碳纳米管阵列、捆束的三步升温工艺制备及其形貌与结构

使用结构简单的单温炉设备，通过三步升温热解二茂铁、三聚氰氨混合物方法，在二氧化硅、多晶陶瓷基底上分别合成了碳纳米管阵列、碳纳米管捆束.使用扫描电子显微镜、透射电子显微镜、电子能量损失谱和x射线光电子能谱对合成样品进行了结构和成分分析.结果显示：两种基底上合成的纳米管均为多壁纯碳管；生长于光滑二氧化硅表面的碳纳米管具有高度取向性和一致的外径，长度为10—40μm.碳纳米管采取催化剂顶端生长模式并展示出类杯状形貌；生长于粗糙多晶陶瓷表面的碳纳米管捆束随机取向，碳纳米管直径为15—80nm，长度在几百微米，展示 关键词： 碳纳米管 热解法 三步升温工艺     

2,9-disubstituted 1,10-phenanthroline nickel complexes: Syntheses,characterization, and their ethylene oligomerization

Nickel complexes 1–4 ligated with 2,9-disubstituted-1,10-phenanthroline were synthesized and characterized by FT-IR spectra and elemental analysis. The molecular structure of complex 2 was confirmed by X-ray crystal diffraction analysis. Activated with methylaluminoxane (MAO), those complexes showed moderate activities for ethylene oligomerization. Published in Kinetika i Kataliz, 2007, Vol. 48, No. 5, pp. 710–714. This article was submitted by the authors in English.     

A method to collect an infrared spectrum in solution.

Herein we report a new method to collect a qualified infrared spectrum of a solute in solution by two solvent cells with different thickness during background single-beam spectrum scanning. By collecting the background spectrum with two cells (two stages), we successfully achieved accurate solvent compensation between a sample and a reference, namely, the solvent amounts in the sample and background measurements could become congruent. Therefore, the solvent bands were thoroughly suppressed in the infrared spectrum and a qualified spectrum of the solute was obtained.     

Mono-dispersed cross-linked polystyrene micro-spheres prepared by seed swelling polymerization method

A two-step swelling procedure was adopted to synthesize mono-dispersed and highly cross-linked poly (St-divinylbenzene) particles with PSt micro-spheres (1.80 μm in diameter). The PSt micro-spheres were prepared by a dispersion polymerization method and used as seeds. The effects of monomer concentration, ratio of ethanol to water, swelling reagents, crosslinking reagents, swelling temperature and agitation speed on particle size were investigated in detail. The morphologies and size distributions of these micro-spheres were examined by SEM and particle size analysis (PSA). The T _g of the micro-spheres was measured by DSC. The results indicate that the particles (6.20 μm in diameter) exhibit excellent mono dispersed property and high crosslinking degree when the concentration of the swelling reagent was 25%, the concentration of the crosslinking reagents was 23%, the swelling temperature was 30°C and the stirring speed was 150 r/min. __________ Translated from Chinese Journal of Applied Chemistry, 2007, 24(11): 1289–1294     

Buckling of a stiff thin film on a compliant substrate in large deformation

A finite-deformation theory is developed to study the mechanics of thin buckled films on compliant substrates. Perturbation analysis is performed for this highly nonlinear system to obtain the analytical solution. The results agree well with experiments and finite element analysis in wavelength and amplitude. In particular, it is found that the wavelength depends on the strain. Based on the accurate wavelength and amplitude, the membrane and peak strains in thin films, and stretchability and compressibility of the system are also obtained analytically.     

The effect of micro-morphology of Bi2O3 on catalytic properties of Co/Bi catalyst for wet air oxidation of acetic acid

The novel phase transfer catalysts S-8 [4-(dimethyloctylammonium) propansultan] and DB-X [1,4-bis(triethylmethylammonium)benzene dibromide] were synthesized and employed for high conversion synthesis of dichlorocyclopropane from various olefins.This revised version was published online in December 2005 with corrections to the Cover Date.     

FIR的FPGA实现及其QuartusⅡ与MATLAB仿真

利用Altera公司的Stratix系列芯片内部的ROM实现了一种基于查找表结构的有限冲击响应(FIR)数字滤波器,从而将卷积运算变换成一种查表后的加法运算,提高了运算速度,节省了逻辑单元;并且利用Altera公司的FPGA开发软件QuartusⅡ与MathWorks公司的MATLAB软件实现电子设计自动化(EDA)应用中的联合仿真,从而提高了现场可编程门阵列(FPGA)设计的效率,使得QuartusⅡ的波形仿真功能更加强大;利用最新版本的QuartusⅡ3.0还可以将波形文件转换成Testbench文件导入到专业仿真软件例如ModelSim中进行仿真.     

WCDMA系统中SPT数字滤波器的一种设计方法

相对于传统的数字滤波器实现方法,符号的2次幂和(SPT)滤波器用移位寄存器替代乘法器,因而资源消耗少、速度快,更加适于专用集成电路(ASIC)设计.介绍了一种适用于宽带码分多址(WCDMA)前向信道中给定基带成形滤波器单位脉冲响应后设计SPT滤波器的方法.相对于传统的理想SPT系数优化方法,此方法更适于给定单位脉冲响应后SPT滤波器的设计,计算复杂度低;仿真结果显示,相对于更加简单的四舍五入方法,此算法在性能上又有可观的增益.     

模拟电路故障诊断系统的设计

介绍了板级模拟电路故障诊断系统,论述了系统的硬件组成和软件功能,该系统结合了测试技术、故障诊断理论,将专家经验融合到计算机软件系统中,能自动完成电路板的性能测试,并根据性能测试结果生成故障隔离引导树,引导操作人员对被测电路板进行故障的检测和维修.系统符合开放的、模块化、通用化的构建思想及在硬件资源的可互换方面的考虑,大大提高了系统的扩展能力和测试程序集(TPS)的重用性,节约了软件开发的成本,对于开发集数字电路与模拟电路为一体的通用故障诊断平台具有一定的借鉴作用.     

CDMA发射分集系统的多用户检测常模算法分析

空时分集技术的最大优点在于在不增加带宽的情况下可以提高系统的可靠性,是目前移动通信的研究热点.常模算法是一种性能优良的码分多址(CDMA)盲多用户检测技术,能确保判决信号与实际传送信号之间的差错较小,误码率性能良好.文中提出将标准线性受限常模算法(LCCMA)与空时分组码(STBC)相结合,设计出一种收敛快、能够改善系统性能的基于2-空时分组码的多用户接收机.