The effect of micro-morphology of Bi2O3 on catalytic properties of Co/Bi catalyst for wet air oxidation of acetic acid

The novel phase transfer catalysts S-8 [4-(dimethyloctylammonium) propansultan] and DB-X [1,4-bis(triethylmethylammonium)benzene dibromide] were synthesized and employed for high conversion synthesis of dichlorocyclopropane from various olefins.This revised version was published online in December 2005 with corrections to the Cover Date.     

基于可重构FPGA技术的自适应FIR滤波器的实现

有限冲激响应(FIR)滤波器设计遇到的难题是滤波要进行大量乘法运算,即使是在全定制的专用集成电路中也会导致过大的面积与功耗.对于用硬件实现系数是常量的专用滤波器,可以通过分解系数变为应用加、减和移位而实现乘法.FIR滤波器的复杂性主要由用于系数乘法的加法器/减法器的数量决定.而对于自适应FIR滤波器,大多数场合下可用数字信号处理器(DSP)或CPU通过软件编程的方法来实现,但是对于要求高速运算的场合,VLSI实现是很好的选择.基于这一考虑,可以用符号数的正则表示(CSD)码表示系数, 再利用可重构现场可编程门阵列(FPGA)技术实现.可重构结构的应用,能保证系统的其余部分同时处于运行状态时实现FIR滤波器系数的更新.文中利用CSD码和可重构思想,提出了用FPGA实现自适应FIR滤波器的一种方案.     

双积分A/D转换器的量程自动转换

介绍了一种双积分式A/D转换器在宽范围量程测量中的自动量程转换技术.在测量仪表的输入通道中,用计数器对双积分型A/D转换器本身所固有的过量程/欠量程信号计数,计数器的输出作为量程编码去控制量程的选择,同时又是送到CPU的量程指示信号.该技术扩大了A/D转换量程,提高了精度,设计简单,工作可靠.     

语音播放邮件系统的设计与实现

基于组件对象模型(COM)技术和微软Office 2000套件的自动化技术,采用内嵌可视BASIC语言(VB)应用编程方法开发了一个基于Outlook 2000的客户端文字邮件语音播放系统.详细介绍了微软语音插件Speech SDK v5.1的架构以及在Outlook 2000中内嵌VB的开发过程.该系统在功能上实现了邮件正文及附件的自动语音播放,在软件界面上实现了语音应用模块与Outlook的无缝集成.     

朗讯cdma 1x基站分组管宽度的配置

简单介绍朗讯系统cdma 1x基站分组管(PP)宽度的配置，并对朗讯cdma 1x基站分组管宽度不合理的配置及信道板扩容后的PP宽度配置进行了案例分析。     

MC模式下顾客需求与厂商供应的纳什均衡

在大规模定制(MC，Mass Customization)模式下，基于市场需求的复杂化，厂商对个性化的顾客需求很难做出及时准确的反应，而且由于其自身生产能力的限制，不可能对所有的个性化用户进行一一地满足，只可能对已经存在的个性化需求，根据自身的生产能力和规模，以利润最大化及顾客对产品的满意度为目标，对个性化需求进行较准确地预测，从而正确指导生产。本通过博弈论的方法，提出了一个基于顾客对产品的满意度及企业的利润的一个非合作博弈模型，并给出求解纳什均衡的方法。     

Low Cost, High Efficiency, Gain Flattened L Band EDFA Using FBGs as C Band Seed Generators

A low cost, coolerless 980nm diode pumped, gain flattened L band EDFA with fast transient control, high pump efficiency and gain clamping effect was realized by using FBGs as C band seed generators.     

Living/controlled radical copolymerization of N‐substituted maleimides with styrene in 1‐butyl‐3‐methylimidazolium hexafluorophosphate and anisole

The atom transfer radical copolymerization of N‐substituted maleimides such as N‐phenylmaleimide (PhMI), N‐cyclohexylmaleimide (ChMI), and N‐butylmaleimide (NBMI) with styrene initiated with dendritic polyarylether 2‐bromoisobutyrates in an ionic liquid, 1‐butyl‐3‐methylimidazolium hexafluorophosphate ([bmim][PF₆]), at room temperature and anisole at 110 °C was investigated. The dendritic‐linear block copolymers obtained in ionic liquid possessed well‐defined molecular weight and low polydispersity (1.05 < M_w/M_n < 1.32) and could be used as a macroinitiator for chain‐extension polymerization, suggesting the living nature of the reaction system. The ionic liquids containing catalyst could be recycled in the atom transfer radical polymerization systems without further treatment. Compared with polymerization conducted in anisole, the polymerization in ionic liquid had a stronger tendency for alternation. The tendency for alternation decreased in the order PhMI > NBMI > ChMI in [bmim][PF₆] and PhMI > ChMI > NBMI in anisole. © 2003 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 41: 2156–2165, 2003     

Yellow‐light‐emitting cyano‐substituted poly[(1,3‐phenylene vinylene)‐alt‐(1,4‐phenylene vinylene)] derivative: Its synthesis and optical properties

A soluble cyano‐substituted poly[(1,3‐phenylene vinylene)‐alt‐(1,4‐phenylene vinylene)] derivative ( 9 ) was synthesized and characterized. Comparison between 9 and its model compound ( 10 ) showed that the chromophore in 9 remained to be well defined as a result of a π‐conjugation interruption at adjacent m‐phenylene units. The attachment of a cyano substituent only at the β position of the vinylene allowed the maximum electronic impact of the cyano group on the optical properties of the poly(p‐phenylene vinylene) material. At a low temperature (?108 or ?198 °C), the vibronic structures of 9 and 10 were partially resolved. The absorption and emission spectra of a film of 9 were less temperature‐dependent than those of a film of 10 , indicating that the former had a lower tendency to aggregate. A light‐emitting diode (LED) based on 9 emitted yellow light (λ_max ≈ 578 nm) with an external quantum efficiency of 0.03%. © 2003 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 41: 3149–3158, 2003     

CNx纳米管的制备、结构观察及低场致电子发射性能研究

采用高温热解法，以乙二胺为前驱液，在沉积有铁催化剂的p型硅（111）基底上制备出了定向生长的CNx纳米管.利用扫描电子显微镜、高分辨率透射电子显微镜和拉曼光谱对CNx纳米管进行了形貌观察和表征.CNx纳米管的高度在20?μm左右，直径在50—100nm之间，具有明显的“竹节状”结构，结晶有序度较差.对CNx纳米管薄膜进行低场致发射性能测试：外加电场为1.4V/μm，观察到20?μA /cm2发射电流，外电场升至2.54V/μm时发射电流达到1.280mA/cm2，在较高外电场下，没有发现电流“饱和”.这比 关键词： CNx纳米管 高温热解 “竹节状”结构 场致发射