全文获取类型
收费全文 | 92696篇 |
免费 | 14279篇 |
国内免费 | 9657篇 |
专业分类
化学 | 50222篇 |
晶体学 | 657篇 |
力学 | 4669篇 |
综合类 | 310篇 |
数学 | 8188篇 |
物理学 | 27693篇 |
无线电 | 24893篇 |
出版年
2024年 | 231篇 |
2023年 | 2339篇 |
2022年 | 2562篇 |
2021年 | 3596篇 |
2020年 | 3728篇 |
2019年 | 3422篇 |
2018年 | 2925篇 |
2017年 | 2799篇 |
2016年 | 4038篇 |
2015年 | 4178篇 |
2014年 | 4995篇 |
2013年 | 6317篇 |
2012年 | 7956篇 |
2011年 | 8038篇 |
2010年 | 5718篇 |
2009年 | 5637篇 |
2008年 | 5956篇 |
2007年 | 5303篇 |
2006年 | 4970篇 |
2005年 | 4202篇 |
2004年 | 3111篇 |
2003年 | 2633篇 |
2002年 | 2338篇 |
2001年 | 1982篇 |
2000年 | 1926篇 |
1999年 | 2135篇 |
1998年 | 1838篇 |
1997年 | 1686篇 |
1996年 | 1683篇 |
1995年 | 1414篇 |
1994年 | 1229篇 |
1993年 | 1004篇 |
1992年 | 900篇 |
1991年 | 761篇 |
1990年 | 618篇 |
1989年 | 439篇 |
1988年 | 379篇 |
1987年 | 298篇 |
1986年 | 273篇 |
1985年 | 233篇 |
1984年 | 171篇 |
1983年 | 123篇 |
1982年 | 93篇 |
1981年 | 75篇 |
1980年 | 76篇 |
1979年 | 38篇 |
1978年 | 35篇 |
1977年 | 46篇 |
1976年 | 39篇 |
1973年 | 29篇 |
排序方式: 共有10000条查询结果,搜索用时 265 毫秒
91.
In this Letter,a novel system for adaptively correcting the phase of a dynamic multimode beam is proposed.While using merely one spatial light modulator,the phase measurement of the first-order diffraction pattern and the correction of the zeroth diffraction order are simultaneously realized.The real-time experimental result is obtained at a control rate of 10 Hz.The power-in-the-bucket value is improved from 38.5%to 61.8%,even with fundamental mode content that is consistently below 30%.To the best of our knowledge,this is the first implementation of real-time adaptive correction of the entire multimode beam. 相似文献
92.
Floquet engineering appears as a new protocol for designing topological states of matter,and features anomalous edge modes pinned at quasi-energy π/T with vanished topological index.We propose how to predict the anomalous edge modes via the bulk Hamiltonian in frequency space,and use Zak phase to quantitatively index the topological properties.The above methods are clarified by the example of time periodic Kitaev chain with chemical potential of harmonic driving and pulse driving,and topological phase transitions are manifested at different driving frequencies. 相似文献
93.
94.
In order to improve the signal-to-noise ratio and mitigate the damage of noise to the communication quality,an effective interference suppression algorithm,which is based on the improved density-based spatial clustering of applications with noise algorithms,is proposed for visible light communication systems using the complementary metal–oxide–semiconductor image sensor as the receiver.Experimental results show that the algorithm can learn the region where the payload data is located,filter out the noise data,and greatly decrease the interference.The effect of the algorithm is also studied through bit error ratio performance. 相似文献
95.
分析了建立高可用性DHCP服务的迫切需求,根据DHCP服务体系结构,提出了DHCP服务的设计方法,并进行了周密的系统设计和系统部署,总结出了大型局域网部署DHCP服务的优化策略。 相似文献
96.
The discharge of diverse pollutants has led to a complex water environment and posed a huge health threat to humans and animals. Self-propelled micromotors have recently attracted considerable attention for efficient water remediation due to their strong localized mass transfer effect. However, a single functionalized component is difficult to tackle with multiple contaminants and requires to combine different decontamination effects together. Here, we introduced a multifunctional micromotor to implement the adsorption and degradation roles simultaneously by integrating the poly(aspartic acid) (PASP) adsorbent with a MnO2-based catalyst. The as-prepared micromotors are well propelled in contaminated waters by MnO2 catalyzing hydrogen peroxide. In addition, the catalytic ramsdellite MnO2(R-MnO2) inner layer is decorated with Fe2O3 nanoparticles to improve their catalytic performance, contributing to an excellent degradation ability with 90% tetracycline (TC) removal in 50 minutes by enhanced Fenton-like reactions. Combining the attractive adsorption capability of poly (aspartic acid) (PASP), the composite micromotors offer an efficient removal of heavy metal ions in short time. Moreover, the designed micromotors are able to simultaneously remove antibiotic and heavy metals in mixed contaminants circumstance just in single treatment. This multifunctional micromotor with distinctive decontamination ability exhibits a promising prospective in treating multiple pollutants in the future. 相似文献
97.
Shi-Tao Han Hong-Ying Duan Lan-Yun Chen Dr. Tian-Guang Zhan Dr. Li-Juan Liu Li-Chun Kong Prof. Kang-Da Zhang 《化学:亚洲杂志》2021,16(23):3886-3889
A photo-switchable hetero-complementary quadruple H-bonding array, which consists of an azobenzene-derived ureidopyrimidinone (UPy) module ( Azo-UPy ) and a nonphotoactive diamidonaphthyridine (DAN) derivative ( Napy-1 ), is constructed based on a reversible photo-locking approach. Upon UV (390 nm)/Vis (460 nm) light irradiations, photo-switchable quadruple H-bonded dimerization between Azo-UPy and Napy-1 can be achieved with exhibiting 4.8×104-fold differences in binding strength (ON/OFF ratios). Furthermore, smart polymeric gels with unique photo-controlled macroscopic self-assembly behavior can be fabricated by introducing such quadruple H-bonding array as photo-regulable noncovalent interfacial connections. 相似文献
98.
Dr. Feifan Wang Jie Tian Dr. Mengzhu Li Dr. Weizhen Li Dr. Lifang Chen Xiaozhi Liu Dr. Jian Li Aidaer Muhetaer Prof. Dr. Qi Li Prof. Dr. Yuan Wang Prof. Dr. Lin Gu Prof. Dr. Ding Ma Prof. Dr. Dongsheng Xu 《Angewandte Chemie (Weinheim an der Bergstrasse, Germany)》2020,132(21):8280-8286
Fully utilizing solar energy for catalysis requires the integration of conversion mechanisms and therefore delicate design of catalyst structures and active species. Herein, a MOF crystal engineering method was developed to controllably synthesize a copper–ceria catalyst with well-dispersed photoactive Cu-[O]-Ce species. Using the preferential oxidation of CO as a model reaction, the catalyst showed remarkably efficient and stable photoactivated catalysis, which found practical application in feed gas treatment for fuel cell gas supply. The coexistence of photochemistry and thermochemistry effects contributes to the high efficiency. Our results demonstrate a catalyst design approach with atomic or molecular precision and a combinatorial photoactivation strategy for solar energy conversion. 相似文献
99.
Cuixia Cui Yong Gao Dr. Jun Li Chao Yang Meng Liu Prof. Dr. Huile Jin Prof. Dr. Zhenhai Xia Prof. Dr. Liming Dai Prof. Dr. Yong Lei Prof. Dr. Jichang Wang Prof. Dr. Shun Wang 《Angewandte Chemie (Weinheim an der Bergstrasse, Germany)》2020,132(20):8002-8007
Although tremendous efforts have been devoted to understanding the origin of boosted charge storage on heteroatom-doped carbons, none of the present studies has shown a whole landscape. Herein, by both experimental evidence and theoretical simulation, it is demonstrated that heteroatom doping not only results in a broadened operating voltage, but also successfully promotes the specific capacitance in aqueous supercapacitors. In particular, the electrolyte cations adsorbed on heteroatom-doped carbon can effectively inhibit hydrogen evolution reaction, a key step of water decomposition during the charging process, which broadens the voltage window of aqueous electrolytes even beyond the thermodynamic limit of water (1.23 V). Furthermore, the reduced adsorption energy of heteroatom-doped carbon consequently leads to more stored cations on the heteroatom-doped carbon surface, thus yielding a boosted charge storage performance. 相似文献
100.