全文获取类型
收费全文 | 23733篇 |
免费 | 3944篇 |
国内免费 | 3192篇 |
专业分类
化学 | 13486篇 |
晶体学 | 219篇 |
力学 | 744篇 |
综合类 | 257篇 |
数学 | 1798篇 |
物理学 | 5917篇 |
无线电 | 8448篇 |
出版年
2024年 | 76篇 |
2023年 | 577篇 |
2022年 | 756篇 |
2021年 | 898篇 |
2020年 | 957篇 |
2019年 | 976篇 |
2018年 | 855篇 |
2017年 | 818篇 |
2016年 | 1150篇 |
2015年 | 1271篇 |
2014年 | 1437篇 |
2013年 | 1774篇 |
2012年 | 2064篇 |
2011年 | 2088篇 |
2010年 | 1552篇 |
2009年 | 1606篇 |
2008年 | 1695篇 |
2007年 | 1547篇 |
2006年 | 1433篇 |
2005年 | 1260篇 |
2004年 | 968篇 |
2003年 | 832篇 |
2002年 | 917篇 |
2001年 | 673篇 |
2000年 | 601篇 |
1999年 | 419篇 |
1998年 | 287篇 |
1997年 | 244篇 |
1996年 | 211篇 |
1995年 | 194篇 |
1994年 | 148篇 |
1993年 | 127篇 |
1992年 | 96篇 |
1991年 | 69篇 |
1990年 | 61篇 |
1989年 | 48篇 |
1988年 | 29篇 |
1987年 | 37篇 |
1986年 | 27篇 |
1985年 | 22篇 |
1984年 | 11篇 |
1983年 | 11篇 |
1982年 | 9篇 |
1981年 | 7篇 |
1980年 | 4篇 |
1979年 | 3篇 |
1975年 | 3篇 |
1973年 | 4篇 |
1957年 | 5篇 |
1936年 | 3篇 |
排序方式: 共有10000条查询结果,搜索用时 343 毫秒
61.
A new stochastic method of reconstructing porous media 总被引:1,自引:0,他引:1
We present a new stochastic method of reconstructing porous medium from limited morphological information obtained from two-dimensional
micro- images of real porous medium. The method is similar to simulated annealing method in the capability of reconstructing
both isotropic and anisotropic structures of multi-phase but differs from the latter in that voxels for exchange are not selected
completely randomly as their neighborhood will also be checked and this new method is much simpler to implement and program.
We applied it to reconstruct real sandstone utilizing morphological information contained in porosity, two-point probability
function and linear-path function. Good agreement of those references verifies our developed method’s powerful capability.
The existing isolated regions of both pore phase and matrix phase do quite minor harm to their good connectivity. The lattice
Boltzmann method (LBM) is used to compute the permeability of the reconstructed system and the results show its good isotropy
and conductivity. However, due to the disadvantage of this method that the connectivity of the reconstructed system’s pore
space will decrease when porosity becomes small, we suggest the porosity of the system to be reconstructed be no less than
0.2 to ensure its connectivity and conductivity. 相似文献
62.
研究了具有非线性项|u|~αu的半线性波动方程的Cauclly问题,利用仿积分解及交换子估计等技术,证明了当α为一般的实数且满足一定的限制时,Cauchy问题自相似解的存在性。本文的结果回答了Planchon在其工作中所遗留的问题。 相似文献
63.
系统阐述了全集成自动化理念的内涵,指出其特点在于统一的数据管理、统一的编程组态、统一的通讯以及无与伦比的开放性,其中采用WINCC与STEP7两个软件进行了说明,井提出全集成自动化应用将是今后自动化技术发展应用的方向。 相似文献
64.
The title compound (C2H7NO·C7H4N2O6) has been obtained by the reaction of etha- nolamine with 3,5-dinitrobenzoic acid in deionized water at room temperature. The crystal crystal- lizes in orthorhombic, space group P212121 with a = 6.048(2), b = 9.146(3), c = 21.955(7)(A), C9H11N3O7, Mr = 273.21, Z = 4, V = 1214.3(7)(A)3, Dc = 1.494 g/cm3, F(000) = 568, μ(MoKα) = 0.131 mm-1, R1 = 0.0338 and wR2 = 0.0497. The new organic adduct is composed of one ethanolamine and one 3,5-dinitrobenzoic acid, which are linked up by O-H…O and N-H…O types of hydrogen bonds to form a nine-membered ring and an eleven-membered ring, extending into a one-dimensional network structure. 相似文献
65.
Shen-shui Lü 《高分子科学》2006,(5):441-447
Two kinds of water-soluble metallophthalocyanines, binuclear cobalt phthalocyanine (Co2Pc2) and binuclear ferric phthalocyanine (Fe2Pc2), were synthesized through phenylanhydride-urea route and characterized by elemental analysis and FT-IR spectra. Binuclear metallophthalocyanine derivatives (Mt2Pc2) were immobilized on silk fibers and modified viscose fibers to construct bioactive fibers of mimic enzyme. Mt2Pc2 was used as the active center of bioactive fibers, viscose and silk fibers as the microenvironments. The catalytic oxidation ability of bioactive fibers on the malodors of methanthiol and hydrogen sulfide was investigated at room temperature. The experimental results indicated that the catalytic activity of such bioactive fibers was closely correlative to the types ofbioactive fibers and substrates. 相似文献
66.
Tian-Xi ZhouGuan-Hu Bao Qin-Gao MaGuo-Wei Qin Chu-Tao CheYang Lv Cheng WangQi-Tai Zheng 《Tetrahedron letters》2003,44(1):135-137
Langduin C, a novel dimeric diterpenoid, was isolated from the roots of Euphorbia fischeriana and its structure was established by spectral data and single-crystal X-ray diffraction analysis. 相似文献
67.
双氯芬酸钠与牛血清白蛋白结合反应的特征 总被引:2,自引:0,他引:2
在模拟人体生理条件下,采用荧光光谱和紫外 可见吸收光谱法研究了双氯芬酸钠与牛血清白蛋白的结合反应.实验结果显示,双氯芬酸钠对牛血清白蛋白有较强的荧光猝灭作用,该猝灭过程主要为静态荧光猝灭过程;二者结合常数KLB=2.167×105mol·L-1;二者的结合位置距212位色氨酸2.13nm;同时,由结合反应的热力学参数得出二者作用力主要是氢键或VanderWall's力. 相似文献
68.
基于DSP的电力数据采集平台的设计与研究 总被引:1,自引:0,他引:1
介绍了一种用于电力系统的数据采集系统.该系统采用数字信号处理器(DSP)和复杂可编程逻辑器件(CPLD)作为核心芯片,给出了主要部分的电路及其原理、功能,系统中使用CPLD实现基本逻辑,使系统有足够的冗余和灵活性,具有可靠性高、可升级等优点. 相似文献
69.
Liang Liao Yi Pang Liming Ding Frank E. Karasz 《Journal of polymer science. Part A, Polymer chemistry》2003,41(20):3149-3158
A soluble cyano‐substituted poly[(1,3‐phenylene vinylene)‐alt‐(1,4‐phenylene vinylene)] derivative ( 9 ) was synthesized and characterized. Comparison between 9 and its model compound ( 10 ) showed that the chromophore in 9 remained to be well defined as a result of a π‐conjugation interruption at adjacent m‐phenylene units. The attachment of a cyano substituent only at the β position of the vinylene allowed the maximum electronic impact of the cyano group on the optical properties of the poly(p‐phenylene vinylene) material. At a low temperature (?108 or ?198 °C), the vibronic structures of 9 and 10 were partially resolved. The absorption and emission spectra of a film of 9 were less temperature‐dependent than those of a film of 10 , indicating that the former had a lower tendency to aggregate. A light‐emitting diode (LED) based on 9 emitted yellow light (λmax ≈ 578 nm) with an external quantum efficiency of 0.03%. © 2003 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 41: 3149–3158, 2003 相似文献
70.
报道了硅基有机微腔的电致发光(EL).该微腔由上半透明金属膜、中心有源多层膜和多孔硅分布Bragg反射镜(PS DBR)组成.半透明金属膜由Ag(20nm)构成,充当发光器件的负电极和微腔的上反射镜.有源多层膜由Al (1 nm) / LiF(05 nm) /Alq3/Alq3:DCJTB/NPB/CuPc/ITO/SiO2组成,其中的Al/LiF为电子注入层,ITO为正电极,SiO2为使正、负电极电隔离的介质层.该PS DBR是采用设备简单、成本低廉且非常省时的电化学腐蚀法用单晶Si来制备的;该PS
关键词:
电化学腐蚀
电致发光
窄峰发射
硅基有机微腔 相似文献