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151.
152.
To incorporate an acceptor type polythiophene segment onto a supramolecular block copolymer for potential light harvesting applications, effective synthetic routes for the end‐functionalized and acceptor‐substituted polythiophenes are critical. The Ullmann coupling reaction can be utilized to obtain electron‐deficient polythiophenes and to attach terminal thiophene units that carry functional groups. In this article, the reactions involving a 2,5‐dibromothiophene monomer containing an electron‐withdrawing fluorinated ester and 5‐bromo‐2‐thiophenecarboxaldehyde (the end‐capper) were studied in detail. It was found that the Ullmann coupling reaction of the dibromide is very fast (completed in a few minutes) and the terminal bromine group does not survive long under the reaction condition. These findings lead to the development of an effective procedure for aldehyde end‐capping of electron‐deficient polythiophenes. Polymers with molecular weights around 4000 Da are routinely obtained. © 2006 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 45: 41–47, 2007 相似文献
153.
Grens C.M. Cressler J.D. Andrews J.M. Qingqing Liang Joseph A.J. 《Electron Devices, IEEE Transactions on》2007,54(7):1605-1616
This paper presents a comprehensive picture of operating-voltage constraints in SiGe heterojunction bipolar transistors, addressing breakdown-related issues as they relate to technology generation, bias configuration, and operating-current density. New definitions for breakdown voltage, adopted from standard measurements, are presented. Practical design implications and physical origins of breakdown are explored using calibrated 2-D simulations and quasi-3-D compact models. Device-level analysis of ac instabilities and power performance, which is relevant to mixed-signal circuit design, is presented, and implications of the relaxed voltage constraints for common-base operation are explored. 相似文献
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155.
Cheng Chen Zheng Guo Li Yeng Chai Soh 《Networking, IEEE/ACM Transactions on》2007,15(3):697-708
In this paper, we shall generalize the concepts of fairness, TCP-friendliness and TCP-compatibility such that more source adaptation schemes can be designed to support diverse applications over the Internet. A simple but efficient framework, in the form of a monotonic response function (MRF), is proposed for the analysis and the design of memoryless window-based source adaptation protocols by using these concepts. We first derive a necessary and sufficient condition for step-wise convergence to the weighted fairness. It is then used to construct increase-decrease policies. The requirements of our increase-decrease policy are less conservative than those of the CYRF (Choose Your Response Function) that was proposed in . Our MRF is suitable for transmission control protocol (TCP) and user datagram protocol (UDP), and can be used to design TCP-friendly and multimedia-friendly source adaptation schemes. Meanwhile, our MRF can be applied to provide bandwidth differentiation service without any change to the router of the existing Internet. 相似文献
156.
Q.-Y. Shao A.-D. Li J.-B. Cheng H.-Q. Ling D. Wu Z.-G. Liu N.-B. Ming C. Wang H.-W. Zhou B.-Y. Nguyen 《Applied Physics A: Materials Science & Processing》2005,81(6):1181-1185
LaAlO3 (LAO) gate dielectric films were deposited on Si substrates by low-pressure metalorganic chemical vapor deposition. The interfacial structure and composition distribution were investigated by high-resolution transmission electron microscopy (HRTEM), X-ray photoelectron spectroscopy (XPS), secondary-ion mass spectroscopy (SIMS), and Auger-electron spectroscopy (AES). HRTEM confirms that there exists an interfacial layer between LAO and Si in most samples. AES, SIMS, and XPS analyses indicate that the interfacial layer is compositionally graded La–Al silicate and the Al element is severely deficient close to the Si surface. Electrical properties of LAO films were evaluated. No evident difference in electrical properties between samples with and without native SiO2 layers was observed. The electrical properties are discussed in terms of LAO growth mechanisms, in relation to the interfacial structure. PACS 73.40.Qv; 81.15.Gh; 77.55.+f; 68.35.-p 相似文献
157.
一个推广的Hardy-Hilbert型不等式及其逆式 总被引:1,自引:0,他引:1
本文引入单参数λ及应用Beta函数,给一个Hardy-Hilbert型不等式以具有最佳常数因子的推广,作为应用,给出了它的逆向形式. 相似文献
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160.
本文研究了电子束光刻中电子能量(10—30keV)和电荷剂量(10~(-6)—10~(-3)C·cm~(-2))对铝栅MOS电容器的损伤和低温退火(<500℃)的影响。研究电子束光刻中高能量(30keV)和高剂量(10~(-3)C·cm~(-2))电子束引起的损伤,对电子束汽相显影光刻和电子束无显影光刻是有实际意义的。实验表明,平带电压的损伤可高达十几伏,界面态密度可高达10~(12)cm~(-2)eV~(-1)以上。在一定电荷剂量下,平带电压的损伤对电子能量的变化(在一定范围内)不敏感。在一定电子能量下,界面态密度的损伤对电荷剂量的变化(在一定范围内)不敏感。低温(<500℃)退火能完全消除平带电压的损伤,但不能完全消除界面态密度的损伤。 相似文献