全文获取类型
收费全文 | 1801篇 |
免费 | 178篇 |
国内免费 | 175篇 |
专业分类
化学 | 1020篇 |
晶体学 | 21篇 |
力学 | 70篇 |
综合类 | 14篇 |
数学 | 283篇 |
物理学 | 345篇 |
无线电 | 401篇 |
出版年
2024年 | 3篇 |
2023年 | 36篇 |
2022年 | 66篇 |
2021年 | 75篇 |
2020年 | 74篇 |
2019年 | 64篇 |
2018年 | 72篇 |
2017年 | 65篇 |
2016年 | 102篇 |
2015年 | 79篇 |
2014年 | 105篇 |
2013年 | 128篇 |
2012年 | 93篇 |
2011年 | 131篇 |
2010年 | 99篇 |
2009年 | 87篇 |
2008年 | 102篇 |
2007年 | 92篇 |
2006年 | 90篇 |
2005年 | 76篇 |
2004年 | 46篇 |
2003年 | 39篇 |
2002年 | 30篇 |
2001年 | 26篇 |
2000年 | 37篇 |
1999年 | 29篇 |
1998年 | 24篇 |
1997年 | 16篇 |
1996年 | 29篇 |
1995年 | 36篇 |
1994年 | 22篇 |
1993年 | 17篇 |
1992年 | 18篇 |
1991年 | 29篇 |
1990年 | 12篇 |
1989年 | 5篇 |
1988年 | 4篇 |
1987年 | 5篇 |
1986年 | 6篇 |
1985年 | 9篇 |
1984年 | 5篇 |
1983年 | 8篇 |
1982年 | 9篇 |
1981年 | 4篇 |
1980年 | 7篇 |
1978年 | 11篇 |
1977年 | 8篇 |
1976年 | 6篇 |
1974年 | 4篇 |
1973年 | 5篇 |
排序方式: 共有2154条查询结果,搜索用时 15 毫秒
21.
22.
Chunliu Xu Weibo Hua Qinghua Zhang Yuan Liu Rongbin Dang Ruijuan Xiao Jin Wang Zhao Chen Feixiang Ding Xiaodong Guo Chao Yang Liangrong Yang Junmei Zhao Yong-Sheng Hu 《Advanced functional materials》2023,33(33):2302810
Na superionic conductor of Na3MnTi(PO4)3 only containing high earth-abundance elements is regarded as one of the most promising cathodes for the applicable Na-ion batteries due to its desirable cycling stability and high safety. However, the voltage hysteresis caused by Mn2+ ions resided in Na+ vacancies has led to significant capacity loss associated with Mn reaction centers between 2.5–4.2 V. Herein, the sodium excess strategy based on charge compensation is applied to suppress the undesirable voltage hysteresis, thereby achieving sufficient utilization of the Mn2+/Mn3+ and Mn3+/Mn4+ redox couples. These findings indicate that the sodium excess Na3.5MnTi0.5Ti0.5(PO4)3 cathode with Ti4+ reduction has a lowest Mn2+ occupation on the Na+ vacancies in its initial composition, which can improve the kinetics properties, finally contributing to a suppressed voltage hysteresis. Based on these findings, it is further applied the sodium excess route on a Mn-richer phosphate cathode, which enables the suppressed voltage hysteresis and more reversible capacity. Consequently, this developed Na3.6Mn1.15Ti0.85(PO4)3 cathode achieved a high energy density over 380 Wh kg−1 (based on active substance mass of cathode) in full-cell configurations, which is not only superior to most of the phosphate cathodes, but also delivers more application potential than the typical oxides cathodes for Na-ion batteries. 相似文献
23.
Ultra-Stable and Sensitive Ultraviolet Photodetectors Based on Monocrystalline Perovskite Thin Films
Xu Li Chang Liu Feng Ding Zheyi Lu Peng Gao Ziwei Huang Weiqi Dang Liqiang Zhang Xiaohui Lin Shuimei Ding Bailing Li Ying Huangfu Xiaohua Shen Bo Li Xuming Zou Yuan Liu Lei Liao Yiliu Wang Xidong Duan 《Advanced functional materials》2023,33(15):2213360
The detection of ultraviolet (UV) radiation with effective performance and robust stability is essential to practical applications. Metal halide single-crystal perovskites (ABX3) are promising next-generation materials for UV detection. The device performance of all-inorganic CsPbCl3 photodetectors (PDs) is still limited by inner imperfection of crystals grown in solution. Here wafer-scale single-crystal CsPbCl3 thin films are successfully grown by vapor-phase epitaxy method, and the as-constructed PDs under UV light illumination exhibit an ultralow dark current of 7.18 pA, ultrahigh ON/OFF ratio of ≈5.22 × 105, competitive responsivity of 32.8 A W−1, external quantum efficiency of 10867% and specific detectivity of 4.22 × 1012 Jones. More importantly, they feature superb long-term stability toward moisture and oxygen within twenty-one months, good temperature tolerances at low and high temperatures. The ability of the photodetector arrays for excellent UV light imaging is further demonstrated. 相似文献
24.
Xiaohui Lin Long Chen Chenglin He Yiliu Wang Xu Li Weiqi Dang Kun He Ying Huangfu Dan Wu Bei Zhao Bo Li Jia Li Xidong Duan 《Advanced functional materials》2023,33(1):2210278
Single crystal metal halide perovskites thin films are considered to be a promising optical, optoelectronic materials with extraordinary performance due to their low defect densities. However, it is still difficult to achieve large-scale perovskite single-crystal thin films (SCTFs) with tunable bandgap by vapor-phase deposition method. Herein, the synthesis of CsPbCl3(1–x)Br3x SCTFs with centimeter size (1 cm × 1 cm) via vapor-phase deposition is reported. The Br composition of CsPbCl3(1–x)Br3x SCTFs can be gradually tuned from x = 0 to x = 1, leading the corresponding bandgap to change from 2.29 to 2.91 eV. Additionally, an low-threshold (≈23.9 µJ cm−2) amplified spontaneous emission is achieved based on CsPbCl3(1–x)Br3x SCTFs at room temperature, and the wavelength is tuned from 432 to 547 nm by varying the Cl/Br ratio. Importantly, the high-quality CsPbCl3(1–x)Br3x SCTFs are ideal optical gain medium with high gain up to 1369.8 ± 101.2 cm−1. This study not only provides a versatile method to fabricate high quality CsPbCl3(1–x)Br3x SCTFs with different Cl/Br ratio, but also paves the way for further research of color-tunable perovskite lasing. 相似文献
25.
Yi Wei Wei Wang Zhennan Wang Hang Yang Xinyu You Yunna Zhao Peipei Dang Hongzhou Lian Jianhua Hao Guogang Li Jun Lin 《Advanced functional materials》2023,33(2):2205829
Bismuth (Bi3+)-included lead-free metal halide (LFMH) materials attract much attention in lighting, display, photodetectors, X-ray detectors, and photovoltaic fields, due to the tunable luminescence and optoelectronic performance in response to crystal and electronic structure, morphology, and particle sizes. This review summarizes Bi3+-included LFMH materials about their preparation approach, crystal and electronic structure properties, luminescence performance, and emerging applications. Notably, Bi3+ ions not only can act as framework cation to construct stable LFMH structure, but can also incorporate into LFMH materials as activators or sensitizers to generate remarkable luminescence tuning and band engineering. The Bi3+ effect on the luminescence and optoelectronic properties of LFMH materials, including, promotion of exciton localization, enhancement of light absorption in near-ultraviolet region, action as sensitizer ions to transfer energy to rare earth or transition metal ions and emission of highly-efficient light is systematically summarized. The proposed structure-luminescence relationship offers guidance for the optimization of current Bi3+-included LFMH materials and the exploitation of new LFMH derivatives. 相似文献
26.
Diamond,as an ultra-wide bandgap semiconductor,has become a promising candidate for next-generation microelec-tronics and optoelectronics due to its numerous advantages over conventional semiconductors,including ultrahigh carrier mo-bility and thermal conductivity,low thermal expansion coefficient,and ultra-high breakdown voltage,etc.Despite these ex-traordinary properties,diamond also faces various challenges before being practically used in the semiconductor industry.This review begins with a brief summary of previous efforts to model and construct diamond-based high-voltage switching diodes,high-power/high-frequency field-effect transistors,MEMS/NEMS,and devices operating at high temperatures.Following that,we will discuss recent developments to address scalable diamond device applications,emphasizing the synthesis of large-area,high-quality CVD diamond films and difficulties in diamond doping.Lastly,we show potential solutions to modulate diamond’s electronic properties by the“elastic strain engineering”strategy,which sheds light on the future development of diamond-based electronics,photonics and quantum systems. 相似文献
27.
Explicit formulas of minimum-variance linear unbiased estimators of the unknown mean are derived for homogeneous random fields with correlation functions observed on the set (a cross).Translated from Vychislitel'naya i Prikladnaya Matematika, No. 64, pp. 116–121, 1988. 相似文献
28.
H. S. Dang H. B. Desai D. D. Jaiswal S. R. Kayasth S. Somasundaram 《Journal of Radioanalytical and Nuclear Chemistry》1983,77(1):65-70
A simple separation scheme for the analysis of As, Mn, Mo, Cu and Zn using neutron activation is described. It has been checked
using three standard reference materials, A-11 milk powder (IAEA) and bovine liver and orchard leaves (USNBS) and found to
give acceptable results. This scheme was applied for determination of these trace elements in mature human milk samples. The
concentrations of As, Mn, Mo, Cu in samples obtained from two socio-economic groups—low and middle incomes—were not significantly
different. However, Zn levels in samples obtained from the poor income group were significantly lower than in those obtained
from the other group.
Work carried out under Research Contract No. 2598/RB of International Atomic Energy, Vienna.
Health Physics Division.
Analytical Chemistry Division. 相似文献
29.
文中报道两种新的含茂钛低钛物Cp_2Ti(Cl)-O-[-Ti(Cp)(O_2CCH_4CH-O)-O-]n-H(Ⅰ)与Cp_2Ti(Cl)-O-[-Ti(Cp)(O_2CCH_2CH)-O-]_u-H(Ⅰ)的制备并用元素分析和光谱(IR,1~H NMR,MS)对它们进行了鉴定。 相似文献
30.
Nishi K. Bhardwaj Viet Hoang Vinh Dang Kien L. Nguyen 《Colloids and surfaces. A, Physicochemical and engineering aspects》2006,290(1-3):222-228
A wide range of kraft pulps from radiata pine produced by low-temperature kraft pulping in flow-through reactors was assessed for carboxyl and hexenuronic acid (HexA) contents using the conductometric titrations and UV spectrophotometer, respectively. The Kappa number of pulps varied from 20.8 to 84.7 when using a cooking liquor of 1 M effective alkali as Na2O, 25% sulfidity, and cooking time of 100–250 min. The experimental results showed that the carboxyl groups (including HexA) and HexA groups dissolved and their residual values in the pulp samples correlate linearly with Kappa number and pulp yield. The dissolving rate of all carboxyl groups is much faster than the loss of HexA. The HexA/lignin ratio decreased non-linearly with Kappa number. 相似文献