A structurally guided method for the decomposition of expression in music performance

A method for separating, profiling, and quantifying the contributions of different structural components to expressive musical performance is described. The method is demonstrated through its application to a set of expert piano performances of a short piece from the classical period. The results show that the output of the method aids in the understanding of how the different structural components in a piece of music combine in the generation of an expressive performance. A second demonstration applies the method to performances at different tempi to illustrate its effectiveness in pinpointing the structural features responsible for small but statistically significant differences between performances. The method is compared with other approaches to the analysis and modeling of musical performance, and a number of potential applications are identified.     

Gas phase infrared multiple-photon dissociation spectra of methanol, ethanol and propanol proton-bound dimers, protonated propanol and the propanol/water proton-bound dimer

The infrared multiphoton dissociation (IRMPD) spectra of three homogenous proton-bound dimers are presented and the major features are assigned based on comparisons with the neutral alcohol and with density functional theory calculations. As well, the IRMPD spectra of protonated propanol and the propanol/water proton-bound dimer (or singly hydrated protonated propanol) are presented and analysed. Two primary IRMPD photoproducts were observed for each of the alcohol proton bound dimers and were found to vary with the frequency of the radiation impinging upon the ions. For example, when the proton-bound dimer absorbs weakly a larger amount of S(N)2 product, protonated ether and water, are observed. When the proton-bound dimer absorbs more strongly, an increase in the simple dissociation product, protonated alcohol and neutral alcohol, is observed. With the aid of RRKM calculations this frequency dependence of the branching ratio is explained by assuming that photon absorption is faster than dissociation for these species and that only a few photons extra are necessary to make the higher-energy dissociation channel (simple cleavage) competitive with the lower energy (S(N)2) reaction channel.     

Morphology of polythiophene and polyphenyl films produced via surface polymerization by ion-assisted deposition

Conducting polymer films are grown by either mass-selected or non-mass-selected, hyperthermal thiophene ions coincident on a surface with a thermal beam of organic monomers of either alpha-terthiophene (3T) or p-terphenyl (3P) neutrals. Previous experiments verified polymerization of both 3T and 3P by 200 eV C(4)H(4)S(+) during surface polymerization by ion-assisted deposition (SPIAD). A wide variety of structures are observed by scanning electron microscopy to form in the SPIAD polythiophene and polyphenyl films. These structures include microscale islands, lamellar structures, fractal-like growth patterns, and nanoscale crystallites. Some of the deposited films diffract X-rays while others show electron micrographs of crystallites. The variation of these patterns with deposition conditions clearly indicate that ion-induced polymerization mediates film morphology through control of ion energy and ion/neutral ratio. Furthermore, these ion-assisted events mediate important thermal processes such as sublimation.     

Lost heat capacity and entropy in the helical magnet MnSi

The heat capacity of MnSi at B = 0 and B = 4 T was measured in the temperature range 2.5-100 K. To analyze the data, calculations of the phonon spectrum and phonon density of states in MnSi were performed. The calculated phonon frequencies were confirmed by means of inelastic neutron scattering. The analysis of the data suggests the existence of negative contributions to the heat capacity and entropy of MnSi at T > T(c) that may imply a specific ordering in the spin subsystem in the paramagnetic phase of MnSi.     

A globally linearly convergent method for pointwise quadratically supportable convex–concave saddle point problems

We study the Proximal Alternating Predictor–Corrector (PAPC) algorithm introduced recently by Drori, Sabach and Teboulle [8] to solve nonsmooth structured convex–concave saddle point problems consisting of the sum of a smooth convex function, a finite collection of nonsmooth convex functions and bilinear terms. We introduce the notion of pointwise quadratic supportability, which is a relaxation of a standard strong convexity assumption and allows us to show that the primal sequence is R-linearly convergent to an optimal solution and the primal-dual sequence is globally Q-linearly convergent. We illustrate the proposed method on total variation denoising problems and on locally adaptive estimation in signal/image deconvolution and denoising with multiresolution statistical constraints.     

Evaluation of physical carrier sense based spanner construction and maintenance as well as broadcast and convergecast in ad hoc networks

While the use of physical carrier sensing for medium access control in ad hoc wireless networks is well established, exploiting physical carrier sensing directly for network layer functions is largely unexplored. We conduct extensive simulation evaluations of recently proposed algorithms that directly exploit physical carrier sensing for backbone network (spanner) construction, broadcast, and convergecast in wireless ad hoc networks. Our algorithms accommodate interference ranges larger than transmission ranges, explicitly incorporate the medium access control and packet collisions, and do not require any prior knowledge of the network. For spanner construction, our algorithms include three self-stabilizing phases that establish leader nodes able to reach all nodes in one hop, assign the leaders non-interfering transmission rounds, and connect the leaders through gateway nodes. We evaluate the backbone construction and maintenance as well as broadcast and convergecast through simulations. We find that over 75% of the control messages for backbone network construction are received from physical carrier sensing. While the number of backbone nodes is relatively large, the backbone is very robust, quickly self-stabilizing, and only a fraction of the backbone nodes are used for broadcast.     

Symbolic Computation with Monotone Operators

We consider a class of monotone operators which are appropriate for symbolic representation and manipulation within a computer algebra system. Various structural properties of the class (e.g., closure under taking inverses, resolvents) are investigated as well as the role played by maximal monotonicity within the class. In particular, we show that there is a natural correspondence between our class of monotone operators and the subdifferentials of convex functions belonging to a class of convex functions deemed suitable for symbolic computation of Fenchel conjugates which were previously studied by Bauschke & von Mohrenschildt and by Borwein & Hamilton. A number of illustrative examples utilizing the introduced class of operators are provided including computation of proximity operators, recovery of a convex penalty function associated with the hard thresholding operator, and computation of superexpectations, superdistributions and superquantiles with specialization to risk measures.     

Antimicrobial Gallium‐Doped Phosphate‐Based Glasses

Novel quaternary gallium‐doped phosphate‐based glasses (1, 3, and 5 mol % Ga₂O₃) were synthesized using a conventional melt quenching technique. The bactericidal activities of the glasses were tested against both Gram‐negative (Escherichia coli and Pseudomonas aeruginosa) and Gram‐positive (Staphylococcus aureus, methicillin‐resistant Staphylococcus aureus, and Clostridium difficile) bacteria. Results of the solubility and ion release studies showed that these glass systems are unique for controlled delivery of Ga³⁺. ⁷¹Ga NMR measurements showed that the gallium is mostly octahedrally coordinated by oxygen atoms, whilst FTIR spectroscopy provided evidence for the presence of a small proportion of tetrahedral gallium in the samples with the highest gallium content. FTIR and Raman spectra also afford an insight into the correlation between the structure and the observed dissolution behavior via an understanding of the atomic‐scale network bonding characteristics. The results confirmed that the net bactericidal effect was due to Ga³⁺, and a concentration as low as 1 mol % Ga₂O₃ was sufficient to mount a potent antibacterial effect. The dearth of new antibiotics in development makes Ga³⁺ a potentially promising new therapeutic agent for pathogenic bacteria including MRSA and C. difficile.     

Insight into Three‐Coordinate Aluminum Species on Ethanol‐to‐Olefin Conversion over ZSM‐5 Zeolites

Commercial bioethanol can be readily converted into ethylene by a dehydration process using solid acids, such as Brønsted acidic H‐ZSM‐5 zeolites, and thus, it is an ideal candidate to replace petroleum and coal for the sustainable production of ethylene. Now, strong Lewis acidic extra‐framework three‐coordinate Al³⁺ species were introduced into H‐ZSM‐5 zeolites to improve their catalytic activity. Remarkably, Al³⁺ species working with Brønsted acid sites can accelerate ethanol dehydration at a much lower reaction temperature and shorten the unsteady‐state period within 1–2 h, compared to >9 h for those without Al³⁺ species, which can significantly enhance the ethanol dehydration efficiency and reduce the cost. The reaction mechanism, studied by solid‐state NMR, shows that strong Lewis acidic EFAl‐Al³⁺ species can collaborate with Brønsted acid sites and promote ethanol dehydration either directly or indirectly via an aromatics‐based cycle to produce ethylene.     

Absence of broken time-reversal symmetry in the pseudogap state of the high temperature La(2-x)SrxCuO4 superconductor from muon-spin-relaxation measurements

We have performed zero-field muon-spin-relaxation measurements on single crystals of La(2-x)SrxCuO4 to search for spontaneous currents in the pseudogap state. By comparing measurements on materials across the phase diagram, we put strict upper limits on any possible time-reversal symmetry breaking fields that could be associated with the pseudogap. Comparison between experimental limits and the proposed circulating current states effectively eliminates the possibility that such states exist in this family of materials.