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101.
Hussain S Brotherhood PR Judd LW Davis AP 《Journal of the American Chemical Society》2011,133(6):1614-1617
Decalins bearing two axial -NHCONHAr substituents and an ester-linked alkyl side chain have been synthesized and studied as anion receptors and transporters. The design relates to steroid-based "cholapods" but is more compact and less intrinsically lipophilic. Transport rates depend on both NHAr and the alkyl side chain. High activities can be achieved; with optimal substitution, chloride-nitrate exchange across vesicle membranes is measurable at transporter/lipid ratios as low as 1:250,000. 相似文献
102.
Chimuka L van Pinxteren M Billing J Yilmaz E Jönsson JÅ 《Journal of chromatography. A》2011,1218(5):647-653
A selective extraction technique based on the combination of membrane assisted solvent extraction and molecularly imprinted solid phase extraction for triazine herbicides in food samples was developed. Simazine, atrazine, prometon, terbumeton, terbuthylazine and prometryn were extracted from aqueous food samples into a hydrophobic polypropylene membrane bag containing 1000μL of toluene as the acceptor phase along with 100mg of MIP particles. In the acceptor phase, the compounds were re-extracted onto MIP particles. The extraction technique was optimised for the type of organic acceptor solvent, amount of molecularly imprinted polymers particles in the organic acceptor phase, extraction time and addition of salt. Toluene as the acceptor phase was found to give higher triazine binding onto MIP particles compared to hexane and cyclohexane. Extraction time of 120min and 100mg of MIP were found to be optimum parameters. Addition of salt increased the extraction efficiency for more polar triazines. The selectivity of the technique was demonstrated by extracting spiked cow pea and corn extracts where clean chromatograms were obtained compared to only membrane assisted solvent extraction or only molecularly imprinted solid phase extraction. The study revealed that this combination may be a simple way of selectively extracting compounds in complex samples. 相似文献
103.
Drahoš B Kotek J Císařová I Hermann P Helm L Lukeš I Tóth É 《Inorganic chemistry》2011,50(24):12785-12801
Mn(2+) complexes represent an alternative to Gd(3+) chelates which are widely used contrast agents in magnetic resonance imaging. In this perspective, we investigated the Mn(2+) complexes of two 12-membered, pyridine-containing macrocyclic ligands bearing one pendant arm with a carboxylic acid (HL(1), 6-carboxymethyl-3,6,9,15-tetraazabicyclo[9.3.1] pentadeca-1(15),11,13-triene) or a phosphonic acid function (H(2)L(2), 6-dihydroxyphosphorylmethyl-3,6,9,15-tetraazabicyclo[9.3.1]pentadeca-1(15),11,13-triene). Both ligands were synthesized using nosyl or tosyl amino-protecting groups (starting from diethylenetriamine or tosylaziridine). The X-ray crystal structures confirmed a coordination number of 6 for Mn(2+) in their complexes. In aqueous solution, these pentadentate ligands allow one free coordination site for a water molecule. Potentiometric titration data indicated a higher basicity for H(2)L(2) than that for HL(1), related to the electron-donating effect of the negatively charged phosphonate group. According to the protonation sequence determined by (1)H and (31)P pH-NMR titrations, the first two protons are attached to macrocyclic amino groups whereas the subsequent protonation steps occur on the pendant arm. Both ligands form thermodynamically stable complexes with Mn(2+), with full complexation at physiological pH and 1:1 metal to ligand ratio. The kinetic inertness was studied via reaction with excess of Zn(2+) under various pHs. The dissociation of MnL(2) is instantaneous (at pH 6). For MnL(1), the dissociation is very fast (k(obs) = 1-12 × 10(3) s(-1)), much faster than that for MnDOTA, MnNOTA, or the Mn(2+) complex of the 15-membered analogue. It proceeds exclusively via the dissociation of the monoprotonated complex, without any influence of Zn(2+). In aqueous solution, both complexes are air-sensitive leading to Mn(3+) species, as evidenced by UV-vis and (1)H NMRD measurements and X-ray crystallography. Cyclic voltammetry gave low oxidation peak potentials (E(ox) = 0.73 V for MnL(1) and E(ox) = 0.68 V for MnL(2)), in accordance with air-oxidation. The parameters governing the relaxivity of the Mn(2+) complexes were determined from variable-temperature (17)O NMR and (1)H NMRD data. The water exchange is extremely fast, k(ex) = 3.03 and 1.77 × 10(9) s(-1) for MnL(1) and MnL(2), respectively. Variable-pressure (17)O NMR measurements have been performed to assess the water exchange mechanism on MnL(1) and MnL(2) as well as on other Mn(2+) complexes. The negative activation volumes for both MnL(1) and MnL(2) complexes confirmed an associative mechanism of the water exchange as expected for a hexacoordinated Mn(2+) ion. The hydration number of q = 1 was confirmed for both complexes by (17)O chemical shifts. A relaxometric titration with phosphate, carbonate or citrate excluded the replacement of the coordinated water molecule by these small endogenous anions. 相似文献
104.
A simple and expedient process for the Heck aminocarbonylative synthesis of Weinreb and MAP amide acylating agents, from aryl halides, is reported. This methodology utilizes solid sources of CO making it readily accessible to chemists working in small-scale laboratory applications. 相似文献
105.
106.
Clifton LA Sanders MR Castelletto V Rogers SE Heenan RK Neylon C Frazier RA Green RJ 《Physical chemistry chemical physics : PCCP》2011,13(19):8881-8888
The self-assembly in solution of puroindoline-a (Pin-a), an amphiphilic lipid binding protein from common wheat, was investigated by small angle neutron scattering, dynamic light scattering and size exclusion chromatography. Pin-a was found to form monodisperse prolate ellipsoidal micelles with a major axial radius of 112 ± 4.5 ? and minor axial radius of 40.4 ± 0.18 ?. These protein micelles were formed by the spontaneous self-assembly of 38 Pin-a molecules in solution and were stable over a wide pH range (3.5-11) and at elevated temperatures (20-65 °C). Pin-a micelles could be disrupted upon addition of the non-ionic surfactant dodecyl-β-maltoside, suggesting that the protein self-assembly is driven by hydrophobic forces, consisting of intermolecular interactions between Trp residues located within a well-defined Trp-rich domain of Pin-a. 相似文献
107.
Florian Hatesuer Tillmann Groth Mark Reichwage Dieter Mewes Andrea Luke 《Heat and Mass Transfer》2011,47(8):921-931
Twin-screw multiphase pumps are employed increasingly to convey multiphase mixtures of crude oil, accompanying fluids, associated
gas and solid particles. They are positive displacement pumps and suitable for handling products containing liquid accompanied
by large amounts of gas. Experimental investigations on the conveying characteristic, namely measuring the delivered volume
flow as a function of the pressure difference, provide results for selected mixtures. By means of the on hand work, the influence
of sorption phenomena occurring due to pressure variations alongside the conveying process on the conveying characteristics
of twin-screw pumps delivering mixtures of oil and gases is measured. The employed gases are air and carbon dioxide, which
differ strongly in solubility in oil. All experiments are conducted in a closed loop test facility, where oil and gas volume
flows are mixed before the inlet and separated after the outlet of the multiphase pump. In order to simulate the influence
of the suction side pressure drop in the reservoir on the conveying characteristic, packed beds are employed as oil-filed
model. Sorption processes inside of the oil-field model and within the multiphase pump affect the conveying behaviour significantly.
The two-phase flow in the inlet and outlet pipe is visualised by means of a capacitance tomography system. Results show that
the oil fraction of the total delivered volume flow is decreased due to desorption at the pump inlet. The gas fraction at
the pump outlet is further decreased due to absorption. Experimental results are compared to calculated solubilities of the
on-hand gases in oil and to the theoretically derived gas volume flow fraction expected at the multiphase pump. 相似文献
108.
Bianca Haberl Jamie J. Molaison Joerg C. Neuefeind Luke L. Daemen Reinhard Boehler 《高压研究》2013,33(3):426-437
ABSTRACTA simple modified Bridgman design for large volume pressure anvils usable in the Paris-Edinburgh (PE) press has been demonstrated at Oak Ridge National Laboratory Spallation Neutron Source. The design shows advantages over the toroidal anvils typically used in the PE press, mainly rapid compression/decompression rates, complete absence of blow-outs upon drastic phase transitions, simplified cooling, high reliability, and relative low loads (~40 tons) corresponding to relatively high pressures (~20?GPa). It also shows advantages over existing large-volume diamond cells as sample volumes of ~2–3?mm3 can be easily and rapidly synthesized. The anvils thus allow sample sizes sufficient for in situ neutron diffraction as well as rapid synthesis of adequate amounts of new materials for ex situ analysis via total neutron scattering and neutron spectroscopy. 相似文献
109.
110.
S Kailas R Vandenbosch A Charlop A Garcia S Gil S J Luke B McLain D Prindle 《Pramana》1990,35(5):439-447
The fusion cross section for the system6Li+28Si has been measured atE∼36 MeV. Combining this with the data available at lower energies, the nucleus-nucleus real potentials have been determined
for a range of interaction distances. 相似文献