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71.
Rodrigo París Jos Luis de la Fuente 《Journal of polymer science. Part A, Polymer chemistry》2006,44(18):5304-5315
Functional spontaneous gradient copolymers of allyl methacrylate (A) and butyl acrylate (B) were synthesized via atom transfer radical polymerization. The copolymerization reactions were carried out in toluene solutions at 100 °C with methyl 2‐bromopropionate as the initiator and copper bromide with N,N,N′,N″,N″‐pentamethyldiethylenetriamine as the catalyst system. Different aspects of the statistical reaction copolymerizations, such as the kinetic behavior, crosslinking density, and gel fraction, were studied. The gel data were compared with Flory's gelation theory, and the sol fractions of the synthesized copolymers were characterized by size exclusion chromatography and nuclear magnetic resonance spectroscopy. The copolymer composition, demonstrating the gradient character of the copolymers, and the microstructure were analyzed. The experimental data agreed well with data calculated with the Mayo–Lewis terminal model and Bernoullian statistics, with monomer reactivity ratios of 2.58 ± 0.37 and 0.51 ± 0.05 for A and B, respectively, an isotacticity parameter for A of 0.24, and a coisotacticity parameter of 0.33. © 2006 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 44: 5304–5315, 2006 相似文献
72.
73.
74.
Hyeong Taek Ham Yeong Suk Choi Mu Guen Chee In Jae Chung 《Journal of polymer science. Part A, Polymer chemistry》2006,44(1):573-584
This work is to make carbon nanotubes dispersible in both water and organic solvents without oxidation and cutting nanotube threads. Polystyrene‐singlewall carbon nanotube (PS‐SWNT) composites were prepared with three different methods: miniemulsion polymerization, conventional emulsion polymerization, and mixing SWNT with PS latex. The two factors, crosslinking and surface coverage of PS are important factors for the mechanical and electrical properties, including dispersion states of SWNT in various solvents. The PS‐SWNT composite prepared via a conventional emulsion polymerization showed SWNT bundles entirely covered with PS, whereas the PS‐SWNT composite prepared via a miniemulsion polymerization showed SWNT partially covered with crosslinked PS nanoparticles. The method of mixing SWNTs with PS latex did not show the well dispersed state of carbon nanotubes because PS was not crosslinked and was dissolved in a solvent, and nanotubes separated from PS precipitated. So the PS nanoparticle‐SWNT composite had lower electrical resistance, and higher mechanical strength than the other composites made by the latter two methods. As the amount of SWNT increases, the bare surface area of SWNT increases and the electrical conductivity increases in the composite made by the miniemulsion polymerization. © 2005 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 44: 573–584, 2006 相似文献
75.
Olga Ordeig Craig E Banks Trevor J Davies F Javier del Campo Francesc Xavier Mu?oz Richard G Compton 《Analytical sciences》2006,22(5):679-683
Gold ultra-microelectrode arrays are used to explore the electrochemical oxidation of hydroxide ions and are shown to be analytical useful. Two types of ultra-microelectrode arrays are used; the first consist of 256 individual electrodes of 5 microm in radius, 170 of which are electrochemically active in a cubic arrangement which are separated from their nearest neighbour by a distance of 100 microm. The second array compromises 2597 electrodes of 2.5 microm in radius and of which 1550 of which are electrochemically active in a hexagonal arrangement separated by the nearest neighbour by 55 microm. Well defined voltammetric waves are found with peak currents proportional to the concentration of hydroxide ions in the range 50 microM to 1 mM. Detection limits of 20 microM using the 170 ultra-microelectrode and 10 microM with the 1550 ultra-microelectrode array are shown to be possible but with a higher sensitivity of 4 mA M(-1) observed using the 1550 ultra-microelectrode array compared to 1.2 mA M(-1) with the 170 ultra-microelectrode array. 相似文献
76.
77.
Ligia E. Zamora G. A. Perez Alcazar J. M. Greneche S. Suriñach 《Hyperfine Interactions》2006,168(1-3):1057-1063
Fe60Mn10Al20Nb10, (Fe60Mn10Al30)95Nb5 and (Fe60Mn10Al30)90Nb10 ball milled powdered alloys were investigated using X-ray diffraction, Mössbauer spectrometry, thermomagnetic (TGM) and magnetization measurements. We studied the influence of Nb content and of different milling times on the structural and magnetic properties. Two main features can be concluded: (1) the FeAlMn induces a BCC phase whatever the Nb content is, and (2) as both increasing Nb content and milling time give rise to an highly disordered state in conjunction with a decrease of the ferromagnetic behavior. 相似文献
78.
Francisco-Javier Muñoz-Delgado Victoriano Ramirez-González Paul Sablonnière 《分析论及其应用》1995,11(1):62-71
In this work we study linear polynomial operators preserving some consecutive i-convexities and leaving invariant the polynomials
up to a certain degree. First, we study the existence of an incom patibility between the conservation of certain i-convexities
and the invariance of a space of polynomials. Interpolation properties are obtained and a theorem by Berens and DeVore about
the Bernstein's operator is extended. Finally, from these results a generalized Bernstein's operator is obtained.
This work was supported by Junta de Andalucia. Grupo de investigación: Matemática Aplicada. Código: 1107 相似文献
79.
Winner-Take-All (WTA) or K-Winner-Take-All (KWTA) networks have been frequently used as the basic building blocks of complex neural networks. This paper introduces a new selection rule for network connections that implements stable KWTA networks. To widen the applications of WTA networks, a new class of WTA networks is proposed, and their efficient design methods are presented. We demonstrate the properties of the generalized class of WTA networks, through three application examples. 相似文献
80.
Mikhael Balabane Thierry Cazenave Luis Vázquez 《Communications in Mathematical Physics》1990,133(1):53-74
We prove the existence of stationary states for nonlinear Dirac equations of the form (E) $$i\sum\limits_{\mu = 0}^3 {\gamma ^\mu \partial _\mu \psi - M\psi + F\left( {\bar \psi \psi } \right)\psi = 0,} $$ whereM>0 andF is a singular self-interaction. In particular, in the model case whereF(s)=?s ?α, for some 0<α<1, and for every ω>M, there exists a solution of (E) of the form ψ(t, x)=e iωt?(x), wherex 0=t andx=(x 1,x 2,x 3), such that ? has compact support. IF 0<α<1/3, then ? is of classC 1. If 1/3<α<1, then ? is continuously differentiable, except on some sphere {|x|=R}, where |??| is infinite. 相似文献