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71.
The polymeric material is very promising for fabricating the integrated optical waveguide devices. The polymeric op- tical waveguide has become the hotspot because the poly- meric material can offer a series of merits, such as easy integration, rapid resp… 相似文献
72.
Shaolin Liao Ronald J. Vernon 《International Journal of Infrared and Millimeter Waves》2007,28(6):479-490
The newly developed Taylor-Interpolation-FFT (TI-FFT) algorithm dramatically increases the computational speeds for millimeter
wave propagation from a planar (cylindrical) surface onto a “quasi-planar” (“quasi-cylindrical”) surface. Two different scenarios
are considered in this article: the planar TI-FFT is for the computation of the wave propagation from a plane onto a “quasi-planar” surface and the cylindrical TI-FFT is for the computation of wave propagation from a cylindrical surface onto a “quasi-cylindrical” surface. Due to the
use of the FFT, the TI-FFT algorithm has a computational complexity of O(N
2 log2
N
2) for an N × N computational grid, instead of N
4 for the direct integration method. The TI-FFT algorithm has a low sampling rate according to the Nyquist sampling theorem.
The algorithm has accuracy down to −80 dB and it works particularly well for narrow-band fields and “quasi-planar” (“quasi-cylindrical”)
surfaces. 相似文献
73.
W. Liu J.S. Wang X.L. Liao S.J. Zheng G.T. Ma J. Zheng S.Y. Wang 《Physica C: Superconductivity and its Applications》2011,471(5-6):156-162
To a high-Tc superconducting (HTS) maglev system which needs large levitation force density, the magnetized bulk high-Tc superconductor (HTSC) magnet is a good candidate because it can supply additional repulsive or attractive force above a permanent magnet guideway (PMG). Because the induced supercurrent within a magnetized bulk HTSC is the key parameter for the levitation performance, and it is sensitive to the magnetizing process and field, so the magnetized bulk HTSC magnets with different magnetizing processes had various levitation performances, not only the force magnitude, but also its force relaxation characteristics. Furthermore, the distribution and configuration of the induced supercurrent are also important factor to decide the levitation performance, especially the force relaxation characteristics. This article experimentally investigates the influences of different magnetizing processes and trapped fields on the levitation performance of a magnetized bulk HTSC magnet with smaller size than the magnetic inter-pole distance of PMG, and the obtained results are qualitatively analyzed by the Critical State Model. The test results and analyses of this article are useful for the suitable choice and optimal design of magnetized bulk HTSC magnets. 相似文献
74.
Mallamace F Gambadauro P Micali N Tartaglia P Liao C Chen S 《Physical review letters》2000,84(23):5431-5434
We show that percolation and structural arrest transitions coexist in different regions of the phase diagram of a copolymer-micellar system and relate them to short-range intermicellar attraction. The intermediate scattering function shows a nonergodic transition along a temperature and concentration dependent line. Analyses show a logarithmic time dependence, attributed to a higher-order glass transition singularity predicted by mode-coupling theory, followed by a power law. 相似文献
75.
此文简要叙述用于离子束材料改性装置的Freeman离子源的特性,其主要参数:灯丝电流、孤压、磁场、气流量和吸极电压与引出离子束流强的关系。对源体内部因微漏冷却水(真空度由3.9×10-4降至4.2×10-4Pa)致使气体分子电离、起弧困难和等离子体不稳作了实验研究;对灯丝与弧室间的氮化硼绝绝物上沉积被溅射出的W、Mo原子导致绝缘下降、灯丝寿命缩短进行了部份结构改进。结果表明,提高加工工艺,确保真空系统密封性能和输入气体纯度对弧室内气体分子碰撞电离和等离子体的稳定至关重要;在BN绝缘物上放置钼制屏蔽罩有效地屏蔽掉W、MO原子沉积使灯丝寿命延长一倍,达到了40小时。 相似文献
76.
Herein we report a novel visible-light-mediated external reductant-free reductive cross coupling for the construction of C sp~2–C sp~3 bonds. A variety of benzylammonium salts underwent selective coupling with(hetero)aryl nitriles to deliver important diarylmethanes under mild reaction conditions. Importantly, photocatalysts can be omitted for many cases, which might involve the electron donor acceptor(EDA) complex. Mechanistic studies indicated benzylic radicals might be involved as the key intermediates. Moreover, the in situ generated NMe_3 via cleavage of C–N bond in ammonium salts acts as the electron donor,thus avoiding the use of external-reductant. 相似文献
77.
Wei-Zhen Sun Lin-Lin Dai Xiang-He Kong Yu Mao Zhi-Lin Wu Li-Fu Liao Xi-Lin Xiao Chang-Ming Nie 《应用有机金属化学》2020,34(4):e5486
The design of new uranyl-ligands (uranyl-Ls) is of great significance for the separation and utilization of uranium. In this paper, the triazole group was introduced into uranyl-salophen (uranyl-S) to form new asymmetric uranyl-unilateral benzotriazole salophen (uranyl-UBS); we further replaced two oxygen atoms of uranyl-UBS with two sulfur atoms to generate uranyl-unilateral benzotriazole thio-salophen (uranyl-UBTS) as a new receptor. Then, we comprehensively explored coordination models of uranyl-UBS and uranyl-UBTS with R/S-triadimefons (R/S-TDFs) enantiomers as the guests using density functional theory calculations at the B3LYP//RECP/6-311G** level; we then investigated enantioselectivity recognition of the new receptors to the guests R/S-TDFs. The results indicated that the uranium atoms of the receptors uranyl-S, uranyl-UBS and uranyl-UBTS could coordinate with the carbonyl oxygens in guests R/S-TDFs to form complexes of guest-receptors R/S-TDFs-uranyl-Ls that exhibited two stable V-shaped structures with quite different properties. It was found that the coordination ability to the guests R/S-TDFs is uranyl-UBTS > uranyl-UBS > uranyl-S, while the enantioselectivity for the guests is uranyl-UBTS > uranyl-S > uranyl-UBS and, when the receptor is the same, R-TDF has stronger coordination ability than S-TDF. These results provide information and theoretical supports for the experiments of asymmetric uranyl-UBS with R/S-TDFs, and produce a reference for further exploring the coordination characteristics of asymmetric uranyl-salophen with the triazole derivatives. 相似文献
78.
Fang Tao Chen Xiuting Wang Miao Wang Yanan Liao Lixia Li Bin 《Research on Chemical Intermediates》2020,46(12):5459-5477
Research on Chemical Intermediates - In recent years, how to improve photocatalytic performance under visible light has become one of the research hot topics. The nano-TiO2 particles were... 相似文献
79.
Nonlinear Dynamics - The continuation and stability analysis methods for quasi-periodic solutions of nonlinear systems are proposed. The proposed continuation method advances the... 相似文献
80.
Dr. Gang Liao Dr. Tao Zhang Zhi-Keng Lin Prof. Dr. Bing-Feng Shi 《Angewandte Chemie (Weinheim an der Bergstrasse, Germany)》2020,132(45):19941-19954
Transition metal-catalyzed enantioselective functionalization of C−H bond, the most abundant functionality in organic molecules, has emerged as an expedient synthetic approach to streamline the synthesis of complex chiral molecules. Despite significant progress, traditional directing group-enabled strategies require additional steps for the installation and removal of directing groups from the target molecule. The recently developed asymmetric C−H functionalization using chiral transient directing groups (cTDGs) offers a promising alternative that can circumvent this obstacle and therefore simplify the process. In this Minireview, we briefly discuss the advent and recent advances of this emerging concept, with an emphasis on discussing the creation of various stereogenic centers and the developments of cTDGs. Applications in natural product synthesis and ligand derivatizations are also discussed. We hope this Minireview will highlight the great potential of this strategy and help to inspire further endeavors. 相似文献