Optical multistability in 1D photonic crystals with nonlinear Thue–Morse structure

A 1D photonic crystal structure contains 16 layers, 8 common dielectric layers and 8 layers with nonlinear medium, with an arrangement similar to the 5th generation, Thue–Morse multilayer is presented. The properties of photonics band gap, field distribution and optical multistability are investigated. On the band gap, 5 resonant modes is observed. On the behavior of output intensity versus input intensity around resonant frequencies, the multistability response observed. When the frequency of incident field is close to the resonant frequency, the threshold intensity of multistability is decreased.     

Size-dependent magnetic properties of CoFe2O4 nanoparticles prepared in polyol

Highly crystalline CoFe(2)O(4) nanoparticles with different diameters ranging from 2.4 to 6.1 nm have been synthesized by forced hydrolysis in polyol. The size can be controlled through adjusting the nominal water/metal molar ratio. X-ray diffraction, transmission electron microscopy, x-ray absorption spectroscopy and (57)Fe M?ssbauer spectrometry were employed to investigate the structure and the microstructure of the particles produced. Magnetic measurements performed on these particles show that they are superparamagnetic with a size-dependent blocking temperature. At 5 K, high saturation magnetization (~85 emu g(-1)) approaching that of the bulk was found for the larger particles, whereas a very large coercivity (14.5 kOe) is observed for the 3.5 nm sized particles.     

Production of single-walled carbon nanotubes from methane over Co-Mo/MgO nanocatalyst:A comparative study of fixed and fluidized bed reactors

In this study,the performances of fixed and fluidized bed reactors in the production of single-walled carbon nanotubes(SWNTs)have been investigated.In both reactors,single-walled carbon nanotubes were grown by catalytic chemical vapor decomposition(CCVD)of methane over Co-Mo/MgO nanocatalyst under two different operating conditions.The synthesized samples were characterized by TEM,TGA and Raman spectroscopy.It is found that the performance of a fluidized bed in the synthesis of carbon nanotubes is much better than that of a fixed bed.The quality of carbon nanotubes obtained from the fluidized bed was significantly higher than that from the fixed bed and the former one with the ID/IG ratio of 0.11 while the latter one with the ID/IG ratio of 0.71.Also,the yield of SWNTs in the fluidized bed was 92 wt%,while it was 78 wt%in the fixed bed.These advantages of fluidized bed reactors for the synthesis of carbon nanotubes can be attributed to more available space for the growth of carbon nanotubes and more uniform temperature and concentration profiles.     

Synthesis and Structure of Bis(3-dimethylammonium-1-propyne)pentachlorobismuthate(III) (C<Subscript>5</Subscript>H<Subscript>10</Subscript>N)<Subscript>2</Subscript>BiCl<Subscript>5</Subscript>

Abstract  

The synthesis and crystal structure are given for the bis(3-dimethylammonium-1-propyne)pentachlorobismuthate(III) salt. An X-ray investigation has shown that the title compound crystallizes at 298 K in a centrosymmetric monoclinic system, space group C2/c with the following lattice parameters a = 12.6215(4) ?, b = 18.9228(5) ?, c = 8.3134(2) ?, β = 104.100(2)°, V = 1925.70(9) ?³. The structure was solved from 7,716 independent reflections with R ₁ = 0.0457 and wR ₂ = 0.0906, and refined with 85 parameters. The structure consists of disordered 3-dimethylammonium-1-propyne, C₅H₉NH⁺ cations and polynuclear anions in which slightly distorted (BiCl₅)²⁻ anions, sharing an apex are interconnected in chains. These chains are themselves interconnected by means of N–H···Cl originating from the C₅H₉NH⁺ entities, forming a three-dimensional network.     

Crystal structure,NMR study,dielectric relaxation and AC conductivity of a new compound [Cd3(SCN)2Br6(C2H9N2)2]n

The crystal structure, the ¹³C NMR spectroscopy and the complex impedance have been carried out on [Cd₃(SCN)₂Br₆(C₂H₉N₂)₂]_n. Crystal structure shows a 2D polymeric network built up of two crystallographically independent cadmium atoms with two different octahedral coordinations. This compound exhibits a phase transition at (T=355±2 K) which has been characterized by differential scanning calorimetry (DSC), X-rays powder diffraction, AC conductivity and dielectric measurements. Examination of ¹³C CP/MAS line shapes shows indirect spin–spin coupling (¹⁴N and ¹³C) with a dipolar coupling constant of 1339 Hz. The AC conductivity of this compound has been carried out in the temperature range 325–376 K and the frequency range from 10⁻² Hz to 10 MHz. The impedance data were well fitted to two equivalent electrical circuits. The results of the modulus study reveal the presence of two distinct relaxation processes. One, at low frequency side, is thermally activated due to the ionic conduction of the crystal and the other, at higher frequency side, gradually disappears when temperature reaches 355 K which is attributed to the localized dipoles in the crystal. Moreover, the temperature dependence of DC-conductivity in both phases follows the Arrhenius law and the frequency dependence of σ(ω,T) follows Jonscher's universal law. The near values of activation energies obtained from the conductivity data and impedance confirm that the transport is through the ion hopping mechanism.     

Numerical Model for Electro-Mechanical Analysis Based on Finite Element Method

In this paper, we present a numerical procedure that can be used to model the electro-mechanical coupled behavior of the dielectric actuator domain. The equation describing the electrostatical part is given by the reduced form of the Maxwell equation and the electrostatic potential [1]. The mechanical problem is described by the constitutive equations and equilibrium equations. Using the finite element method, this technique is to divide a whole problem into sub-problems. The complexity of the original problem is therefore reduced by focusing only on the most relevant areas. A finite element analysis is then performed by applying the electrostatic Maxwell pressure as Neumann boundary conditions to compute the displacements. Once the displacement is computed, the electrostatic domain or the conductor is updated. Electrostatic analysis is performed on the updated geometry and the finite element method is then used to determine the change in potential due to geometric perturbations. Once the surface charge densities are known, the new electrostatic Maxwell pressure is computed. The mechanical and electrostatic analysis is repeated until an equilibrium state is computed. The procedure is demonstrated in the paper by the solution of some two-dimensional and three-dimensional problems. (© 2013 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim)     

An offset cancellation technique for comparators using body-voltage trimming

A novel offset cancellation technique based on body-voltage trimming is presented to be used in the comparators employed in high-speed analog-to-digital converters (ADCs) such as Flash ADCs. The proposed offset cancellation is achieved by body-voltage adjustment using a low-power simple analog control feedback circuit without any additional capacitive loading at the comparator output or complicated digital calibration scheme. The accuracy of the proposed technique is higher than its digital calibration counterparts due to its analog nature. Simulation results in a 1.8?V 0.18???m CMOS technology show that using the proposed technique the standard deviation of the comparator offset is significantly reduced from 36.2 to 7.1?mV operating at 1?GHz with only 32???W of power dissipation in the offset cancellation circuit.