Studies on the method of total synthesis of koumine: I. 4-Substituted 1,2-dihydropyridine derivatives and their function as a conjugated diene in Diels-Alder reaction

A route to the total synthesis of koumine has been suggested. Five 4-substituted 1, 2-d hydropyridine derivatives, which are supposed to be a conjugated diene of Diels-Alder reaction to produce the isoquinuclidine ring of koumine, have been synthesized. Only two of them were found to be able to undergo the Diels-Alder reaction. The stereochemistry of the reaction product has also been examined.     

Validation of 3-D curved objects: CAD model and fabricatedworkpiece

This paper proposes a new method to describe and identify a 3-D curved object for the purpose of validating a fabricated object to the design specification. Curved 3-D objects are, in general, difficult to represent and identify because they lack distinct properties such as edges, planes, or cylindrical surfaces which are the building blocks in representing objects. In this paper, the authors propose to use principal axes of a 3-D object to establish a reference for the representation. A method of obtaining an inertia matrix from a 3-D range image is developed. The unique set of principal axes is obtained from the inertia matrix of an object with an arbitrary 3-D position and orientation, and the object can be described uniquely on these principal axes. On the principal axes, an object is described by a set of features describing the shape of the object such as spine, section size, section orientation, and section contraction. The features are used for comparing two objects for the validation purpose. The authors also propose a direct measure of similarity between two objects as a mean-squared difference of radii. As an experiment, two 3-D object models are designed through a CAD package, and fabricated objects are compared with the designed models for validation purposes     

Reversible addition–fragmentation transfer (RAFT) copolymerization of methyl methacrylate and styrene in miniemulsion

In the reversible addition–fragmentation transfer (RAFT) copolymerization of two monomers, even with the simple terminal model, there are two kinds of macroradical and two kinds of polymeric RAFT agent with different R groups. Because the structure of the R group could exert a significant influence on the RAFT process, RAFT copolymerization may behave differently from RAFT homopolymerization. The RAFT copolymerization of methyl methacrylate (MMA) and styrene (St) in miniemulsion was investigated. The performance of the RAFT copolymerization of MMA/St in miniemulsion was found to be dependent on the feed monomer compositions. When St is dominant in the feed monomer composition, RAFT copolymerization is well controlled in the whole range of monomer conversion. However, when MMA is dominant, RAFT copolymerization may be, in some cases, out of control in the late stage of copolymerization, and characterized by a fast increase in the polydispersity index (PDI). The RAFT process was found to have little influence on composition evolution during copolymerization. The synthesis of the well‐defined gradient copolymers and poly[St‐b‐(St‐co‐MMA)] block copolymer by RAFT miniemulsion copolymerization was also demonstrated. © 2004 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 42: 6248–6258, 2004     

拳王阿里

该片根据拳王阿里的故事改编而成。编导在影片中不但在努力塑造这位世界三大拳击组织的金腰带获得者，而且还塑造成了一个另类英雄。从更深的层面上看，正是因为阿里的传奇经历早已超越了一个体育明星的影响力。作为社会活动家与慈善大使，对发展中国家进行人道主义救援成为了这位拳王生活中极为重要的内容。他对他这一代人以及后来的几代人的影响为世人所公认。     

High voltage (>1kV) and high current gain (32) 4H-SiC power BJTs using Al-free ohmic contact to the base

This letter reports the design and fabrication of 4H-SiC bipolar junction transistors with both high voltage (>1kV) and high dc current gain (/spl beta/=32) at a collector current level of I/sub c/=3.83A (J/sub c/=319 A/cm/sup 2/). An Al-free base ohmic contact has been used which, when compared with BJTs fabricated with Al-based base contact, shows clearly improved blocking voltage. A specific on-resistance of 17 m/spl Omega//spl middot/cm/sup 2/ has been achieved for collector current densities up to 289 A/cm/sup 2/.     

A retractable structure based on Bricard linkages and rotating rings of tetrahedra

Retractable structures which alter their geometries according to practical requirements are widely used in roof structures of stadiums for their versatility. A retractable structure based on threefold-symmetric Bricard linkages and rotating rings of tetrahedra is proposed and developed in this paper. By replacing each link of a threefold-symmetric Bricard linkage with a tetrahedron, a retractable structure is obtained which can repeatedly open and close by rotating the tetrahedra. The geometric relationship between the retractable structure and the threefold-symmetric Bricard linkage is derived and ranges of main geometric parameters are determined to ensure a continuous and smooth movement in the deployment of the structure. Then the relative displacement of the support and the open rate of the structure, two main parameters concerned in practical applications, are investigated. Preferred ranges of main geometric parameters are proposed and a physical model is manufactured to verify them. A discussion on some possible improvements and modifications of the structure is also presented.     

MOS结构准静态测试中的异常C—V曲线

本文报导了MOS结构在准静态测试中的异常电容-电压曲线。讨论了它们产生的原因。     

Unified analytical expressions for calculating resonantfrequencies, transimpedances, and equivalent input noise currentdensities of tuned receiver front ends

Unified analytical expressions have been derived for calculating the resonant frequencies, transimpedance and equivalent input noise current densities of the four most widely used tuned optical receiver front ends built with FETs and p-i-n diodes. A more accurate FET model has been used to improve the accuracy of the analysis. The Miller capacitance has been taken into account, and its impact on the performances of the tuned front ends has been demonstrated. The accuracy of the expressions has been verified by Touchstone simulations. The agreement between the calculated and simulated performances of the front ends is very good. The expressions can be used to investigate the performances of different tuned front ends in a very simple way and provide a good starting point for further computer optimizations of the front ends     

I．O．T．旧梦成真

该文较详细地介绍了Ｉ．Ｏ．Ｔ管的发展历程，其特点及工作方式。