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31.
We report the spectroscopic properties of femtosecond laser-irradiated sodium-alumino-borate glass doped with silver and gold ions. We precipitated gold and silver nanoparticles by laser irradiation and annealing at 400°C for 30 min. The irradiation and annealing treatment produced different absorption and emission characteristics in Au3+ doped and Au3+, Ag+ codoped glasses, and the possible mechanisms of the observed results are discussed. The size of the nanoparticles was estimated by TEM and absorption band analysis.  相似文献   
32.
The mono- and di-chloroform solvates of [Au2(μ-1,2-bis(diphenylarsino)ethane)2](AsF6)2 undergo single-crystal-to-single-crystal transformations that result in gain (over 12 hours) or slow loss (over five years) of only one chloroform molecule. The change in solvation results in changes in the structure and luminescence of the digold cation. The cation consists of a pair of slightly bent As-Au-As units that are connected through the two bridging dpae ligands and by aurophilic interactions with Au⋅⋅⋅Au contacts of 3.05152(15) Å in the disolvate or 2.9570(5) Å in the monosolvate.  相似文献   
33.
An attempt to extend Nelson's stochastic quantization procedure to tensor fields indicates that the results of Guerra et al. on the connection between a euclidean Markov scalar field and a stochastic scalar field fails to hold for tensor fields.  相似文献   
34.
The bbody, 4-body and 5-body quantum mechanical systems with pairwise interactions having repulsive core and attractive tail and with completely symmetric permutation symmetry in the spatial wavefunctions are studied. The spatial distribution of the wavefunctions of the low-lying O+ states is investigated in detail. The features of the geometric structures and of the internal motions of each of these states are revealed. Certain modes of the internal motions are discovered.  相似文献   
35.
To clarify the nature of microscopic structural changes of N(CH3)4CdCl3 at high temperatures, the nuclear magnetic resonance (NMR) spectra of the protons and carbons in N(CH3)4CdCl3 were measured. NMR studies of the 1H and 13C spin–lattice relaxation time, T , in the rotating frame were also performed. No changes in the T of 1H and 13C associated with the N(CH3)4 groups were observed at the high-temperature transition from phase I to phase I′. However, the 14N NMR spectra reflected changes in the structural geometry during the transition to phase I′, indicating that this transition is driven by N(CH3)4.  相似文献   
36.
Let V be a Euclidean Jordan algebra, and let be the corresponding symmetric cone. The geometric mean of two elements a and b in is defined as a unique solution, which belongs to of the quadratic equation where P is the quadratic representation of V. In this paper, we show that for any a in the sequence of iterate of the function defined by converges to a. As applications, we obtain that the geometric mean of can be represented as a limit of successive iteration of arithmetic means and harmonic means, and we derive the L?wner-Heinz inequality on the symmetric cone Furthermore, we obtain a formula which leads a Golden-Thompson type inequality for the spectral norm on V. Received October 5, 1999 / Revised March 6, 2000 / Published online October 30, 2000  相似文献   
37.
We consider an integrated problem of plant location and capacity planning for components procurement in knockdown production systems. The problem is that of determining the schedule of opening components manufacturing plants, plans for acquisition of capacities in opened components manufacturing plants, and plans for components procurement in final assembly plants with the objective of minimizing the sum of fixed costs for opening plants, acquisition and operation costs of facilities, and delivery and subcontracting costs of components. The problem is formulated as a mixed integer linear program and solved by a two-stage solution procedure. In the solution procedure, the problem is decomposed into two tractable subproblems and these subproblems are solved sequentially. In the first stage, a dynamic plant location problem is solved using a cut and branch algorithm based on Gomory cuts, while a multiperiod capacity planning problem is solved in the second stage by a heuristic algorithm that uses a cut and branch algorithm and a variable reduction scheme. The solution procedure is tested on problems of a practical size and results show that the procedure gives reasonably good solutions.  相似文献   
38.
MMoO4 (M=Ca, Ba) particles were synthesized by a metathetic reaction in ethylene glycol assisted by cyclic microwave irradiation followed by further heat-treatment. The MMoO4 (M=Ca, Ba) particles were well crystallized after heat-treatment at 400–600 °C for 3 h. The microstructures exhibited fine morphologies with sizes of 0.5–1 μm and 1.5–2 μm for the CaMoO4 and BaMoO4 particles, respectively. The synthesized MMoO4 (M=Ca, Ba) particles were characterized by X-ray diffraction, Fourier transform infrared spectroscopy, scanning electron microscopy and transmission electron microscopy. The optical properties were examined by photoluminescence emission and Raman spectroscopy.  相似文献   
39.
Lim  Hyun-Hee  Choi  Kyeong-Yun  Shin  Ho-Sang 《Chromatographia》2022,85(8):699-717
Chromatographia - Optimal derivatization conditions were established for the simultaneous determination of 12 aliphatic saturated aldehydes, 8 aliphatic saturated ketones, 4 cyclic ketones, 3...  相似文献   
40.
Available in small print : Block copolymer lithography has great potential for reducing the size and fabrication time of integrated circuits. Hydrogen‐bonding‐mediated molecular recognition in self‐assembly processes can be used to produce highly ordered square arrays of block copolymers on the surface of a silicon substrate (see picture).

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