Surface Reconstruction Engineering with Synergistic Effect of Mixed-Salt Passivation Treatment toward Efficient and Stable Perovskite Solar Cells

Surface passivation treatment is a widely used strategy to resolve trap-mediated nonradiative recombination toward high-efficiency metal-halide perovskite photovoltaics. However, a lack of passivation with mixture treatment has been investigated, as well as an in-depth understanding of its passivation mechanism. Here, a systematic study on a mixed-salt passivation strategy of formamidinium bromide (FABr) coupled with different F-substituted alkyl lengths of ammonium iodide is demonstrated. It is obtained better device performance with decreasing chain length of the F-substituted alkyl ammonium iodide in the presence of FABr. Moreover, they unraveled a synergistic passivation mechanism of the mixed-salt treatment through surface reconstruction engineering, where FABr dominates the reformation of the perovskite surface via reacting with the excess PbI₂. Meanwhile, ammonium iodide passivates the perovskite grain boundaries both on the surface and top perovskite bulk through penetration. This synergistic passivation engineer results in a high-quality perovskite surface with fewer defects and suppressed ion migration, leading to a champion efficiency of 23.5% with mixed-salt treatment. In addition, the introduction of the moisture resisted F-substituted groups presents a more hydrophobic perovskite surface, thus enabling the decorated devices with excellent long-term stability under a high humid atmosphere as well as operational conditions.     

Phase Transitions in Ferroelectric KNO3/Al2O3 Nanocomposites

Russian Physics Journal - The temperature dependences of the linear dielectric permittivity ε′ and the third harmonic coefficient γ3ω for nanocomposites obtained by embedding a...     

Column-oriented algebraic iterative methods for nonnegative constrained least squares problems

Numerical Algorithms - This paper considers different versions of block-column iterative (BCI) methods for solving nonnegative constrained linear least squares problems. We present the convergence...     

SPLITTING ALGORITHMS FOR NUMERICAL SOLUTION OF NAVIER — STOKES EQUATIONS IN FLUID DYNAMICS PROBLEMS

Journal of Applied Mechanics and Technical Physics - Implicit finite-volume predictor-corrector algorithms based on the splitting method are proposed for the numerical solution of the...     

Advances in the computational analysis of SARS-COV2 genome

Nonlinear Dynamics - Given a data-set of Ribonucleic acid (RNA) sequences we can infer the phylogenetics of the samples and tackle the information for scientific purposes. Based on current data and...     

Propagating and Standing Rayleigh Waves near Rivet Chains Connecting Kirchhoff Plates

We show that near periodic rivet chains that connect two Kirchhoff plates and are modeled by point Sobolev transmission conditions, Rayleigh waves arise, propagate along the chains, and decay exponentially in the orthogonal direction. Under additional geometric conditions we discover the standing (periodic) waves that carry no energy.

     

Fock–Schwinger Method in the Case of Different Masses

JETP Letters - The result of removing heavy particles with different mass from the theory spectrum can be described at low energy by the effective action, which is an asymptotic series in inverse...     

On the Use of Indium Arsenide as the Waveguide Material in the Measurements by Attenuated Total Reflectance

Optics and Spectroscopy - The current–voltage characteristics and photocurrent of “monolithic” diode optical pairs optically coupled by a substrate made of InAs common for them...     

Spatial Separation of Scalar Light Beams with Orbital Angular Momentum Using a Phase Metasurface

JETP Letters - The concept and design optimization of a polarization-independent dielectric metasurface for the spatial separation of scalar light beams with different values of the orbital angular...     

Structural Specific Features of Solid Solutions NdxGd1 – xCr3(BO3)4

Optics and Spectroscopy - Optical investigations of crystals of solid solutions NdxGd1 – xCr3(BO3)4, 0.01 ≤ x ≤ 1, have been performed. Absorption spectra in the...