Precise electro-reduction of alkyl halides for radical defluorinative alkylation

Reported here is a precise electro-reduction strategy for radical defluorinative alkylation towards the synthesis of gem-difluoroalkenes from α-trifluoromethylstyrenes. According to the redox-potential difference of the radical precursors, direct or indirect electrolysis is respectively adopted to realize the precise reduction. An easy-to-handle, catalyst-and metal-free condition is developed for the reduction of alkyl radical precursors that are generally easier to be reduced than α-trifluorome...     

关于有消失矩的函数的Hilbert变换的加权范数不等式

为刻划一类权函数W,使具有N阶消失矩的函数f的Hilbert变换f满足带权L~P强型不等式Adams给出了一个充要条件。利用A_P权的性质,本文进一步完善了这个结果。     

超细银粉制备技术的现状与展望

本文介绍了超细银粉制备技术的各种方法,尤其重点介绍了真空油面蒸发法和沉淀过滤法等。并对各种方法的优缺点作了比较。同时展望了今后超细银粉制备技术的发展方向。     

基于无线数据业务智能优化系统算法的研究与应用

针对业界GPRS/EDGE无线数据优化方法、算法不完善,工作效率低的问题,广西联通通过长期研究建立了一套优化经验方法和较适合现网的参数配置、算法,并将这套方法、算法应用到自主开发的无线数据业务智能优化系统中,使系统实现自动采集分析数据、自动提供优化方案、自动执行优化方案、自动生成优化报告功能,使无线数据业务优化工作朝着智能化方向迈进。     

基于图像识别的路侧停车位数目检测方法研究

为了解决路侧停车位数目检测问题,本文采用基于图像识别的方法,将复杂的动态视频信息转化为简单的静态图像信息.首先,采用中值滤波、伽马变换和形态学处理等方法对感兴趣区域进行图像预处理;接着采用基于PPHT与直线聚类的方法检测停车位标记线;其次,采用二次方递减图像拼接的方法将该路段所有停车位拼接到一幅图像上,既防止了停车位数...     

殷钢荫罩彩管用弹簧片的设计及试验

本文离殷钢荫罩彩色显像管拚接式双金属弹簧片的设计及试验，确定了该管型的整管结构设计。     

某型雷达旁瓣抑制电路抗干扰分析

旁瓣对消是雷达抗有源干扰的有效方法。文章介绍了某型雷达旁瓣抑制电路的组成,分析了其基本的对消原理,并进行了计算机仿真,最后,给出了对几种有源压制干扰的对消结果。仿真结果表明,该旁瓣抑制电路具有很好的抗旁瓣干扰能力。     

Responses of Issatchenkia terricola WJL-G4 upon Citric Acid Stress

This study aimed to elucidate the responses of a novel characterized Issatchenkia terricola WJL-G4 against citric acid stress by performing physiological analysis, morphology observation, and structural and membrane fatty acid composition analysis. The results showed that under citric acid stress, the cell vitality of I. terricola WJL-G4 was reduced. The cell morphology changed with the unclear, uncompleted and thinner cell wall, and degraded the cell structure. When the citric acid concentration was 20 g/L, I. terricola WJL-G4 could tolerate citric acid and maintain the cell structure by increasing the intracellular pH, superoxide dismutase activity, and contents of unsaturated fatty acids. As the citric acid concentration was ≥80 g/L, the stress has exceeded the cellular anti-stress ability, causing substantial cell damage. The cell membrane permeability, the content of membrane lipids, malondialdehyde and superoxide anion increased, but the intracellular pH and superoxide dismutase activities decreased, accompanying the increase of citric acid concentrations. The findings of this work provided a theoretical basis for the responsive mechanism of I. terricola WJL-G4 under high concentrations of citric acid, and can serve as a reference for biological acid reduction in fruit processing.     

Optical properties of two-dimensional perovskites

The optical properties of two-dimensional (2D) perovskites recently receive numerous research focus thanks to the strong quantum and dielectric confinement effects. In addition to the strong excitonic effect at room temperature, 2D perovskites also have appealing features that their optical properties can be flexibly tuned by alternating organic or inorganic layers. Particularly, 2D chiral perovskites and 2D perovskites based heterostructures are emerging as new platforms to extend their functionalities. To optimize performance of 2D perovskites-based optoelectronic devices, it is critical to understand the fundamentals and explore the strategies to engineer their optical properties. This review begins with an introduction to the excitons and self-trapped excitons of 2D perovskites. Subsequently, inorganic/organic layer effects on optical properties and 2D perovskites based heterostructures are discussed. We also discussed the nonlinear optical properties of 2D perovskite. We are looking forward to that this review can stimulate more efforts to understand and optimize the optical properties of 2D perovskites.     

绝缘衬底上硅表面载流子的超快动力学研究

利用800 nm波长的飞秒抽运探测技术测量r具有不同单晶硅薄膜厚度的绝缘衬底上硅(SOI)皮秒瞬态反射率变化,并通过基于受激载流子密度和温度变化过程建立的反射率模型讨论了SOI表面载流子的超快动力学过程.研究表明,表面复合速度(SRV)是影响载流子动力学响应的主要因素,且薄膜厚度越小表面复合速度就越大,对应的表面态密度可达到1013cm-2 .对于较小的SRV,受激载流子的超快响应决定了瞬念反射率变化;而对于较大的SRV,晶格温升对瞬态反射率变化的贞献变得显著,使得反射率在更短的时间内恢复并超过初始值.