高氯酸-硫酸消化植物样品防止氮素损失的研究

本文研究利用加纯水缓冲的方法,使H_2SO_4-HClO_4消煮液的氧化能力随消化时间的推移而逐渐增强,与植物材料分解前易后难的规律相吻合,有效地防止了氮在消煮过程中的损失。比较表明,该方法准确度和精密度都达到K氏法水平,同时还具有操作简便、省时,对磷和钾的测定无干扰等特点,尤其适用于作物诊断样中氮、磷、钾的联合消化。     

TPS601XX系列低波纹电荷泵DC/DC变换器原理与应用

简要分析了TPS601XX系列芯片功能，特性和工作原理。     

低温物理领域的开拓者——卡末林—昂内斯

1卡末林-昂内斯的青年时代 1853年9月21日卡末林-昂内斯出生于荷兰的Groningen.他的父亲拥有一制瓦厂,但他的母亲艺术素养颇佳,深深影响了他.他的姐夫是当时Leiden有些名气的画家.卡末林-昂内斯年轻时也曾涉猎诗歌.     

包含自旋1/2和自旋S的系统中的热纠缠(英文)

研究了一个处在均匀外磁场中的包含四个量子比特的各向同性海森堡XY模型中,两个间隔的量子比特之间的量子热纠缠,并用并发度来量度.这个模型包含两种量子比特:自旋为1/2的量子比特和自旋为S的量子比特.结果表明,外磁场可以引起两个间隔的量子比特之间的量子热纠缠.热纠缠的幅度与自旋S,温度T以及均匀外磁场B有关.因此,可以通过调节B的取值来控制热纠缠.当S足够大时,阈值温度也可能很高.这个特性可以被用于研究凝聚态系统的热纠缠,并且在固体系统进行量子信息研究中也将发挥很大的作用.     

New true-triaxial rock strength criteria considering intrinsic material characteristics

A reasonable strength criterion should reflect the hydrostatic pressure effect, minimum principal stress effect,and intermediate principal stress effect. The former two effects can be described by the meridian curves, and the last one mainly depends on the Lode angle dependence function. Among three conventional strength criteria, i.e.Mohr–Coulomb(MC), Hoek–Brown(HB), and Exponent(EP) criteria, the difference between generalized compression and extension strength of EP criterion experience a firstly increase then decrease process, and tends to be zero when hydrostatic pressure is big enough. This is in accordance with intrinsic rock strength characterization. Moreover, the critical hydrostatic pressure I_c corresponding to the maximum difference of between generalized compression and extension strength can be easily adjusted by minimum principal stress influence parameter K. So, the exponent function is a more reasonable meridian curves, which well reflects the hydrostatic pressure effect and is employed to describe the generalized compression and extension strength.Meanwhile, three Lode angle dependence functions of L_(MN),L_(WW), and L_(YMH), which unconditionally satisfy the convexity and differential requirements, are employed to represent the intermediate principal stress effect. Realizing the actual strength surface should be located between the generalized compression and extension surface, new true-triaxial criteria are proposed by combining the two states of EP criterion by Lode angle dependence function with a same lode angle. The proposed new true-triaxial criteria have the same strength parameters as EP criterion. Finally, 14 groups of triaxial test data are employed to validate the proposed criteria. The results show that the three new true-triaxial exponent criteria,especially the Exponent Willam-Warnke criterion(EPWW)criterion, give much lower misfits, which illustrates that the EP criterion and L_(WW) have more reasonable meridian and deviatoric function form, respectively. The proposed new true-triaxial strength criteria can provide theoretical foundation for stability analysis and optimization of support design of rock engineering.     

父母教养方式与高中生自我监控学习的关系——核心自我评价的中介作用

考察了父母教养方式与高中生自我监控学习的关系,及核心自我评价在其中的中介作用.选取424名高中生,采用简式父母教养方式问卷、核心自我评价量表和中学生自我调节学习策略问卷,分别测量其父母教养方式、核心自我评价及自我监控学习.父亲情感温暖直接预测自我监控学习(B=0.22,p0.001),又通过核心自我评价间接预测自我监控学习(B=0.09,p0.05);母亲情感温暖直接预测自我监控学习(B=0.27,p0.001),又通过核心自我评价间接预测自我监控学习(B=0.07,p0.05).自我监控学习与父母教养方式、核心自我评价密切相关,核心自我评价在父母教养方式与自我监控学习及其各维度之间起部分中介作用.     

Nondestructive imaging of the internal microstructure of vessels and nerve fibers in rat spinal cord using phase‐contrast synchrotron radiation microtomography

The spinal cord is the primary neurological link between the brain and other parts of the body, but unlike those of the brain, advances in spinal cord imaging have been challenged by the more complicated and inhomogeneous anatomy of the spine. Fortunately with the advancement of high technology, phase‐contrast synchrotron radiation microtomography has become widespread in scientific research because of its ability to generate high‐quality and high‐resolution images. In this study, this method has been employed for nondestructive imaging of the internal microstructure of rat spinal cord. Furthermore, digital virtual slices based on phase‐contrast synchrotron radiation were compared with conventional histological sections. The three‐dimensional internal microstructure of the intramedullary arteries and nerve fibers was vividly detected within the same spinal cord specimen without the application of a stain or contrast agent or sectioning. With the aid of image post‐processing, an optimization of vessel and nerve fiber images was obtained. The findings indicated that phase‐contrast synchrotron radiation microtomography is unique in the field of three‐dimensional imaging and sets novel standards for pathophysiological investigations in various neurovascular diseases.     

Synthesis and study the liquid crystalline properties of compounds containing benzoxazole core and terminal vinyl group

Terminal vinyl-based benzoxazole liquid crystalline compounds, 2-(3-fluoro-4?-alkoxy-1,1?-biphenyl ?4-yl)-5-(2-propenyloxymethyl)-benzoxazole (nPPF(2)BP), were synthesised and their structures were confirmed by infrared (IR) spectra, proton nuclear magnetic resonance (¹H-NMR) spectra, gas chromatography with electron impact-mass spectrometry (GC/EI-MS), matrix-assisted laser desorption/ionisation-time of flight (MALDI-TOF) mass spectrometry and elemental analysis (EA). The compounds show enantiotropic smectic/nematic phases with mesophase ranges are 71–97 °C and 87–136°C on heating and cooling processes for nPPF(2)BP, respectively. They give low melting points due to lateral fluoro substituent and flexible terminal 2-propenyloxymethyl chain. It is found that the compounds nPPF(2)BP with shorter alkoxy chain (n = 3, 4) exhibit a wide range of nematic mesophase, which is ascribed to enhanced π–π interaction caused by terminal vinyl moiety, whereas further elongation of the terminal alkoxy chain results in supressing nematic phase and increasing smectic mesophase. Compared with methyl terminated analogues, 2-propenyloxymethyl terminated compounds nPPF(2)BP display much lower melting points and wider or comparable mesophase range both in heating and cooling.