全文获取类型
收费全文 | 215598篇 |
免费 | 21402篇 |
国内免费 | 14700篇 |
专业分类
化学 | 92003篇 |
晶体学 | 1816篇 |
力学 | 12700篇 |
综合类 | 631篇 |
数学 | 42440篇 |
物理学 | 55709篇 |
无线电 | 46401篇 |
出版年
2024年 | 571篇 |
2023年 | 3400篇 |
2022年 | 4243篇 |
2021年 | 5410篇 |
2020年 | 5330篇 |
2019年 | 4779篇 |
2018年 | 15147篇 |
2017年 | 14720篇 |
2016年 | 12251篇 |
2015年 | 7172篇 |
2014年 | 7842篇 |
2013年 | 9905篇 |
2012年 | 15342篇 |
2011年 | 22488篇 |
2010年 | 14533篇 |
2009年 | 14514篇 |
2008年 | 15437篇 |
2007年 | 16948篇 |
2006年 | 7570篇 |
2005年 | 7644篇 |
2004年 | 6058篇 |
2003年 | 5714篇 |
2002年 | 4374篇 |
2001年 | 3153篇 |
2000年 | 3001篇 |
1999年 | 3104篇 |
1998年 | 2747篇 |
1997年 | 2487篇 |
1996年 | 2506篇 |
1995年 | 2065篇 |
1994年 | 1842篇 |
1993年 | 1549篇 |
1992年 | 1355篇 |
1991年 | 1162篇 |
1990年 | 898篇 |
1989年 | 704篇 |
1988年 | 557篇 |
1987年 | 454篇 |
1986年 | 450篇 |
1985年 | 375篇 |
1984年 | 254篇 |
1983年 | 186篇 |
1982年 | 161篇 |
1981年 | 114篇 |
1980年 | 102篇 |
1979年 | 76篇 |
1914年 | 45篇 |
1912年 | 40篇 |
1909年 | 41篇 |
1908年 | 40篇 |
排序方式: 共有10000条查询结果,搜索用时 9 毫秒
21.
Wei Li Zhang Wei Pan Bin Luo Xi Hua Zou Meng Yao Wang 《Photonics Technology Letters, IEEE》2008,20(9):712-714
A theoretical construction of one-to-many (OTM) and many-to-one (MTO) chaos synchronization communications using semiconductor lasers is presented. One center laser provides strong injections (strong link) to other side lasers, and the side lasers also provide weak injections (weak link) to the center one. Simulation results show that the side lasers synchronize with the center laser through injection-locking. In addition, messages transmitted via the strong links or the weak links experience strong chaos pass filtering, enabling us to realize OTM and MTO communications. 相似文献
22.
Christiane Albrecht 《Analytical and bioanalytical chemistry》2008,390(5):1223-1224
23.
24.
Chengzhi Qi Mingyang Wang Qihu Qian Jianjie Chen 《Moscow University Mechanics Bulletin》2008,63(5):113-121
The formation mechanisms for the structural hierarchy in geological media are discussed. It is shown that the formation of such a hierarchy is caused by certain external and internal circumstances. The first ones consist in the fact that, because of external actions, the Earth’s poles continuously execute the translational and rotational motions responsible for a regular structure of rock fracture and for the appearance of the scale factor √2. The second ones consist in the fact that, under the action of many random factors and because of external actions, during the formation of geological media there appear dissipative structures and, hence, some self-similar fractal structures are formed. 相似文献
25.
Guobao Zhang Jianming Zhang Shenguo Wang Deyan Shen 《Journal of Polymer Science.Polymer Physics》2003,41(1):23-30
Blends of amorphous poly(DL‐lactide) (DL‐PLA) and crystalline poly(L‐lactide) (PLLA) with poly(methyl methacrylate) (PMMA) were prepared by both solution/precipitation and solution‐casting film methods. The miscibility, crystallization behavior, and component interaction of these blends were examined by differential scanning calorimetry. Only one glass‐transition temperature (Tg) was found in the DL‐PLA/PMMA solution/precipitation blends, indicating miscibility in this system. Two isolated Tg's appeared in the DL‐PLA/PMMA solution‐casting film blends, suggesting two segregated phases in the blend system, but evidence showed that two components were partially miscible. In the PLLA/PMMA blend, the crystallization of PLLA was greatly restricted by amorphous PMMA. Once the thermal history of the blend was destroyed, PLLA and PMMA were miscible. The Tg composition relationship for both DL‐PLA/PMMA and PLLA/PMMA miscible systems obeyed the Gordon–Taylor equation. Experiment results indicated that there is no more favorable trend of DL‐PLA to form miscible blends with PMMA than PLLA when PLLA is in the amorphous state. © 2002 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 41: 23–30, 2003 相似文献
26.
You‐Liang Zhao Chuan‐Fu Chen Fu Xi 《Journal of polymer science. Part A, Polymer chemistry》2003,41(14):2156-2165
The atom transfer radical copolymerization of N‐substituted maleimides such as N‐phenylmaleimide (PhMI), N‐cyclohexylmaleimide (ChMI), and N‐butylmaleimide (NBMI) with styrene initiated with dendritic polyarylether 2‐bromoisobutyrates in an ionic liquid, 1‐butyl‐3‐methylimidazolium hexafluorophosphate ([bmim][PF6]), at room temperature and anisole at 110 °C was investigated. The dendritic‐linear block copolymers obtained in ionic liquid possessed well‐defined molecular weight and low polydispersity (1.05 < Mw/Mn < 1.32) and could be used as a macroinitiator for chain‐extension polymerization, suggesting the living nature of the reaction system. The ionic liquids containing catalyst could be recycled in the atom transfer radical polymerization systems without further treatment. Compared with polymerization conducted in anisole, the polymerization in ionic liquid had a stronger tendency for alternation. The tendency for alternation decreased in the order PhMI > NBMI > ChMI in [bmim][PF6] and PhMI > ChMI > NBMI in anisole. © 2003 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 41: 2156–2165, 2003 相似文献
27.
Liang Liao Yi Pang Liming Ding Frank E. Karasz 《Journal of polymer science. Part A, Polymer chemistry》2003,41(20):3149-3158
A soluble cyano‐substituted poly[(1,3‐phenylene vinylene)‐alt‐(1,4‐phenylene vinylene)] derivative ( 9 ) was synthesized and characterized. Comparison between 9 and its model compound ( 10 ) showed that the chromophore in 9 remained to be well defined as a result of a π‐conjugation interruption at adjacent m‐phenylene units. The attachment of a cyano substituent only at the β position of the vinylene allowed the maximum electronic impact of the cyano group on the optical properties of the poly(p‐phenylene vinylene) material. At a low temperature (?108 or ?198 °C), the vibronic structures of 9 and 10 were partially resolved. The absorption and emission spectra of a film of 9 were less temperature‐dependent than those of a film of 10 , indicating that the former had a lower tendency to aggregate. A light‐emitting diode (LED) based on 9 emitted yellow light (λmax ≈ 578 nm) with an external quantum efficiency of 0.03%. © 2003 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 41: 3149–3158, 2003 相似文献
28.
Howard Robinson 《Acta Analytica》2005,20(3):7-10
Nicholas Nathan tries to resist the current version of the causal argument for sense-data in two ways. First he suggests that,
on what he considers to be the correct re-construction of the argument, it equivocates on the sense of proximate cause. Second
he defends a form of disjunctivism, by claiming that there might be an extra mechanism involved in producing veridical hallucination,
that is not present in perception. I argue that Nathan’s reconstruction of the argument is not the appropriate one, and that,
properly interpreted, the argument does not equivocate on proximate cause. Furthermore, I claim that his postulation of a
modified mechanism for hallucinations is implausibly ad hoc. 相似文献
29.
Aiqing Zhang Xiangdan Li Changwoon Nah Keejun Hwang Myong‐Hoon Lee 《Journal of polymer science. Part A, Polymer chemistry》2003,41(1):22-29
A soluble aromatic polyimide was chloromethylated via a reaction with chloromethyl methyl ether in the presence of tin(IV) chloride to produce a new starting material for the modification of aromatic polyimides. The chemical structure of the resulting polymer was confirmed by 1H NMR and Fourier transform infrared spectroscopy. The maximum number of chloromethyl groups per repeat unit was 1.81. The chloromethylated polyimide was stable up to 250 °C and soluble in both chloroform and tetrahydrofuran. So that its utilization for further modification could be demonstrated, cinnamic acid was reacted with the formed polyimide, and it produced a new photosensitive polyimide with a cinnamoyl side chain. The photosensitivity of the resulting polyimide was investigated with ultraviolet spectroscopic methods. © 2002 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 41: 22–29, 2003 相似文献
30.
A least‐squares meshfree method based on the first‐order velocity–pressure–vorticity formulation for two‐dimensional incompressible Navier–Stokes problem is presented. The convective term is linearized by successive substitution or Newton's method. The discretization of all governing equations is implemented by the least‐squares method. Equal‐order moving least‐squares approximation is employed with Gauss quadrature in the background cells. The boundary conditions are enforced by the penalty method. The matrix‐free element‐by‐element Jacobi preconditioned conjugate method is applied to solve the discretized linear systems. Cavity flow for steady Navier–Stokes problem and the flow over a square obstacle for time‐dependent Navier–Stokes problem are investigated for the presented least‐squares meshfree method. The effects of inaccurate integration on the accuracy of the solution are investigated. Copyright © 2004 John Wiley & Sons, Ltd. 相似文献