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121.
This Letter presents the results of a series of measurements of the Newtonian gravitational constant G using the compensated torsion balance developed at the Measurement Standards Laboratory. Since our last published result using the torsion balance in the compensated mode of operation [Meas. Sci. Technol. 10, 439 (1999)]], several improvements have been made to reduce the uncertainty in the final result. The new measurements have used both stainless steel and copper large masses. The values of G for the two sets of masses are in good agreement. After combining all of the measurements we get a value of G=6.673 87(0.000 27) x 10(-11) m3 kg(-1) s(-2). This new value is 5 parts in 10(5) smaller than our previous published values. 相似文献
122.
TonyArmstrong 《世界电子元器件》2004,(7):38-39
许多微处理器和数字信号处理器(DSP)需要一个核心电源和一个在启动期间必须进行排序的输入/输出(I/O)电源。如果未经过适当的电源排序,可能发生闭锁或过流,从而损害微处理器的I/O端口或诸如存储器、逻辑电路、现场可编程门阵列(FPGA)或数据转换器之类支持设备的I/O端口。为了确保在主电源电压未被适当偏置之前I/O负载不被驱动,对核心电源电压和I/O电源电压进行跟踪是必要的。 相似文献
123.
(上接2009年第3期79页)
3.5.11浪涌抑制器件的组合应用
有时候靠一个浪涌抑制器件(SPD)很难满足所有的需求,为了优化SPD的浪涌抑制性能,同时减小生产成本,可以将多个SPD组合使用。图3AT是一个能够承受高功率的气体放电管(GDT)和一个箝位动作迅速的金属氧化物压敏电阻(MOV)的组合应用情况。GDT被触发后可以吸收大部分浪涌能量,当产生过压时,串联电感可以使GDT触发,而MOV可以保护负载不受GDT触发电压的影响。 相似文献
124.
Sanders L Halder M Xiao TL Ding J Armstrong DW Petrich JW 《Photochemistry and photobiology》2005,81(1):183-186
We report the first separation of the enantiomers of hypericin. Their steady-state optical spectra and ultrafast primary photoprocesses are investigated in chiral environments. Within experimental error, there is no difference between the two enantiomers in any of the systems considered. This is consistent with the emerging picture that the rich and extended absorption spectrum of hypericin is not a result of ground-state heterogeneity. It is also consistent with the observation that the spectra and photophysics of hypericin are generally insensitive to environments in which it does not aggregate. 相似文献
125.
Catalytic hydrogenation of dihydroindolizidinone occurred preferentially from the endo-face giving rapid entry to (8R,8aS)-8-methylhexahydroindolizin-5-one, a key intermediate in the synthesis of 5,8-disubstituted indolizidines and deoxypumiliotoxin 251H. The selectivity could be improved further by diimide reduction though this also resulted in some oxidation of the alkene to the diene. The basis of the unusual stereoselectivity in the diimide reduction is believed to be stereoelectronic in origin. 相似文献
126.
127.
Timothy J. Ward Daniel W. Armstrong Bronislaw P. Czech Jacek F. Koszuk Richard A. Bartsch 《Analytica chimica acta》1986
Two surface-active and one surface-inactive 18-crown-6 derivatives were synthesized and evaluated for their abilities to enhance flame atomic absorption and flame emission signals of monovalent cations. Enhancement of potassium signals were noted for the surface-active compounds but not for the surface-inactive compound. The critical micelle concentration was determined and compared to the degree of enhancement. Surfactant-induced signal enhancements are not due to the slight or moderate decrease in the size of the aerosol first produced in the nebulizing chamber. Additional mechanistic considerations are discussed. 相似文献
128.
Alan R. Kennedy Dr. Prokopis C. Andrikopoulos Dr. Jean‐Baptiste Arlin David R. Armstrong Dr. Neil Duxbury David V. Graham Jennifer B. A. Kirkhouse Dr. 《Chemistry (Weinheim an der Bergstrasse, Germany)》2009,15(37):9494-9504
The first solid‐state structures of ortho‐sulfonated monoazo dyestuffs are reported and compared to those of their para‐ and meta‐sulfonated analogues. The structures of the 16 Na, K, Cs, Mg, Ca, Sr, and Ba ortho‐sulfonated salts are found to have fewer M? O3S bonds than their isomeric equivalents and this in turn means that the metal type is no longer the prime indicator of which structural type will be adopted. M? O3S bonds are replaced by M? OH2, M? HOR and M–π interactions, apparently for steric reasons. As well as new bonding motifs, the changed dye shape also leads to new packing motifs. The simple organic/inorganic layering ubiquitous to the para‐ and meta‐sulfonated dye salt structures is replaced by variations (organic bilayers, inorganic channels), each of which correlates with a different degree of molecular planarity in the sulfonated azo dye anion. 相似文献
129.
Carcinogenic Chromium(VI) Compounds Formed by Intracellular Oxidation of Chromium(III) Dietary Supplements by Adipocytes 下载免费PDF全文
Dr. Lindsay E. Wu Dr. Aviva Levina Prof. Hugh H. Harris Dr. Zhonghou Cai Dr. Barry Lai Dr. Stefan Vogt Prof. David E. James Prof. Peter A. Lay 《Angewandte Chemie (International ed. in English)》2016,55(5):1742-1745
Chromium(III) nutritional supplements are widely consumed for their purported antidiabetic activities. X‐ray fluorescence microscopy (XFM) and X‐ray absorption near‐edge structure (XANES) studies have now shown that non‐toxic doses of [Cr3O(OCOEt)6(OH2)3]+ ( A ), a prospective antidiabetic drug that undergoes similar H2O2 induced oxidation reactions in the blood as other Cr supplements, was also oxidized to carcinogenic CrVI and CrV in living cells. Single adipocytes treated with A had approximately 1 μm large Cr hotspots containing CrIII, CrV, and CrVI (primarily CrVI thiolates) species. These results strongly support the hypothesis that the antidiabetic activity of CrIII and the carcinogenicity of CrVI compounds arise from similar mechanisms involving highly reactive CrVI and CrV intermediates, and highlight concerns over the safety of CrIII nutritional supplements. 相似文献
130.
Henderson NS Nijtmans LG Lindsay JG Lamantea E Zeviani M Holt IJ 《Electrophoresis》2000,21(14):2925-2931
We show that the blue native gel polyacrylamide electrophoresis system (BN-PAGE) can be applied to pyruvate dehydrogenase complex (PDC). BN-PAGE has been used extensively to study the multisubunit enzymes of oxidative phosphorylation, as nondenaturing separation in the first dimension maintains holoenzyme integrity. However, the standard protocol was inappropriate for PDC as, at 10 MDa, it is approximately ten times larger than the largest respiratory chain enzyme complex. Therefore, agarose was substituted for polyacrylamide. Moreover, a substantial decrease in salt concentration was necessary to prevent dissociation of PDC. As with standard BN-PAGE, immunoblots of second-dimensional sodium dodecyl sulfate-PAGE (SDS-PAGE) provided more detailed information on specific subunits and subcomplexes. The method was applied to human heart mitochondrial fragments, control cultured human cells, rho0 cells that lack mitochondrial DNA, and two cell lines derived from patients with PDC deficiency. The PDC deficient cell lines showed a clear correlation between amount of PDC holoenzyme and disease severity. In cells lacking mitochondrial DNA, synthesis and assembly of all PDC subunits (all nuclearly encoded) appeared normal, suggesting that respiratory function has no regulatory role in PDC biogenesis. Blue native agarose gel electrophoresis coupled with standard second-dimensional SDS-PAGE provides a new tool to be used in conjunction with biochemical assays and immunoblots of one-dimensional SDS-PAGE to further elucidate the nature of PDC in normal and disease states. Furthermore, other cellular protein complexes of 1 MDa or more can be analysed by this method. 相似文献