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911.
Xi Li Yi Liu Jun Wu Huigang Liang Songsheng Qu 《Journal of Thermal Analysis and Calorimetry》2002,67(3):589-595
The action of three kinds of the selenomorpholine compounds on a strain ofEscherichia coli was studied by microcalorimetry. Differences in their capacities to affect the metabolism of this bacterium were observed.
The extent and duration of the effect on the metabolism as judged from the rate constant (k) of Escherichia coli (in log phase) varied with the different drugs. The kinetics show that selenomorpholine compounds had an effect on the metabolism
process of Escherichia coli. The k of Escherichia coli in the presence of the drugs increased with the increasing concentrations of the drugs (C) at low concentration; but at high concentration, the rate constant decreased with the increasing concentrations of the drugs.
The experimental results reveal that the sequence of antibiotic activity of selenomorpholines is: N-selenomorpholinemethyl
succinimide and its hydrochloride>N-(α-selenomorpholinebenzyl) succinimide.
This revised version was published online in August 2006 with corrections to the Cover Date. 相似文献
912.
2-(Chloromethyl)furan as an electrophile reacted with lithium trialkylalkyllylbo-rates,followcl by the oxidation with H_2O_2 under basic condition to afford 2-furfurylketonesin good yields.This provides a new method for the preparation of 2-furfurylkctoncs. 相似文献
913.
The thermal reaction of HNCO has been studied in a static cell at temperatures between 873 and 1220 K and a constant pressure of 800 torr under highly diluted conditions. The reaction was measurable above 1000 K by FTIR spectrometry. The products detected include CO, CO2, HCN, NH3, and the unreacted HNCO. In this moderate temperature regime, the rates of product formation and HNCO decay cannot be accounted for by a previously established high-temperature mechanism, assuming HNCO → NH + CO (1) as the initiation process. Instead, a new bimolecular reaction, 2HNCO → CO2 + HNCNH (2), has been invoked to interpret the disappearance of HNCO as well as the formation of various products, most importantly CO2. The concentration profiles of all measured species can be quantitatively modeled, throughout the temperature range analyzed, by varying k2 using a modified mechanism. The kinetically modeled values of k2 can be effectively represented by This result agrees closely with that computed with the conventional transition-state theory using the TST parameters predicted by the BAC-MP4 method: The bimolecular reaction takes place via a stable 4-membered ring intermediate which is isoelectronic with diketene; viz. 相似文献
914.
1引言最近二、三十年来,定域化分子轨道(LM阿理论在化学的各领域内都得到了广泛的应用[‘-‘].本文试图采用LMO方法的计算来研究化学反应.期望对反应过程中电子在各原子间的转移和重新排布,以及键的断裂和生成有一个具体的了解.对于HaPO、H。POH异构化反应(见图1)来说,可看成是H’原子绕P原子向0原子方向移动的结果,而角度zH‘PO的大小可看成是反应过程的一个标度或“反应坐标”.本文中氢原子的编号H‘护p‘仅是为计算和分析的方便而加以标识的.每给定一个ZH‘PO角度,我{rl都采用GAUSSIAN80程序在3-21G基组… 相似文献
915.
Zhang Q Liang X Chen J Lu P Yediler A Kettrup A 《Analytical and bioanalytical chemistry》2002,374(1):93-102
A method has been developed for peak identification of PCBs in GC with ECD detection under different temperature programs and isothermal conditions on two commonly used columns (DB-5 and DB-1701). This was achieved by means of accurate calibration of retention times based on the concept of the relative retention index P (i) and retention times of the selected PCB internal standards. The P (i) was calculated from the predicted retention times with the database of the retention parameters (A, B) and the migration equations. Through comparison of the calibrated and experimental retention times of PCBs in technical samples, it was shown that the developed method was effective for correct PCB comprehensive, quantitative, congener-specific (CQCS) analyses. 相似文献
916.
本文把单个分子链的横截面积与聚合物的玻璃化转变温度联系起来,发现对于所讨论的聚合物,考虑了分子链间的相互作用以后,上面二者之间有一一对应的关系。认为单个分子链的横截面积与聚合物分子链柔顺性有关。同时采用文献[17]的方法,得到了1,2-聚丁二烯的分子链的内旋转异构化能,比较所得结果,证实了上面的看法。 相似文献
917.
918.
919.
Chromatographic Features and Molecular Recognition Mechanism of a Strychnine Monolithic Molecularly Imprinted Polymer 总被引:1,自引:0,他引:1
A monolithic molecularly imprinted polymer (mMIP) with specific recognition ability for strychnine was prepared by in-situ polymerization, using methacrylic acid (MAA) as a functional monomer, ethylene glycol dimethacrylate (EDMA) as a cross-linking agent, toluene and dodecanol as porogenic solvents and 2, 2’-azobisisobutyronitrile (AIBN) as a initiator. Scanning electron microscopy and mercury intrusion porosimetry were used to identify the structural features of the mMIP. The results show that there were three kinds of pore structures. The large through-pore structure allows mobile phase to flow through a column of mMIP with a low back pressure and the other pores lead to the molecular recognition. Some chromatographic conditions such as the pH and the composition of the mobile phase were characterized. Strychnine was separated from compounds such as indole, quinine and brucine. The possible recognition mechanisms were ionic and hydrogen bonding interactions between the strychnine molecule and the mMIP. 相似文献
920.
采用Seemann-Bohlin准聚焦X射线衍射仪测量薄膜厚度的误差理论分析 总被引:1,自引:0,他引:1
本文从理论上分析了衍射强度比偏差Δ(I/I∞)和衍射峰位偏差Δ2θ对Seemann-Bohlin准聚焦X射线衍射仪测量表面单层薄膜厚度误差的影响。分析结果表明,降低Δ(I/I∞)可提高膜厚的测量精度,在Δ(I/I∞)-定的情况下,按μρt[Sin(-1)γ+Sin(-1)(2θ-γ)]=1选择靶辐射和衍射晶面可使由Δ(I/I∞)导致的膜厚测量误差具有极小值;选择高角度衍射线有助于减小试样离焦引起的衍射峰位偏差,亦可降低因衍射角测量偏差导致的膜厚测量误差,当衍射线处于薄膜的法向2θ=γ+π/2时,角度项误差(Δt/t)(2θ)完全消除。 相似文献