characterization of the complexes 1–8 was accomplished by physico chemical studies viz. microanalysis, IR-, UV/VIS-, and CD spectral studies, optical rotation, molar conductance measurements and cyclic voltammetry. Enantioselective epoxidation of non functionalised olefins, viz. cis-stilbene, trans-3-nonene and trans-4-octene with iodosyl benzene as oxidant was demonstrated in the presence of catalytic amounts of chiral Mn(III) and Ru(III) dissymmetric Schiff base complexes. Good optical yields of epoxides were obtained for the catalyst 4 with the substrates trans-3-nonene and cis-stilbene.  相似文献   
设为首页 | 免责声明 | 关于勤云 | 加入收藏

Copyright©北京勤云科技发展有限公司  京ICP备09084417号