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Liyuan Liu Biqin Song Zhibin Pan Chuanwu Yang Chi Xiao Weifu Li 《Entropy (Basel, Switzerland)》2022,24(7)
Gradient Learning (GL), aiming to estimate the gradient of target function, has attracted much attention in variable selection problems due to its mild structure requirements and wide applicability. Despite rapid progress, the majority of the existing GL works are based on the empirical risk minimization (ERM) principle, which may face the degraded performance under complex data environment, e.g., non-Gaussian noise. To alleviate this sensitiveness, we propose a new GL model with the help of the tilted ERM criterion, and establish its theoretical support from the function approximation viewpoint. Specifically, the operator approximation technique plays the crucial role in our analysis. To solve the proposed learning objective, a gradient descent method is proposed, and the convergence analysis is provided. Finally, simulated experimental results validate the effectiveness of our approach when the input variables are correlated. 相似文献
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Zheyan Qian Yiqing Yang Dr. Liyuan Wang Jiajia Wang Yue Guo Ziwei Liu Jianzheng Li Haoyu Zhang Prof. Xuemei Sun Prof. Huisheng Peng 《Angewandte Chemie (International ed. in English)》2023,62(28):e202303268
Biosupercapacitors (BSCs) that can harvest and store chemical energy show great promise for power delivery of biological applications. However, low power density still limits their applications, especially as miniaturized implants. Here, we report an implantable fiber BSC with maximal power density of 22.6 mW cm−2, superior to the previous reports. The fiber BSC was fabricated by integrating anode and cathode fibers of biofuel cell with supercapacitor fibers through multi-strand twisting. This twisting structure endowed many channels inside and high electrochemical active area for efficient mass diffusion and charge transfer among different fibers, benefiting high power output. The obtained thin and flexible fiber BSC operated stably under deformations and performed high biocompatibility after implantation. Eventually, the fiber BSC was implanted subcutaneously in rats and successfully realized electrical stimulation of sciatic nerve, showing promise as a power source in vivo. 相似文献
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基于分子动力学计算方法,运用LAMMPS程序模拟了Si, GaAs, 3C-SiC三种半导体材料中辐照引起的级联碰撞过程,并分析了晶体内微观缺陷的演化特性。模拟结果表明,级联碰撞会在晶体内部形成类似离位峰的结构,大多数空位缺陷聚集在损伤区域内部,而损伤区域外围分布的主要是间隙缺陷。通过对三种材料进行缺陷簇分析,发现Si中缺陷簇数量明显多于GaAs,缺陷簇最大尺寸达到了17个原子。此外,三种材料中的Frenkel对的数量变化过程大致相同,均呈现“上升,下降,稳定”的趋势,但3C-SiC中的缺陷数量要远小于Si和GaAs,表明3C-SiC具有更好的辐射抗性,其晶体结构在受到辐照后仍能保持相对稳定。 相似文献
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Hang Zhang Tao Luo Yingkang Chen Dr. Kang Liu Hongmei Li Dr. Evangelina Pensa Prof. Junwei Fu Prof. Zhang Lin Prof. Liyuan Chai Prof. Emiliano Cortés Prof. Min Liu 《Angewandte Chemie (International ed. in English)》2023,62(46):e202305651
Tetrafluoromethane (CF4), the simplest perfluorocarbon (PFC), has the potential to exacerbate global warming. Catalytic hydrolysis is a viable method to degrade CF4, but fluorine poisoning severely restricts both the catalytic performance and catalyst lifetime. In this study, Ga is introduced to effectively assists the defluorination of poisoned Al active sites, leading to highly efficient CF4 decomposition at 600 °C with a catalytic lifetime exceeding 1,000 hours. 27Al and 71Ga magic-angle spinning nuclear magnetic resonance spectroscopy (MAS NMR) showed that the introduced Ga exists as tetracoordinated Ga sites (GaIV), which readily dissociate water to form Ga−OH. In situ diffuse reflectance infrared Fourier transform spectroscopy (DRIFTS) and density function theory (DFT) calculations confirmed that Ga−OH assists the defluorination of poisoned Al active sites via a dehydration-like process. As a result, the Ga/Al2O3 catalyst achieved 100 % CF4 decomposition keeping an ultra-long catalytic lifetime and outperforming reported results. This work proposes a new approach for efficient and long-term CF4 decomposition by promoting the regeneration of active sites. 相似文献
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间歇采样转发式干扰(ISRJ)能够在雷达接收机形成多个逼真的假目标,兼具压制和欺骗的干扰效果。为提升雷达在此干扰场景下的目标检测能力,提出了一种全极化雷达体制下的抗ISRJ非匹配滤波方法。文中以脉冲压缩后信号最小旁瓣能量输出和干扰最小积分能量输出为出发点,基于罚函数的思想建立多目标优化模型;通过帕累托参数的组合加权,将模型转化为多线性约束下最小输出积分能量的目标函数,以此设计非匹配滤波器。仿真实验表明,本文方法能够有效抑制不同样式的间歇采样转发式干扰。 相似文献
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Dr. Haoxiang Yu Zhen Wang Runtian Zheng Dr. Lei Yan Dr. Liyuan Zhang Prof. Jie Shu 《Angewandte Chemie (International ed. in English)》2023,62(46):e202308397
Due to the natural abundance of iodine, cost-effective, and sustainability, metal-iodine batteries are competitive for the next-generation energy storage systems with high energy density, and large power density. However, the inherent properties of iodine such as electronic insulation and shuttle behavior of soluble iodine species affect negatively rate performance, cyclability, and self-discharge behavior of metal-iodine batteries, while the dendrite growth and metal corrosion on the anode side brings potential safety hazards and inferior durability. These problems of metal-iodine system still exist and need to be solved urgently. Herein, we summarize the research progress of metal-iodine batteries in the past decades. Firstly, the classification, design strategy and reaction mechanism of iodine electrode are briefly outlined. Secondly, the current development and protection strategy of conventional metal anodes in metal-iodine batteries are highlighted, and some potential anode materials and their design strategies are proposed. Thirdly, the key electrochemical parameters of state-of-art metal-iodine batteries are compared and analyzed to solve critical issues for realizing next-generation iodine-based energy storage systems. Therefore, the aim of this review is to promote the development of metal-iodine batteries and provide guidelines for their design. 相似文献