2.45GHz ECR 强流等离子体源核心部件设计与实验研究

电子回旋共振(Electron Cyclotron Resonance,ECR)等离子体源能产生高电荷态离子、高流强的单电荷态离子,提供稳定的束流和良好的重复性.核心部件的设计对ECR等离子体源是至关重要的,磁场对等离子体的生成和分布有直接影响,良好的磁场可以提高等离子体的性能和效率.采用有限元分析方法对ECR等离子体源磁场进行分析与设计,得到了满足设计需求与目标的磁场位形,通过高斯计对设计的永磁环轴向磁场精确测量,发现磁场仿真结果与实验结果吻合比较好,只是轴向磁场最大值及对应位置上有点偏差.通过集成实验,研究核心部件对离子源引出束流强度的影响,引出束流稳定且强度达到7 m A.     

Ultra-Broadband Infrared Metamaterial Absorber for Passive Radiative Cooling

Infrared metamaterial absorber(MMA) based on metal-insulator-metal(MIM) configuration with flexible design,perfect and selective absorption,has attracted much attention recently for passive radiative cooling applications.To cool objects passively,broadband infrared absorption(i.e.8-14 μm) is desirable to emit thermal energy through atmosphere window.We present a novel MMA composed of multilayer MIM resonators periodically arranged on a PbTe/MgF_2 bilayer substrate.Verified by the rigorous coup led-wave analysis method,the proposed MMA shows a relative bandwidth of about 45%(from 8.3 to 13.1 μm with the absorption intensity over 0.8).The broadband absorption performs stably over a wide incident angle range(below 50°) and predicts 12 K cooling below ambient temperature at nighttime.Compared with the previous passive radiative coolers,our design gets rid of the continuous metal substrate and provides an almost ideal transparency window(close to 100%)for millimeter waves over 1 mm.The structure is expected to have potential applications in thermal control of integrated devices,where millimeter wave signal compatibility is also required.     

反铁磁链中Dzyaloshinskii–Moriya机制驱动矢量自旋手征束缚态的研究

Dzyaloshinskii-Moriya(DM)相互作用驱动的矢量自旋手征态,能和声子发生耦合,具备非常丰富的物理现象.本论文以一维反铁磁链中自旋手征-声子耦合模型为基础,研究不同声子环境下,耦合强度对自旋手征动力学演化过程的影响规律.结果表明,对自旋S=1/2的系统,在不同的声子浴(sub-Ohmic(0 1))中,均会在非相干到相干自旋涨落过程中产生无能隙一级相变,其来源是自旋手征束缚态的形成.相变发生的临界自旋-声子耦合强度正比于自旋涨落大小,反比于系统德拜频率.当自旋-声子耦合强度超过其临界值时,自旋手征束缚态的产生将极大地抑制非相干自旋涨落.     

偶氮四唑叠氮基甲脒AFZT高压物性的第一性原理计算

偶氮四唑叠氮基甲脒AFZT的爆轰性能表现优异,在高能炸药领域中具有广阔的应用前景.本文采用基于密度泛函理论的第一性原理方法计算了AFZT在0～50 GPa压力下的晶体结构、电子性质以及氢键相互作用,并分析了这些性质在压力下的变化规律.在压力的作用下,AFZT晶体在5 GPa下发生了结构转变并伴随着电子结构中带隙值的突变,其带隙先减小后增大再减小,总态密度的峰值随着压力的增加而减小.结构中叠氮甲脒阳离子上的N8-N9与N9-N10键在压力下表现得最稳定,N-H^…N类型的氢键在所有相互作用中占据主导地位.此外,AFZT结构沿不同晶轴压缩的难易程度与此方向上氢键相互作用分布的疏密有关,并且其氢键主要沿xz平面分布而在y轴上分布极少,这导致了它沿y轴方向最易被压缩.     

Total Focusing Method Damage Imaging in Frequency Domain Using Laser-Ultrasonic Lamb Wave Based on Time-domain Filtering in Multi-band

A fully non-contact experimental platform for ultrasonic Lamb wave damage detec-tion was constructed,where laser exciting and the scanning laser Doppler vibrome...     

High-performance all-solid-state electrolyte for sodium batteries enabled by the interaction between the anion in salt and Na3SbS4

All-solid-state sodium batteries with poly(ethylene oxide) (PEO)-based electrolytes have shown great promise for large-scale energy storage applications. However, the reported PEO-based electrolytes still suffer from a low Na⁺ transference number and poor ionic conductivity, which mainly result from the simultaneous migration of Na⁺ and anions, the high crystallinity of PEO, and the low concentration of free Na⁺. Here, we report a high-performance PEO-based all-solid-state electrolyte for sodium batteries by introducing Na₃SbS₄ to interact with the TFSI⁻ anion in the salt and decrease the crystallinity of PEO. The optimal PEO/NaTFSI/Na₃SbS₄ electrolyte exhibits a remarkably enhanced Na⁺ transference number (0.49) and a high ionic conductivity of 1.33 × 10⁻⁴ S cm⁻¹ at 45 °C. Moreover, we found that the electrolyte can largely alleviate Na⁺ depletion near the electrode surface in symmetric cells and, thus, contributes to stable and dendrite-free Na plating/stripping for 500 h. Furthermore, all-solid-state Na batteries with a 3,4,9,10-perylenetetracarboxylic dianhydride cathode exhibit a high capacity retention of 84% after 200 cycles and superior rate performance (up to 10C). Our work develops an effective way to realize a high-performance all-solid-state electrolyte for sodium batteries.

A high-performance all-solid-state PEO/NaTFSI/Na₃SbS₄ electrolyte for sodium batteries is realized owing to the electrostatic interaction between TFSI⁻ in the salt and Na₃SbS₄, which immobilizes TFSI⁻ anions and promotes the dissociation of NaTFSI.     

Polyimide separators for rechargeable batteries

Separators are indispensable components of modern electrochemical energy storage devices such as lithium-ion batteries (LIBs).They perform the critical function...     

Production of Atosiban’s Key Intermediate Pentapeptide: Synthetic Approaches to the Development of a Peptide Synthesis with Less Racemization and Simplifier Purification Process

The key intermediate NH₂-Ile-Thr(Bzl)-Asn-Cys(Bzl)-Pro-COOH of Atosiban was prepared from N-Boc-S-Bzl-cysteine by the stepwise lengthening of the chain according to the repetitive N,O-bis(trimethylsilyl)acetamide/N-hydroxysuccinimide ester (BSA/NHS) strategy. This synthetic route required no chromatography purification and can be readily performed, yielding a highly pure pentapeptide compound.     

Analytical Methods for the Determination of 90Sr and 239,240Pu in Environmental Samples

Artificial long-lived radionuclides such as ⁹⁰Sr and ^239,240Pu have been long released into the environment by human nuclear activities, which have a profound impact on the ecological environment. It is of great significance to monitor the concentration of these radionuclides for environmental safety. This paper summarizes and critically discusses the separation and measurement methods for ultra-trace determination of ⁹⁰Sr, ²³⁹Pu, and ²⁴⁰Pu in the environment. After selecting the measurement method, it is necessary to consider the decontamination of the interference from matrix elements and the key elements, and this involves the choice of the separation method. Measurement methods include both radiometric methods and non-radiometric methods. Radiometric methods, including alpha spectroscopy, liquid scintillation spectrometry, etc., are commonly used methods for measuring ^239+240Pu and ⁹⁰Sr. Mass spectrometry, as the representative of non-radiometric measurement methods, has been regarded as the most promising analytical method due to its high absolute sensitivity, low detection limit, and relatively short sample-analysis time. Through the comparison of various measurement methods, the future development trend of radionuclide measurement is prospected in this review. The fully automatic and rapid analysis method is a highlight. The new mass spectrometer with ultra-high sensitivity shows strong analytical capabilities for extremely low concentrations of ⁹⁰Sr, ²³⁹Pu, and ²⁴⁰Pu, and it is expected to develop determination methods with higher sensitivity and lower detection limit.     

Stable Zinc-Based Metal-Organic Framework Photocatalyst for Effective Visible-Light-Driven Hydrogen Production

Herein, a new Zn-MOF material, [Zn(L1)(L2)], 1, was built successfully through a one-pot solvothermal method. The 3D MOF structure was determined by Single X-ray diffraction analysis, IR, and elemental analysis. A series of PXRD tests of 1 after being immersed in different solvents and pH solutions demonstrated the good stability of 1. Interestingly, this material displayed high catalytic activity for the visible-light-driven hydrogen generation under the illumination of white LED in pure water or a mixture of DMF and H₂O without additional photosensitizers and cocatalysts. Besides, the studies also showed that the catalytic activity changed constantly as well as the solvent ratio adjustment of DMF and H₂O from 4:6 to 2:8. Additionally, the catalytic activity reached the best value (743 μmol g⁻¹ h⁻¹) when the solvent ratio was 4:6. The heterogeneous nature and recyclability of the MOF catalyst, as well as several factors that affect the catalytic activity, were investigated and described in detail. Moreover, the photocatalytic mechanism for the hydrogen generation of 1 was also proposed based on the fluorescence spectra and UV-vis absorption.