Theoretical studies on the reaction path and dynamics of the reaction CH_3+H_2O→CH_4+OH

The reaction path, the dynamical properties along the reaction path and CVT rate constants are computed by the ab initio MO method, the reaction path Hamiltonian theory and the variational transition state theory. The results show that the effect of the electron correlation energy on activation barrier is large, the recrossing and tunneling effects exist in the reaction.     

气相色谱质谱法快速测定人血浆中克仑特罗

血浆样品经0.01mol·L-1盐酸和无水乙醇浸取,在碱性条件下用氯仿萃取,GG-MS-选择离子测量法测定,外标法定量。在选定的色谱条件下,盐酸克仑特罗的检出限为0.05ng,线性范围为0.1-100ng,方法的平均回收率为95.6％,RSD小于6.82％(n=6)。该法毋需衍生化,基质无干扰,简便可靠,适用于生物材料中克仑特罗的快速分析。     

三芳基膦配体的合成研究

从间溴苯酚出发, 利用新的合成方法经五步反应合成了一系列具有不同烷氧基的芳基膦配体. 改进后的方法可方便地通用于在苯环上具有各种不同基团基的膦配体衍生物的合成, 且有原料易得、操作简单、产率较高的优点.     

Advanced Current Collectors for Alkali Metal Anodes

High-energy-density batteries are in urgent need to solve the ever-increasing energy storage demand for portable electronic devices, electric vehicles, and renewable solar and wind energy systems. Alkali metals, typically lithium(Li), sodium(Na) and potassium(K), are considered as the promising anode materials owing to their low electrochemical potential, low density, and high theoretical gravimetric capacities. However, the problem of dendrite growth of alkali metals during their plating/stripping process will lead to low Coulombic efficiencies, a short lifespan and huge volume expansion, eventually hindering their practical commercialization. To resolve this issue, a very effective approach is engineering the anodes on structured current collectors. This review summarizes the development of the alkali metal batteries and discusses the recent advances in rational design of anode current collectors. First, the challenges and strategies of suppressing alkali-metal dendrite growth are presented. Then the special attention is paid to the novel current collector design for dendrite-free alkali metal anodes. Finally, we give conclusions and perspective on the current challenges and future research directions toward advanced anode current collectors for alkali metal batteries.     

A Novel, Simple and Efficient Synthesis of Ferrocenyl Enones and Alkynols

Propargylic alcohols are versatile precursors to many organic molecules including natural products and pharmaceutical compounds.[1] In our continuing interest in the development of practical methods for synthesis of ferrocene derivatives, we decided to investigate the efficiencies of ferrocenylacetylene addition to aromatic aldehydes under t-BuOKcatalyzed condition.[2] Interestingly, we found that the usually reliable coupling reaction between terminal alkyne of type 1 and aromatic aldehydes of type 2 does not furnish the expected propargylic alcohols, but that the isomeric aryl enones 3are found in high yield and very short reaction time (10～20 min). This provided a promising protocol for preparation of ferrocenyl chalcones in a practical, economical and mild sense compared with the traditional method. To the best of our knowledge, this unusual reaction was first observed for the addition of ferrocenylacetylene to aldehyde in a base-catalyzed manner (Eq. 1).     

基于DFRFT水下动目标LFM回波检测算法

匹配滤波器作为高斯白噪声背景下线性调频信号的最优检测器,在水下声信号处理中得到了广泛的应用。根据匹配滤波器输出峰值位置可以获得目标距离的估计,但运动目标径向速度造成的回波和样本失配将导致匹配滤波器检测性能下降。利用分数阶傅里叶变换对线性调频信号的聚焦特性,提出了应用离散分数阶傅里叶变换的水下运动目标线性调频回波检测算法。仿真测试表明,该算法对于混响噪声背景下径向速度未知动目标的线性调频回波具有良好的检测性能。     

舰载防空反导激光武器作战需求分析

随着激光技术的日益成熟和水面舰艇面临的防空作战环境越来越严峻,激光武器逐渐体现出在水面舰艇防空反导作战中的明显优势和特点.介绍了激光武器对目标的毁伤机理,通过与普通舰载火炮和防空导弹武器相比较,论述了激光武器在防空反导中的作战运用特点和优势.结合对未来水面舰艇面临防空作战环境特点的分析,提出发展舰载防空反导激光武器的作战需求.并综述了国外海军舰载防空反导激光武器系统的发展历程和研究现状.     

激光扫描测量信号边界检出方法研究

信号边界检出是激光扫描测量系统实现稳定和高精度测量的关键技术之一.本文对标准电平切割法和二次微分法等边界检出方法的特点进行了分析和比较.基于光电共轭原理,设计了一种可实现光电共轭信号边界检出的新型电路,并使用仿真软件Multisim对该电路进行了动态仿真,表明该电路采用测量信号的自共轭函数作为参考基准,通过确定两共轭交点可稳定实现信号的边界检出.实验验证了该甄别电路,具有灵敏度高、自适应特性好的优点.     

基于单电子晶体管的数字滤波器硬件实现

基于互补型单电子晶体管（SET）逻辑门，提出了SET加法器、移位寄存器和ROM的单元电路。在讨论数字滤波器硬件实现原理基础上，由这三个单元电路实现了一个二阶IIR滤波器。SET的SPICE宏模型验证了设计的正确性。     

无线移动数字图像传输系统MDG

详细介绍了基于4OQAM技术搭建的MDG无线移动数字图像传输系统,分析了其性能指标,提出了无线移动数字图像传输系统的系统解决方案,为广电系统突发新闻、文体活动等电视现场直播开辟了新的传输方式.