Aperture-Adjustable and Repairable Metal-Based MOFs Catalysis Membrane for Water Purification

Precise adjustment of the pore size, damage repair, and efficient cleaning is all challenges for the wider application of inorganic membranes. This study reports a simple strategy of combining dry-wet spinning and electrosynthesis to fabricate stainless-steel metal–organic framework composite membranes characterized by customizable pore sizes, targeted reparability, and high catalytic activity for membrane cleaning. The membrane pore size can be precisely customized in the range of 14–212 nm at nanoscale, and damaged membranes can be repaired by targeted treatment in 120 s. In addition, advanced oxidation processes can be used to quickly clean the membrane and achieve 98% flux recovery. The synergistic actions of the membrane matrix and the selective layer increase the adsorption energy of active sites to oxidant, shorten the electron transfer cycle, and enhance the overall catalytic performance. This study can provide a new direction for the development of advanced membranes for water purification and high-efficiency membrane cleaning methods.     

Femtosecond Laser 4D Printing of Light-Driven Intelligent Micromachines

Intelligent micromachines that respond to external light stimuli have a broad range of potential applications, such as microbots, biomedicine, and adaptive optics. However, artificial light-driven intelligent micromachines with a low actuation threshold, rapid responsiveness, and designable and precise 3D transformation capability remain unachievable to date. Here, a single-material and one-step 4D printing strategy are proposed to enable the nanomanufacturing of agile and low-threshold light-driven 3D micromachines with programmable shape-morphing characteristics. The as-developed carbon nanotube-doped composite hydrogel simultaneously enhanced the light absorption, thermal conductivity, and mechanical modulus of the crosslinked network, thus significantly increasing the light sensitivity and response speed of micromachines. Moreover, the structural design and assembly of asymmetric microscale mechanical metamaterial unit cells enable the highly efficient additive nanomanufacturing of 3D shape-morphable micromachines with large dynamic modulation and spatiotemporal controllability. Using this strategy, the world's smallest artificial beating heart with programmable light-stimulus responsiveness for the cardiac cycle is successfully printed. This 4D printing method paves the way for the construction of multifunctional intelligent micromachines for bionics, drug delivery, integrated microsystems, and other fields.     

Proximity-Induced Fully Ferromagnetic Order with Eightfold Magnetic Anisotropy in Heavy Transition Metal Oxide CaRuO3

Ferromagnetic materials with a strong spin-orbit coupling (SOC) have attracted much attention in recent years because of their exotic properties and potential applications in energy-efficient spintronics. However, such materials are scarce in nature. Here, a proximity-induced paramagnetic to ferromagnetic transition for the heavy transition metal oxide CaRuO₃ in (001)-(LaMnO₃/CaRuO₃) superlattices is reported. Anomalous Hall effect is observed in the temperature range up to 180 K. Maximal anomalous Hall conductivity and anomalous Hall angle are as large as ∼15 Ω⁻¹ cm⁻¹ and ∼0.93%, respectively, by one to two orders of magnitude larger than those of the typical 3d ferromagnetic oxides such as La_0.67Sr_0.33MnO₃. Density functional theory calculations indicate the existence of avoid band crossings in the electronic band structure of the ferromagnetic CRO layer, which enhances Berry curvature thus strong anomalous Hall effects. Further evidences from polarized neutron reflectometry show that the CaRuO₃ layers are in a fully ferromagnetic state (∼0.8 μ_B/Ru), in sharp contrast to the proximity-induced canted antiferromagnetic state in 5d oxides SrIrO₃ and CaIrO₃ (∼0.1 μ_B/Ir). More than that, the magnetic anisotropy of the (001)-(LaMnO₃/CaRuO₃) superlattices is eightfold symmetric, showing potential applications in the technology of multistate data storage.     

面向鲁棒频谱感知的模糊K-means++算法

恶意用户通过向数据融合中心发送伪造的频谱感知数据,解决自身频谱资源短缺问题,但会极大地降低频谱感知系统的检测概率。为了解决此问题,提出了基于模糊K means++的数据融合算法。该算法首先引入模糊处理机制处理样本的数据特征值,以此来增加样本间的差异性;然后将模糊处理后的数据发送到融合中心,融合中心采用离群点挖掘的方法排除恶意用户,并对保留下来的用户进行融合,使样本向量具有鲁棒性;最后运用K means++算法对样本向量进行聚类。该算法利用轮盘法选择聚类中心,可有效抵御恶意用户的攻击,提高系统感知性能;无需知晓信号与噪声的分布等一些先验信息,也避免了繁杂的门限推导。从仿真结果可以看出,该算法对抵御恶意用户攻击具有突出的效果,有效提升了协同频谱感知系统的稳定性和鲁棒性。     

Cryptanalysis of Two Signature Schemes for IoT and Mobile Health Systems

Wireless Personal Communications - Recently, Lee et al. (Sensors 20(14): 3983, 2020) proposed a certificateless aggregate arbitrated signature scheme CLAAS for IoT environments. Addobea et...     

基于90°电桥芯片的小型化和差器设计

介绍了一种基于90°电桥芯片的和差器的设计原理、封装测试方法以及实测结果。针对小型化设计、测试的难点进行攻关,在低温共烧陶瓷(LTCC)基板表贴电桥芯片,并在基板内部引出走线至基板表面,形成测试端口;利用微组装技术实现小型化高集成设计方案。在此基础上设计封装壳体,实现芯片气密封装,提高工程应用可靠性。根据组件实测结果,驻波比小于1.8,幅度一致性优于±0.8 dB,相位一致性优于10°,质量为35 g。     

飞秒激光加工镍基高温合金叶片气膜孔的试验研究北大核心CSCD

分析了飞秒激光与镍基高温合金的相互作用机理,对于飞秒激光加工的热影响区极小做出了理论解释;对单脉冲的激光光源项进行改进,使用螺旋加工法,进行了飞秒激光加工镍基高温合金气膜孔加工试验,得到了激光功率、离焦量、单层进给量、单层扫描时间对于加工质量的影响规律,找到了最优工艺参数,对设计激光加工工艺参数提供理论参考。     

基于差和共阵的新型高自由度互质阵

针对均匀线列阵自由度(DOF)受限于阵元数的问题,该文提出一种基于差和共阵的新型互质阵,称为放置互质阵(DCA),其借助由接收信号的时域和空域信息组合成的共轭增广矩阵得到等价的差和共阵来进行波达方向(DOA)估计.DCA将广义互质阵放置在与原点处单阵元相隔一定距离的位置,实现了和共阵与差共阵的阵元位置互补,从而最大限度上利用和共阵带来的自由度增幅.该文给出了DCA阵元位置和放置距离的闭式表达,随后分别对DCA的差共阵及和共阵的连续阵元及孔洞位置进行了理论分析,同时给出了两者间的关系,说明了DCA的高自由度特性.多个仿真实验验证了所提阵型DOA估计的有效性.     

一种人与人和机器到机器共存下能效最大化的上行用户分配算法

针对5G超密集异构蜂窝网络中人与人(H2H)和机器到机器(M2M)共存场景下有服务质量(QoS)保障和负载均衡的上行用户分配问题,该文提出一种基于匹配理论的用户分配算法.该算法在用户分配过程中同时考虑不同类型节点的接入控制策略,在最大化网络能效的同时,实现节点QoS保障.仿真结果表明,与其他算法相比,该算法不仅能够在能效、负载均衡以及QoS保障方面获得更好的性能,并且能获得与穷举法相近的性能.此外,所提算法的收敛速度很快且不受节点和基站数目变化的影响,适合解决H2H和M2M共存场景中的用户分配问题.     

Improve the quality of charging services for rechargeable wireless sensor networks by deploying a mobile vehicle with multiple removable chargers

Wireless Networks - The increasing demand for real-time applications of Wireless Sensor Networks (WSNs) makes Quality of Service (QoS)-based charging scheduling models an interesting and hot...