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141.
Carmen Festa Valentina Sepe Paolo Luciano Cecile Débitus Valentina Vellecco 《Tetrahedron》2009,65(50):10424-1496
Two new metabolites, perthamides C and D, have been isolated from the marine sponge Theonella swinhoei. Their structures were determined by interpretation of NMR and ESIMS data. All compounds exhibited in vivo potent anti-inflammatory activity. Biological activity and structural elucidation are reported. 相似文献
142.
143.
The use of explicit methods in the numerical treatment of differential equations of fractional order is an area not yet widely investigated. In this paper stability properties of some multistep methods of explicit type are investigated and new methods with larger intervals of stability are proposed. Some numerical experiments are presented in order to validate theoretical results. 相似文献
144.
Differential scanning calorimetry (DSC) and thermogravimetric analysis (TG) were performed on wood samples of different essences (fir, chestnut, poplar, linden and oak) before consolidation. A kinetic analysis was applied on the two-steps decomposition processes occurring in all wood samples using either the multiheating rates Kissinger equation and the isoconversional Ozawa-Flynn-Wall method that enables the variation of activation energy to be determined as a function of the degree of reaction. Taking into account both decomposition temperature and activation energy for the first degradation step oak seems to be the less stable sample. The comparison of DSC curves performed in air with those in oxygen enables to consider the role of the partial pressure of oxygen in the mechanisms of both decompositions. 相似文献
145.
Caseli L Moraes ML Zucolotto V Ferreira M Nobre TM Zaniquelli ME Rodrigues Filho UP Oliveira ON 《Langmuir : the ACS journal of surfaces and colloids》2006,22(20):8501-8508
This paper reports the surface activity of phytase at the air-water interface, its interaction with lipid monolayers, and the construction of a new phytic acid biosensor on the basis of the Langmuir-Blodgett (LB) technique. Phytase was inserted in the subphase solution of dipalmitoylphosphatidylglycerol (DPPG) Langmuir monolayers, and its incorporation to the air-water interface was monitored with surface pressure measurements. Phytase was able to incorporate into DPPG monolayers even at high surface pressures, ca. 30 mN/m, under controlled ionic strength, pH, and temperature. Mixed Langmuir monolayers of phytase and DPPG were characterized by surface pressure-area and surface potential-area isotherms, and the presence of the enzyme provided an expansion in the monolayers (when compared to the pure lipid at the interface). The enzyme incorporation also led to significant changes in the equilibrium surface compressibility (in-plane elasticity), especially in liquid-expanded and liquid-condensed regions. The dynamic surface elasticity for phytase-containing interfaces was investigated using harmonic oscillation and axisymmetric drop shape analysis. The insertion of the enzyme at DPPG monolayers caused an increase in the dynamic surface elasticity at 30 mN m(-)(1), indicating a strong interaction between the enzyme and lipid molecules at a high-surface packing. Langmuir-Blodgett (LB) films containing 35 layers of mixed phytase-DPPG were characterized by ultraviolet-visible and fluorescence spectroscopy and crystal quartz microbalance nanogravimetry. The ability in detecting phytic acid was studied with voltammetric measurements. 相似文献
146.
Gennari M Lanfranchi M Marchiò L Pellinghelli MA Tegoni M Cammi R 《Inorganic chemistry》2006,45(8):3456-3466
Complexes [PPh3Cu(Tr(Mes,Me))] (1), [PPh3Cu(Tr(Me,o-Py))] (2), and [PPh3Cu(Br(Mes)pz(o-Py))] (3) (Tr(Mes,Me) = hydrotris[1,4-dihydro-3-methyl-4-mesityl-5-thioxo-1,2,4-triazolyl]borate; Tr(Me,o-Py) = hydrotris[1,4-dihydro-4-methyl-3-(2-pyridyl)-5-thioxo-1,2,4-triazolyl]borate; Br(Mes)pz(o-Py) = hydro[bis(thioxotriazolyl)-3-(2-pyridyl)pyrazolyl]borate; PPh3 = triphenylphosphine) were synthesized by the reaction of dinuclear complexes [Cu(Tr(Mes,Me))]2, [Cu(Tr(Me,o-Py))]2, [Cu(Br(Mes)pz(o-Py))]2, and PPh3. 1-3 were characterized by 1H, 13C, and 31P NMR spectroscopy and ESI-mass spectrometry. Crystal structure analyses were performed for 1 and 2. Both complexes crystallize in the triclinic P space group with the metal in a slightly distorted tetrahedral geometry (S3P coordination) bound by a kappa3-S3 ligand and a PPh3 molecule. The solution molecular structures were investigated by means of variable-temperature (210-310 K, CDCl3, 1-2; 200-310 K, CD2Cl2, 3) and NOESY NMR spectroscopy. The solution structures of 1-2 are in accordance with the X-ray structures, and the complexes do not exhibit fluxional behavior. On the other hand, 3 is subject to an equilibrium between two species with a coalescing temperature of approximately 260 K. DFT geometry optimizations suggest that the major species of 3 consists of the Br(Mes)pz(o-Py) ligand bound to Cu(I) in the kappa3-S2H fashion with two C=S groups and a [Cu...H-B] interaction. A PPh3 completes the copper coordination (S2HP coordination). The complex [TuCu(Tr(Mes,Me))] (4) (Tu = thiourea) was crystallized using an excess of Tu with respect to [Cu(Tr(Me,2-Py))]2 (approximately a 6:1 ratio). The metal adopts a distorted tetrahedral geometry with an overall S3H coordination determined by the bound kappa3-S2H ligand (two C=S groups and a [B-H...Cu] interaction) and by a Tu. The reactivity of dinuclear complexes [Cu(Tr(Mes,Me))]2, [Cu(Tr(Me,o-Py))]2, and [Cu(Br(Mes)pz(o-Py))]2 with monodentate ligands was investigated by means of NMR titrations with PPh3, Tu. and pyridine (Py), and formation constants for the adducts [DCu(L)] (D = monodentate donor, L = tripodal ligand) were determined. 相似文献
147.
Luciano Gonç alves Noleto Manuel N. D. Barcelos Jr. & Antonio C. P. Brasil Jr. 《advances in applied mathematics and mechanics.》2013,5(2):194-211
This work presents a moving mesh methodology based on the solution
of a pseudo flow problem. The mesh motion is modeled as a pseudo Stokes
problem solved by an explicit finite element projection method. The mesh
quality requirements are satisfied by employing a null divergent velocity
condition. This methodology is applied to triangular unstructured meshes
and compared to well known approaches such as the ones based on diffusion
and pseudo structural problems. One of the test cases is an airfoil with
a fully meshed domain. A specific rotation velocity is imposed as the
airfoil boundary condition. The other test is a set of two cylinders
that move toward each other. A mesh quality criterion is employed to
identify critically distorted elements and to evaluate the performance
of each mesh motion approach. The results obtained for each test case
show that the pseudo-flow methodology produces satisfactory meshes
during the moving process. 相似文献
148.
149.
Ali J. Ghandour Kassem Fawaz Hassan Artail Marco Di Felice Luciano Bononi 《Ad hoc Networks》2013,11(8):2408-2422
The Wireless Access in Vehicular Environments (WAVE) protocol stack has been recently defined to enable vehicular communication on the Dedicated Short Range Communication (DSRC) frequencies. Some recent studies have demonstrated that the WAVE technology might not provide sufficient spectrum for reliable exchange of safety information over congested urban scenarios. In this paper, we address this issue, and present a novel cognitive network architecture in order to dynamically extend the Control Channel (CCH) used by vehicles to transmit safety-related information. To this aim, we propose a cooperative spectrum sensing scheme, through which vehicles can detect available spectrum resources on the 5.8 GHz ISM band along their path, and forward the data to a fixed infrastructure known as Road Side Units (RSUs). We design a novel Fuzzy-Logic based spectrum allocation algorithm, through which the RSUs infer the actual CCH contention conditions, and dynamically extend the CCH bandwidth in network congestion scenarios, by using the vacant frequencies detected by the sensing module. The simulation results reveal the effectiveness of our architecture in providing dynamic and scalable allocation of spectrum resources, and in increasing the performance of safety-related applications. 相似文献
150.
Cavani L Ciavatta C Trubetskaya OE Reznikova OI Afanas'eva GV Trubetskoj OA 《Journal of chromatography. A》2003,983(1-2):263-270
Capillary zone electrophoresis (CZE) was used for characterisation of soil humic acid (HA) fractions obtained by coupling size-exclusion chromatography with polyacrylamide gel electrophoresis, on the basis of their molecular size and electrophoretic mobility. CZE was conducted using several low alkaline buffers as background electrolyte (BGE): 50 mM carbonate, pH 9.0; 50 mM phosphate, pH 8.5; 50 mM borate, pH 8.3; 50 mM Tris-borate+1 mM EDTA+7 M urea+0.1% sodium dodecyl sulphate (SDS), pH 8.3. Independently of BGE conditions, the effective electrophoretic mobility of HA fractions were in good agreement with their molecular size. The better resolution of HA were obtained in Tris-borate-EDTA buffer with urea and SDS. This results indicated that CZE, mostly with BGE-contained disaggregating agents, is useful for separating HAs in fractions with different molecular sizes. 相似文献