机械转向器冲击试验台建模与仿真

EPS用机械转向器是实现汽车转向的主要部件之一,为保证车辆的安全性,需要了解其耐冲击性能。机械转向器冲击试验台主要用于对机械转向器的冲击试验。文中针对试验台的阀控非对称缸电液力控制系统进行了研究。通过对控制系统的各个环节的分析,建立各环节的数学模型。进而得到以力为控制量的电液伺服系统数学模型,并利用Simulink仿真平台对系统进行频域和时域分析。分析结果表明,试验台液压系统闭环稳定,满足性能要求。     

转向器试验台液压位置伺服系统建模与仿真

随着对汽车安全性以及舒适性要求的提高,汽车厂商对于负载模拟系统的动态响应和控制精度也有了更高的要求。在电机控制系统中,参数的突变会引起试验台的稳定性降低并且伴有震荡产生。为克服震荡,文中使用伺服控制液压马达模拟EPS的方向盘系统以及负载系统代替原有的电机控制。通过Simulink仿真得到的系统阶跃响应图和Bode图分析发现,该试验台液压系统闭环稳定,且在一定程度上克服了震荡现象,具有可借鉴性。     

智能电网需求侧响应评价指标研究

本文针对实施的智能电网需求侧响应,提出综合效益评价法,从电网运行经济性的提高、对电网运行可靠性的提高、促进可再生能源消纳的能力以及对调度灵敏性的提高四个方面建立了评价指标,对需求侧响应实施后的智能电网做出全方位、客观的评价,更好的适应电力市场改革.     

基于捕集柱阵列的制备型二维液相色谱纯化烟草中的4个组分

二维液相色谱(2D-LC)因具有较高的峰容量,在复杂样品的分离分析中获得了广泛的关注。然而,制备型2D-LC以纯化高纯单体为目标,在方法开发和设备构成等方面与分析型2D-LC有较大的不同,目前尚未得到充分的开发,在大规模的制备纯化中应用较少。本文以一套制备液相色谱模块为分离系统,以稀释泵、切换阀和捕集柱阵列为接口,构建了新型的制备型2D-LC系统,旨在规模化纯化多个活性成分。以烟叶中可以用作医药原料的烟碱、绿原酸、芦丁和茄尼醇等组分为目标物,考察了不同类型填料对样品的捕集效率、过载条件下的色谱保留行为等,优化了制备色谱条件。进而利用在线2D-LC系统实现了烟叶提取物的纯化,通过一次运行获得了4个高纯化合物。该系统具有中压色谱纯化成本低、系统在线运行自动化程度高、稳定性好及容易放大等优点。烟叶中活性化学成分的回收利用对促进烟草行业的发展及带动地方农业经济开发具有重大的意义。     

新型两性聚电解质高吸水性树脂CMCTS-g-（PAA-co-PTMAAC）的制备研究

通过氧化还原引发荆引发的接枝共聚反应,使阴离子型单体丙烯酸(AA)和阳离子型单体三甲基烯丙基氯化铵(TMAAC)在羧甲基壳聚糖(CMCTS)的分子链上接枝共聚,制得羧甲基壳聚糖接枝-(聚丙烯酸-co-聚三甲基烯丙基氯化铵)(CMCTS-g-(PAA-co-PTMAAC)两性聚电解质高吸水性树脂.采用红外光谱对产物的结构进行了表征,比较了反应条件对产物吸液性能的影响.发现制备具有良好吸液性能的高吸水性树脂的最优化反应条件为:TMAAC占单体总质量的14.3%,mNNMBA/mAA值在0.014附近,单体总质量为CMCTS质量的9.33倍,丙烯酸中和度在20%～30%之间.研究发现,随外部溶液pH值的变化,两性聚电解质高吸水性树脂的溶胀性能在酸性和碱性条件下各有一个最大值,在等电点处产物的吸液性相对较低.     

太阳能自动追踪系统的设计与研究

太阳能具有可再生、分布地域广、使用清洁、经济效益高等优势,是理想的新能源,其开发使用是解决能源短缺、温室效应和环境污染等问题的有效途径。本文开发了一套太阳能自动追踪系统,该系统能够使得太阳能电池板及集热管始终垂直于太阳光线,最大限度的采集太阳能。在保证成本低廉、结构简单的前提下,实现了较高的跟踪精度。     

Adsorbed para-nitrophenol on HDTMAB organoclay--a TEM and infrared spectroscopic study

para-Nitrophenol adsorbed on hexadecyltrimethylammonium bromide modified montmorillonite has been studied using a combination of X-ray diffraction TEM and infrared spectroscopy. Upon formation of the organoclay, the properties change from hydrophilic to hydrophobic. It is proposed that para-nitrophenol is adsorbed onto the water in the cation hydration sphere of the organoclay. As the cation is replaced by the surfactant molecules the para-nitrophenol replaces the surfactant molecules in the clay interlayer. Significant changes in the water vibrations occur in this process. Bands attributed to CH stretching and bending vibrations in general decrease as the concentration of the surfactant (CEC) increases up to 1.0 CEC. After this concentration the bands increase approaching a value the same as that of the surfactant. Strong changes occur in the HCH deformation modes of the methyl groups of the surfactant. These changes are attributed to the methyl groups locking into the siloxane surface of the montmorillonite. Such a concept is supported by changes in the SiO stretching bands of the montmorillonite siloxane surface. This study demonstrates that para-nitrophenol will penetrate into the untreated clay interlayer and replace the intercalated surfactant in surfactant modified clay, resulting in the change of the arrangement of the intercalated surfactant.     

Changes in the surfaces of adsorbed p-nitrophenol on methyltrioctadecylammonium bromide organoclay--an XRD, TG, and infrared spectroscopic study

Water purification is of extreme importance worldwide. p-Nitrophenol was used as a test chemical to design and test an organoclay for the removal of p-nitrophenol from an aqueous solution. Synthesis of the organoclay with methyltrioctadecylammonium bromide [CH(3)(CH(2))(17)](3)NBr(CH(3)) labeled as MTOAB results in multiple expansions of the montmorillonite clay from 1.24 nm to a maximum of 5.20 nm as is evidenced by the XRD patterns. Thermal analysis shows strong bonding of the surfactant to the clay siloxane layers and the interaction of the p-nitrophenol with the clay surfaces. It is proposed that the p-nitrophenol penetrates the siloxane layer of the clay and bonds through the ditrigonal space of the siloxane hexagonal units to the inner OH units. Such a concept is supported by the observation of an additional infrared band at 3652 cm(-1) for the organoclay. Shifts in the p-nitrophenol OH stretching vibrations mean a strong interaction of the p-nitrophenol molecule. Significant changes in the siloxane stretching bands are also observed.