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71.
Dissociative Chemisorption of an H2(v,j) Molecule on Rigid Ni (100) Surface: Dependence on Surface Topologies and Initial Rovibrational States of the Molecules
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MeryemEvecen MustafaBǒyǚkata MehmetCivi ZiyaB.Gǚvenc 《中国物理快报》2005,22(2):420-423
The H2(v,j) Ni(100) collision system has been studied to understand the effects of the surface sites and initial rovibrational states of the molecule on molecule-surface interactions, by a quasiclassical molecular dynamic simulation method. Dissociative adsorption of an H2 molecule on the rigid Ni(100) surface is investigated at topologically different three sites of the surface. Interaction between the molecule and Ni surface was described by a London-Eyring-Polani-Sato (LEPS) potential. Dissociative chemisorption probabilities of the H2(v, j) molecule on various sites of the surface are presented as a function of the translation energies between 0.001-1.0eV. The probabilities obtained at each collision site have unique behaviour. At lower collision energies, indirect processes enhance the reactivity, effects of the rotational excitations and impact sites on the reactivity are more pronounced. The results are compared with the available studies. The physical mechanisms underlying the results and quantum effects are discussed. 相似文献
72.
杂波抑制抑制杂波是许多雷达系统中主要考虑的问题。利用动目标显示(MTI)或脉冲多卜勒(PD)原理就可以实现杂波对消。MTI或PD的设计取决于雷达的特殊性能和所确定的杂波形式。特别重要的是:是否只抑制固定的(零多卜勒)杂波或者还须抑制运动的杂波(云雨、金属箔条)。为了抑制固定的地杂波,有人曾 相似文献
73.
How to select a generator of Zp* is an important problem in cryptographic applications, where p is an odd prime. In this paper, we mainly consider the especial case that p is a safe prime, and give an algorithm for selecting a generator of Zp*,and find all generators of Zp* , where p is a safe prime. Our algorithm is more faster than the algorithm in [1]. Based on the proposed algorithm, one could find all generators of Zp* as well, where p is a perfect prime. 相似文献
74.
A.R.ELAMROUSS 《数学学报(英文版)》2005,21(1):129-142
This paper contains a generalization of the well-known Palais-Smale and Cerami compactness conditions. The compactness condition introduced is used to prove some general existence theorems for critical points. Some applications are given to differential equations. 相似文献
75.
Iso-condensed heteroaromatic pyrroles 1 are 10π-electron aromatic compounds. They are of interest from both theoretical and synthetic points of view. They are the cyclic analogues of heteroaromatic ortho-quinodimethanes 2, and can react with dienophiles in a Diels-Alder reaction to give the synthetically useful cycloadducts 3. Many of them are also of potential pharmaceutical importance because they are isosteric with indoles. Iso-condensed heteroaromatic pyrroles 1 can be used also as the m… 相似文献
76.
YAN Xiaomin ZHAO Lin SHAO Jianhui TAN Xin SONG Zhengxiao School of Chemical Engineering Technology Tianjin University Tianjin China Slichem Liquid Material Co. Ltd. Shijiazhuang China 《Chinese Journal of Reactive Polymers》2004,(Z1)
1. INTRODUCTION Methionine, namely 2-amido-4-thiomethyl butyric acid with a structure of CH3SCH2CH2CHCOOH, is one of the essential amino acids and has two natural enantionmers, D and L-methionine. The mixture of L- and D-isomers can be used as analeptics or nutritive additives to maintain the equilibrium of amino acids of feed [1,2]. L-methionine can release active methyl and accelerate the synthesis of choline, which further speeds up the conversion of the lipid accumulated in liv… 相似文献
77.
CUI Xiao-bing ZHENG Shou-tian SUN Yan-qiong YANG Guo-yu ** . Coordination Hydrothermal Chemistry Group State Key Laboratory of Structural Chemistry Fujian Institute of Research on the Structure of Matter Chinese Academy of Sciences Fuzhou P. R. China . State Key Laboratory of Coordination Chemistry Najing University Nanjing P. R. China 《高等学校化学研究》2004,(1)
IntroductionPolyoxometalatesarewidelystudiedfortheirin terestingapplicationsincatalysis ,electronicconduc tivity ,magnetism ,nonlinearopticsandmedicine[1— 4 ] .Whilethemechanismofthesynthesisofpolyoxometalatesremainselusiveandisoftende scribedasself assembly ,thereseemstobeanincreas inguseofthecombinationofthehydrothermalmethodandthestructure directingtemplate .There searchwiththismethodhasdemonstratedthatanum beroftransitionmetaloxides ,typicallyreducedmolybdenumoxides ,mixedvalancevanadiumo… 相似文献
78.
Li-ming Wu~ Zheng-liang Zhang~ Laboratoire de Mathématiques Appliquées.CNRS-UMR Université Blaise Pascal Aubière France 《应用数学学报(英文版)》2004,(3)
Using the method of Girsanov transformation,we establish the Talagrand's T_2-inequality for dif-fusion on the path space C([0,N],R~d) with respect to a uniform metric,with the constant independent of N.This improves the known results for the L~2-metric. 相似文献
79.
Quan Sen JIU Department of Mathematics Capital Normal University Beijing P.R.China Cheng HE Institute of Applied Mathematics Academy of Mathematics System Sciences Chinese Academy of Sciences Beijing P.R.China 《应用数学学报(英文版)》2004,(4)
In this paper we are interested in the sufficient conditions which guarantee the regularityof solutions of 3-D ideal magnetohydrodynamic equations in the arbitrary time interval [0,T].Fivesufficient conditions are given.Our results are motivated by two main ideas:one is to control theaccumulation of vorticity alone;the other is to generalize the corresponding geometric conditions of3-D Euler equations to 3-D ideal magnetohydrodynamic equations. 相似文献
80.
We observe enhanced terahertz (THz) radiation generated from a Si3N4 film-coated GaAs photoconductive dipole antenna. Compared to an uncoated antenna with identical electrode geometry and optical excitation power, the Si3N4 film-coated antenna has a higher effective DC resistance and larger breakdown voltage. As a result, the peak amplitude of generated THz radiation is significantly enhanced due to the Si3N4 film-coated layer. 相似文献